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    • 34. 发明授权
    • Thermochromic compounds, their preparation and the use thereof
    • 热变色化合物,其制备及其用途
    • US5583223A
    • 1996-12-10
    • US538092
    • 1995-10-02
    • Walter FischerBeat SchmidhalterHeinz Wolleb
    • Walter FischerBeat SchmidhalterHeinz Wolleb
    • B41M5/26B41M5/28C07D233/84C07D249/12C07D513/16
    • C07D233/84B41M5/284C07D249/12
    • There are disclosed compounds ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each independently of one another hydrogen, a C.sub.1 -C.sub.12 alkyl group, a C.sub.1 -C.sub.12 alkoxy group, a C.sub.5 -C.sub.8 cycycloalkyl group, a C.sub.5 -C.sub.8 cycycloalkoxy group, a C.sub.5 -C.sub.8 cycloalkylthio group, a C.sub.6 -C.sub.10 aryl group, a C.sub.6 -C.sub.10 aryloxy group, a C.sub.6 -C.sub.10 arylthio group, nitro, halogen, cyano, --COOH, --COOR.sub.7, --NR.sub.8 R.sub.9 or --CONR.sub.8 R.sub.9, where R.sub.7 is C.sub.1 -C.sub.20 alkyl, C.sub.5 -C.sub.8 cycloalkyl, phenyl or phenyl-C.sub.1 -C.sub.4 alkyl, and R.sub.8 and R.sub.9 are each independently of the other hydrogen, C.sub.1 -C.sub.8 alkyl, phenyl or phenyl-C.sub.1 -C.sub.4 alkyl, X is nitrogen or CR.sub.4, Y is nitrogen or CR.sub.5 and Z is nitrogen or CR.sub.6, and R.sub.4, R.sub.5 and R.sub.6 are each independently of one another hydrogen, a straight-chain or branched C.sub.1 -C.sub.12 alkyl group or a C.sub.6 -C.sub.10 aryl group, with the proviso that, if X is CR.sub.4 and Y is CR.sub.5 and Z is nitrogen or CR.sub.6, or if Y is CR.sub.5 and Z is CR.sub.6 and X is nitrogen or CR.sub.4, then each pair of substituents R.sub.4 and R.sub.5 and R.sub.5 and R.sub.6 form a group --CH.dbd.C(R.sub.10)-C(R.sub.11).dbd.CH-- or a tetramethylene group, wherein R.sub.10 and R.sub.11 are each independently of the other hydrogen, C.sub.1 -C.sub.6 alkyl, phenyl or phenyl-C.sub.1 -C.sub.4 alkyl. The compounds are suitable for use as active components in thermal information recording systems, especially for laser-optical information recording media.
    • 公开了化合物(Ⅰ)其中R1,R2和R3各自独立地为氢,C1-C12烷基,C1-C12烷氧基,C5-C8cy环烷基,C5 -C 8环烷氧基,C 5 -C 8环烷硫基,C 6 -C 10芳基,C 6 -C 10芳氧基,C 6 -C 10芳硫基,硝基,卤素,氰基,-COOH,-COOR 7,-NR 8 R 9或-CONR 8 R 9,其中R 7为C 1 -C 20烷基,C 5 -C 8环烷基,苯基或苯基-C 1 -C 4烷基,R 8和R 9各自独立地为氢,C 1 -C 8烷基,苯基或苯基-C 1 -C 4烷基,X为氮或CR 4,Y为氮或CR 5 并且Z是氮或CR 6,并且R 4,R 5和R 6各自独立地为氢,直链或支链C 1 -C 12烷基或C 6 -C 10芳基,条件是如果X为CR 4且Y为 CR5和Z是氮或CR6,或者如果Y是CR5且Z是CR6,X是氮或CR4,则每对取代基R4和R5以及R5和R6形成基团-CH = C(R10)-C(R11) )= CH-或四亚甲基,w 本文R 10和R 11各自独立地为另一个氢,C 1 -C 6烷基,苯基或苯基-C 1 -C 4烷基。 该化合物适用于热信息记录系统中的有效成分,尤其适用于激光光信息记录介质。
    • 37. 发明授权
    • Substituted tetrathiotetracenes and tetraselenotetracenes
    • US4981962A
    • 1991-01-01
    • US356824
    • 1989-05-24
    • Marcus BaumannWalter FischerVratislav KvitaCarl W. MayerWolfgang Wernet
    • Marcus BaumannWalter FischerVratislav KvitaCarl W. MayerWolfgang Wernet
    • B05D1/20C07D495/06C07D517/06C07D517/16C08G61/12C09K9/02H01B1/12
    • C07D495/06B05D1/202B82Y30/00B82Y40/00C07D517/06C07D517/08C08G61/123C09K9/02H01B1/121
    • Substituted tetrathiotetracenes and tetraselenotetracenes of the formula I ##STR1## in which Z is --S-- or --Se-- and (a) R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are H and R.sup.5 to R.sup.8 are each H and at least one of the radicals R.sup.5 to R.sup.8 independently of one another is a substituent belonging to the group comprising C.sub.1 -C.sub.20 alkyl--X--.sub.p which is unsubstituted or substituted by halogen, --CN, --CONR.sup.9 R.sup.10, --OR.sup.9, --SR.sup.9 or --COOR.sup.9, with the exception of C.sub.1 -C.sub.4 alkyl and methoxy, C.sub.2 -C.sub.18 alkenyl--X--.sub.p, C.sub.2 -C.sub.18 -alkynyl--X--.sub.p, C.sub.3 -C.sub.8 cycloalkyl--X--.sub.p, (C.sub.1 -C.sub.12 alkyl)--C.sub.3 -C.sub.8 cycloalkyl--X--.sub.p, C.sub.3 -C.sub.8 cycloalkyl-C.sub.r H.sub.2r --X--.sub.p, (C.sub.1 -C.sub.12 alkyl)-C.sub.3 -C.sub.8 -cyclo alkyl-C.sub.r H.sub.2r --X--.sub.p, phenyl--X--.sub.p, (C.sub.1 -C.sub.12)alkyl)-phenyl--X--, phenyl-C.sub.r H.sub. 2r --X--.sub.p and (C.sub.1 -C.sub.12 alkyl)-phenyl-C.sub.r H.sub.2r --X--.sub.p, r is 1 or 2 and p is 0 or 1 and X is --O--, --S--, --SO-- or --SO.sub.2 --, or R.sup.5 to R.sup.8 independently are a substituent belonging to the group comprising --Br, --CF.sub.3, --CN, --Si(C.sub.1 -C.sub.4 alkyl).sub.3, --S--(C.sub.m H.sub.2m O)--.sub.n R.sup.11 or --O--C.sub.m H.sub.2m --O--R.sup.11, or each one of R.sup.5 to R.sup.8 is --F or --Cl and at least one further member of R.sup.5 to R.sup.8 is a substituent of the groups defined above, including C.sub.1 -C.sub.4 alkyl and methoxy, R.sup.9 and R.sup.10 independently of one another are H, C.sub.1 -C.sub.12 alkyl, phenyl or --C.sub.m H.sub.2m --O--.sub.q R.sup.11, or R.sup.9 and R.sup.10 together are tetramethylene, pentamethylene, 3-oxapentylene or --CH.sub.2 CH.sub.2 NR.sup.9 CH.sub.2 CH.sub.2 --, R.sup.11 is H or C.sub.1 -C.sub.12 -alkyl, m is a number from 2 to 4, n is a number from 2 to 20 and q is a number from 1 to 20, orb) R.sup.1 to R.sup.8 independently of one another are H or one of the substituents defined above, including C.sub.1 -C.sub.4 alkyl and methoxy, or --COOR.sup.9 or --CONR.sup.9 R.sup.10 or two pairs of adjacent radicals of R.sup.1 to R.sup.8 are --CO--O--CO-- or --CO--NR.sup.9 --CO--, and at least one of R.sup.1 to R.sup.4 and also R.sup.5 to R.sup.8 is a substituent, with the exception of R.sup.2, R.sup.3, R.sup.6 and R.sup.7 when these are --F and methyl, and where R.sup.9 and R.sup.10 are as defined above.With electron acceptors they form charge-transfer complexes which can be used as organic electrical conductors, displays, optical switches and sensors.
    • 39. 发明授权
    • Radio receiver
    • 无线电接收机
    • US4802238A
    • 1989-01-31
    • US36220
    • 1987-04-09
    • Walter FischerChristian Suss
    • Walter FischerChristian Suss
    • H03J3/22H03J5/24H04B1/16H04B1/26
    • H03J5/242
    • In a radio receiver which can be switched between at least two waveranges, the coil winding (33) of the oscillator circuit (31) has a further coil winding (36) inductively coupled to it with which a capacitor (37) is arranged in parallel for limiting the waverange comprising the higher frequencies. In the case of reception of the waverange comprising the lower frequencies this capacitor (37) is effectively arranged as a padding capacitor in series with the set of plates (34) of the variable capacitor in the oscillator circuit (31) while simultaneously the further coil winding (36) is effectively arranged in series with the coil winding (33) of the oscillator circuit (31) for the purpose of extending the range and a further capacitor (38) is effectively arranged in parallel with the set of plates (34) of a variable capacitor in the oscillator circuit (31), for the purpose of shifting the waverange of higher frequencies to the waverange of lower frequencies. This switching process is carried out with a single changeover switch (32) (FIG. 1).
    • 在可以在至少两个摇摆之间切换的无线电接收机中,振荡器电路(31)的线圈绕组(33)具有电感耦合到其上的另外的线圈绕组(36),电容器(37)与其并联布置 用于限制包括较高频率的waverange。 在接收包括较低频率的波动的情况下,该电容器(37)被有效地布置为与振荡器电路(31)中的可变电容器的一组板(34)串联的填充电容器,同时另外的线圈 绕组(36)与振荡电路(31)的线圈绕组(33)串联有效地设置,用于扩展该范围,并且另外的电容器(38)有效地布置成与该组板(34)平行, 的振荡器电路(31)中的可变电容器,用于将较高频率的波动移动到较低频率的波动。 该切换处理由单个转换开关(32)(图1)进行。