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    • 31. 发明授权
    • Fuel cell cooling plate
    • 燃料电池冷却板
    • US4956245A
    • 1990-09-11
    • US300983
    • 1989-01-24
    • Hiroshi ShimizuTakashi HaradaKaoru KondohYoshiji Kobayashi
    • Hiroshi ShimizuTakashi HaradaKaoru KondohYoshiji Kobayashi
    • H01M8/02
    • H01M8/04074
    • There is disclosed a fuel cell cooling plate for eliminating waste heat generated by operation of a fuel cell. The cooling plate consists of an inner substrate layer composed of a soft, deformable plastic or low elastic carbonaceous material, sandwiched between outer substrate layers of a strong gas-impermeable carbonaceous material, and a sealing material. The inner substrate is chased with grooves, which house metal cooling pipes for passage of the cooling medium. The soft, deformable, plastic or low elastic material of the inner substrate can be formed so that the grooves fit tightly around the cooling pipes, preventing formation of any air gaps between the pipes and the grooves. This permits nearly complete circumferential contact between the pipes and the grooves, thereby reducing thermal resistance associated with air gaps, and maintaining a high degree of heat transfer. Further, the plastic or low elastic material of the inner substrate layer can conform to thermal expansion and contraction of the cooling plate and pipes, reducing excessive wear over the lifetime of the cooling plate.
    • 公开了一种用于消除由燃料电池的操作产生的废热的燃料电池冷却板。 冷却板包括由柔软的,可变形的塑料或低弹性碳质材料构成的内部基材层,夹在强气体不渗透的含碳材料的外部基材层之间和密封材料之间。 内部衬底被带有凹槽,该凹槽容纳用于冷却介质通过的金属冷却管。 可以形成内部基板的柔软的,可变形的,塑料的或低弹性的材料,使得凹槽紧密地配合在冷却管周围,防止在管道和槽之间形成任何气隙。 这允许管和槽之间几乎完全的圆周接触,从而降低与气隙相关联的热阻,并且保持高度的热传递。 此外,内基材层的塑料或低弹性材料可以符合冷却板和管道的热膨胀和收缩,从而减少冷却板寿命期间的过度磨损。
    • 35. 发明授权
    • Aluminum titanate-mullite base ceramics
    • 钛酸铝 - 莫来石基陶瓷
    • US4767731A
    • 1988-08-30
    • US886365
    • 1986-07-17
    • Seiichi AsamiToshiyuki HamanakaTakashi Harada
    • Seiichi AsamiToshiyuki HamanakaTakashi Harada
    • C04B35/18C04B35/46C04B35/478C04B35/10
    • C04B35/478C04B35/18
    • A sintered aluminum titanate-mullite base ceramic having a chemical composition of not more than 0.8% of MgO, from 53 to 74% of Al.sub.2 O.sub.3, from 14 to 33% of TiO.sub.2, from 1.2 to 5% of Fe.sub.2 O.sub.3, from 6 to 20% of SiO.sub.2, and not more than 0.3% of (CaO+Na.sub.2 O+K.sub.2 O), and an amount of glass in mullite base matrices of the sintered body being not more than 5% when measured at a section of the sintered body. This aluminum titanate-mullite base ceramic is obtained by compounding from 40 to 65% of a starting material of aluminum titanate essentially consisting of from 45 to 62% of Al.sub.2 O.sub.3, from 34 to 50% of TiO.sub.2, from 3 to 7% of Fe.sub.2 O.sub.3, not more than 1% of SiO.sub.2 and not more than 0.3% of (CaO+Na.sub.2 O+K.sub.2 O) with from 35 to 60% of a starting material of mullite essentially consisting of from 18 to 32% of SiO.sub.2, from 68 to 82% of Al.sub.2 O.sub.3, and not more than 0.85% of (Fe.sub.2 O.sub.3 +TiO.sub.2 +CaO+MgO+Na.sub.2 O+K.sub.2 O), at least one of said aluminum titanate starting material and said mullite starting material being fired, and molding a resulting mixture, and firing a thus obtained molding at from 1,550.degree. to 1,700.degree. C. in an oxidizing atmosphere. The alumina titanate starting material may contain not more than 0.1% of MgO.
    • 一种烧结的钛酸铝莫来石基陶瓷,其化学组成不超过MgO的0.8%,Al 2 O 3的53至74%,TiO 2的14至33%,Fe 2 O 3的1.2至5%,6至20% 的SiO 2和不超过0.3%的(CaO + Na 2 O + K 2 O),并且当在烧结体的截面处测量时,烧结体的莫来石基体中的玻璃的量不超过5%。 这种钛酸铝 - 莫来石基陶瓷是通过将基本上由45%至62%的Al 2 O 3,34%至50%的TiO 2,3至7%的Fe 2 O 3组成的钛酸铝原料的40至65% 不大于1%的SiO 2和不超过0.3%的(CaO + Na 2 O + K 2 O),其中35至60%的莫来石原料主要由18至32%的SiO 2,68至82%的 Al 2 O 3和0.85%以下的(Fe 2 O 3 + TiO 2 + CaO + MgO + Na 2 O + K 2 O),所述钛酸铝原料和所述莫来石原料中的至少一种被烧成, 在氧化气氛中在1550℃至1700℃下进行模塑。 钛酸铝原料可含有不超过0.1%的MgO。
    • 39. 发明授权
    • Porous aromatic imide polymer membrane and a process for its manufacture
    • 多芳香族酰亚胺聚合物膜及其制造方法
    • US4512893A
    • 1985-04-23
    • US367954
    • 1982-04-13
    • Hiroshi MakinoYoshihiro KusukiTakashi HaradaHiroshi ShimazakiTosio Isida
    • Hiroshi MakinoYoshihiro KusukiTakashi HaradaHiroshi ShimazakiTosio Isida
    • B01D71/64C08G73/14C08J9/28B29D27/04B32B9/02
    • C08J9/28B01D71/64C08G73/14C08J2379/08Y10S55/05
    • A porous aromatic imide polymer membrane usable as a gas or liquid separator or concentrator is prepared by a process comprising the steps of:(1) dissolving 3 to 30% by weight of an aromatic imide polymer which comprises at least 80 molar % of a recurring unit selected from those of the formulae (I) and (II): ##STR1## wherein R represents a divalent aromatic or heterocyclic radical in 70 to 97% by weight of a solvent consisting essentially of a homogeneous mixture of:(A) 100 parts by weight of a base solvent which consists essentially of at least one polar organic compound and is capable of dissolving therein said aromatic imide polymer in a concentration of 5% by weight or more therein and of evaporating at a temperature of from 50.degree. to 400.degree. C., and(B) 5 to 150 parts by weight of an additional liquid which consists essentially of at least one polar organic compound, is incapable of dissolving therein 3% by weight or more of said aromatic imide polymer and is capable of evaporating at a smaller evaporating rate than that of said base solvent at the above-mentioned evaporating temperature so as to provide a dope solution:(2) forming a thin layer of the dope solution; and(3) heating the thin layer of the dope solution at a temperature of from 50.degree. to 400.degree. C., whereby said mixed solvent is gradually evaporated from the thin layer of the dope solution.
    • 可用作气体或液体分离器或浓缩器的多孔芳族酰亚胺聚合物膜通过包括以下步骤的方法制备:(1)将3至30重量%的芳族酰亚胺聚合物溶解,所述芳族酰亚胺聚合物包含至少80摩尔% 单元选自式(I)和(II)的那些:其中R代表二价芳族或杂环基,其中70至97重量%的基本上由 一种均匀的混合物:(A)100重量份基本溶剂,其基本上由至少一种极性有机化合物组成,并且能够以其中5重量%或更多的浓度溶解在其中的芳族酰亚胺聚合物和蒸发 在50〜400℃的温度下,和(B)5〜150重量份基本上由至少一种极性有机化合物组成的附加液体,不能溶解3重量%以上的 所述芳族酰亚胺聚合物和i 能够在上述蒸发温度下以比所述碱性溶剂更低的蒸发速率蒸发,以提供掺杂溶液:(2)形成薄层的涂料溶液; 和(3)在50-400℃的温度下加热所述涂料溶液的薄层,由此所述混合溶剂从掺杂溶液的薄层逐渐蒸发。