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    • 34. 发明申请
    • FORMATION OF BORIDE BARRIER LAYERS USING CHEMISORPTION TECHNIQUES
    • 使用化学技术形成硼化物屏障层
    • US20070197028A1
    • 2007-08-23
    • US11739549
    • 2007-04-24
    • Jeong ByunAlfred Mak
    • Jeong ByunAlfred Mak
    • H01L21/44
    • C23C16/45529C23C16/38C23C16/45531C23C16/45553H01L21/28562H01L21/76843H01L21/76846
    • In one embodiment, a method for depositing a boride-containing barrier layer on a substrate is provided which includes exposing the substrate sequentially to a boron-containing compound and a tungsten precursor to form a first boride-containing layer during a first sequential chemisorption process, and exposing the substrate to the boron-containing compound, the tungsten precursor, and ammonia to form a second boride-containing layer over the first boride-containing layer during a second sequential chemisorption process. In one example, the tungsten precursor contains tungsten hexafluoride and the boron-containing compound contains diborane. In another embodiment, a contact layer is deposited over the second boride-containing layer. The contact layer may contain tungsten and be deposited by a chemical vapor deposition process. Alternatively, the contact layer may contain copper and be deposited by a physical vapor deposition process. In other examples, boride-containing layers may be formed at a temperature of less than about 500° C.
    • 在一个实施例中,提供了一种用于在衬底上沉积含硼化物阻挡层的方法,其包括在第一顺序化学吸附过程期间将衬底依次暴露于含硼化合物和钨前体以形成第一含硼化物层, 以及在第二顺序化学吸附过程期间将所述衬底暴露于含硼化合物,钨前体和氨以在第一含硼化物层上形成第二含硼化物层。 在一个实例中,钨前体含有六氟化钨,含硼化合物含有乙硼烷。 在另一个实施方案中,在第二含硼化物层上沉积接触层。 接触层可以含有钨并通过化学气相沉积工艺进行沉积。 或者,接触层可以含有铜并通过物理气相沉积工艺进行沉积。 在其他实例中,含硼化物的层可以在小于约500℃的温度下形成。