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    • 35. 发明授权
    • Selective removal of tantalum-containing barrier layer during metal CMP
    • 在金属CMP期间选择性去除含钽阻挡层
    • US06858540B2
    • 2005-02-22
    • US10215521
    • 2002-08-08
    • Lizhong SunStan TsaiShijian LiFred C. Redeker
    • Lizhong SunStan TsaiShijian LiFred C. Redeker
    • B24B1/00C09K13/00C11D1/00H01L21/285H01L21/302H01L21/321H01L21/768
    • H01L21/3212H01L21/28568H01L21/7684
    • A method for performing chemical-mechanical polishing/planarization providing highly selective, rapid removal of a Ta-containing barrier layer from a workpiece surface, such as a semiconductor wafer including a damascene-type Cu-based metallization pattern in-laid in a dielectric layer and including a Ta-containing metal diffusion barrier layer, comprises applying an aqueous liquid composition to the workpiece surface during CMP or to the polishing pad utilized for performing the CMP, the composition comprising at least one reducing agent for reducing transition metal ions to a lower valence state, at least one pH adjusting agent, at least one metal corrosion inhibitor, and water, and optionally includes ions of at least one transition metal, e.g., Cu and Fe ions. According to another embodiment, the aqueous liquid composition contains Ag ions and the at least one reducing agent is omitted.
    • 一种用于进行化学机械抛光/平面化的方法,其提供从工件表面高度选择性地快速去除含Ta阻挡层,例如包括嵌入在介电层中的镶嵌型Cu基金属化图案的半导体晶片 并且包括含Ta的金属扩散阻挡层,包括在CMP期间将水性液体组合物施加到工件表面或用于执行CMP的抛光垫,所述组合物包含至少一种还原剂以将过渡金属离子还原成低级 价态,至少一种pH调节剂,至少一种金属腐蚀抑制剂和水,并且任选地包括至少一种过渡金属(例如Cu和Fe离子)的离子。 根据另一个实施方案,含水液体组合物含有Ag离子,并且省略了至少一种还原剂。
    • 40. 发明授权
    • Elimination of pad glazing for Al CMP
    • 消除Al CMP的衬垫玻璃
    • US06509269B2
    • 2003-01-21
    • US09421452
    • 1999-10-19
    • Lizhong SunShijian LiFred C. Redeker
    • Lizhong SunShijian LiFred C. Redeker
    • H01L21302
    • B24B37/0056B24B37/044B24B53/017H01L21/3212
    • Polishing pad glazing during CMP of Al and Al alloys is eliminated or substantially reduced by utilizing a neutral polishing slurry containing a sufficient amount of a surfactant to prevent agglomeration of the abrasive particles with polishing by-products. Embodiments include CMP an Al or an Al alloy surface employing a slurry containing abrasive Al203 particles and about 0.02 to about 5 wt. % of a surfactant to prevent Al203 abrasive slurry particles from agglomerating with Al(OH)3 polishing by-products. Embodiments further include subsequent ex situ pad conditioning using an acid or base to dissolve, or a complexing agent to remove, Al(OH)3 polishing by-products.
    • 通过利用含有足够量的表面活性剂的中性抛光浆料来消除或大大减少Al和Al合金的CMP期间的抛光垫玻璃,以防止磨料颗粒与抛光副产物团聚。 实施方案包括使用含有磨料Al 2 O 3颗粒和约0.02至约5重量%的浆料的CMP或Al合金表面。 %的表面活性剂,以防止Al2O3磨料浆料颗粒与Al(OH)3抛光副产物附聚。 实施例还包括使用酸或碱溶解的随后的非原位垫调节剂或用于去除Al(OH)3抛光副产物的络合剂。