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1. 发明授权

US08436131B2 Solid state polymerization process for polyester with phosphinic acid compounds 失效
标题翻译：具有次膦酸化合物的聚酯的固态聚合方法
公开(公告)号：US08436131B2
公开(公告)日：2013-05-07
申请号：US13568585
申请日：2012-08-07
申请人： Paul Odorisio , Stephen M. Andrews , Thomas F. Thompson , Si Wu , Paragkumar Thanki , Deepak M. Rane , Delina Joseph , Jianzhao Wang
发明人： Paul Odorisio , Stephen M. Andrews , Thomas F. Thompson , Si Wu , Paragkumar Thanki , Deepak M. Rane , Delina Joseph , Jianzhao Wang
IPC分类号： C08G64/00 , C08G63/02
CPC分类号： C08G63/80 , C08G63/85 , C08G63/87
摘要： Disclosed are phosphinic acid compounds of formula I, II or III where R1 and R1′ are for instance straight or branched C1-C50alkyl, R2 is for instance straight or branched C22-C50alkyl, R3 and R3′ are for instance straight or branched C1-C50alkyl, R4 is for instance straight or branched C1-C50alkylene and m is from 2 t 100. Also disclosed are polyester compositions comprising the compounds of formula I, II and III.
摘要翻译：公开了式I，II或III的次膦酸化合物，其中R 1和R 1'为例如直链或支链C 1 -C 50烷基，R 2为直链或支链C 22 -C 50烷基，R 3和R 3'为例如直链或支链C1- C 50烷基，R 4为例如直链或支链C 1 -C 50亚烷基，m为2t 100.还公开了包含式I，II和III化合物的聚酯组合物。

2. 发明授权

US4540732A Alkylated S-(hydroxyphenylthio) alkanoates 失效
标题翻译：烷基化S-（羟基苯硫基）烷酸酯
公开(公告)号：US4540732A
公开(公告)日：1985-09-10
申请号：US547520
申请日：1983-10-31
申请人： John D. Spivack , Stephen D. Pastor , Paul Odorisio
发明人： John D. Spivack , Stephen D. Pastor , Paul Odorisio
IPC分类号： C08K5/00 , C07C67/00 , C07C313/00 , C07C323/52 , C08K5/13 , C08K5/36 , C08K5/375 , C08L15/02 , C08L23/00 , C08L59/00 , C08L101/00 , C09K15/08 , C09K15/14 , C09K15/24 , C10M135/26 , C10M135/28 , C10N30/00 , C07C149/40
CPC分类号： C07C323/00 , C08K5/375 , C09K15/08 , C09K15/14 , C09K15/24 , C10M135/26 , C10M2219/085
摘要： The title compounds correspond to the formula ##STR1## and are useful as stabilizers for organic polymers and lubricating oils to counteract the degradative effects of heat, light and air.
摘要翻译：标题化合物对应于式“IMAGE”，可用作有机聚合物和润滑油的稳定剂，以抵消热，光和空气的降解作用。

3. 发明申请

US20130035451A1 Solid State Polymerization Process for Polyester with Phosphinic Acid Compounds 失效
标题翻译：聚酯与膦酸化合物的固态聚合方法
公开(公告)号：US20130035451A1
公开(公告)日：2013-02-07
申请号：US13568585
申请日：2012-08-07
申请人： Paul Odorisio , Stephen M. Andrews , Thomas F. Thompson , Si Wu , Paragkumar Thanki , Deepak M. Rane , Delina Joseph , Jianzhao Wang
发明人： Paul Odorisio , Stephen M. Andrews , Thomas F. Thompson , Si Wu , Paragkumar Thanki , Deepak M. Rane , Delina Joseph , Jianzhao Wang
IPC分类号： C07F9/30 , C07F9/655 , C07F9/32 , C08G63/00
CPC分类号： C08G63/80 , C08G63/85 , C08G63/87
摘要： Disclosed are phosphinic acid compounds of formula I, II or III where R1 and R1′ are for instance straight or branched C1-C50alkyl, R2 is for instance straight or branched C22-C50alkyl, R3 and R3′ are for instance straight or branched C1-C50alkyl, R4 is for instance straight or branched C1-C50alkylene and m is from 2 to 100. Also disclosed are polyester compositions comprising the compounds of formula I, II and III.
摘要翻译：公开了式I，II或III的次膦酸化合物，其中R 1和R 1'为例如直链或支链C 1 -C 50烷基，R 2为直链或支链C 22 -C 50烷基，R 3和R 3'为例如直链或支链C1- C 50烷基，R 4为例如直链或支链C 1 -C 50亚烷基，m为2至100.还公开了包含式I，II和III化合物的聚酯组合物。

4. 发明授权

US5081300A N-alkenyl substituted amine-N-oxide stabilizers 失效
标题翻译： N-烯基取代的胺-N-氧化物稳定剂
公开(公告)号：US5081300A
公开(公告)日：1992-01-14
申请号：US515013
申请日：1990-04-24
申请人： Paul Odorisio , Joseph E. Babiarz
发明人： Paul Odorisio , Joseph E. Babiarz
IPC分类号： C07C239/20 , C07C291/04 , C08K5/32 , C10L1/14 , C10L1/18 , C10L1/22 , C10L1/23 , C10L1/24 , C10M133/36
CPC分类号： C10L1/23 , C07C239/20 , C07C291/04 , C08K5/32 , C10L1/14 , C10L1/24 , C10M133/36 , C10L1/183 , C10L1/2406 , C10L1/2431 , C10L1/2437 , C10M2215/042 , C10M2215/08 , C10M2215/082 , C10M2215/28 , C10M2219/04 , C10M2219/084 , C10N2240/06 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/106 , C10N2240/12 , C10N2240/121 , C10N2240/14 , C10N2240/40
摘要： N-substituted hydroxylamines of formula I ##STR1## where R.sub.1 and R.sub.2 are independently hydrogen, alkyl, alkenyl, aryl or phenylalkyl, and R.sub.3 to R.sub.7 are independently hydrogen, alkyl or substituted alkyl are very effective process stabilizers for polymeric systems providing melt flow stabilization and resistance to discoloration during processing at elevated temperatures as well as effective stabilizers for lubricant compositions.
摘要翻译：式I的N-取代羟胺其中R1和R2独立地是氢，烷基，烯基，芳基或苯基烷基，R3至R7独立地是氢，烷基或取代的烷基是非常有效的聚合体系的工艺稳定剂，其提供熔体流动稳定性和耐高温加工过程中的变色以及润滑剂组合物的有效稳定剂。

5. 发明授权

US4730083A Process for the preparation of 3,5-dialkyl-4-hydroxy benzoic acid 失效
标题翻译： 3,5-二烷基-4-羟基苯甲酸的制备方法
公开(公告)号：US4730083A
公开(公告)日：1988-03-08
申请号：US898794
申请日：1986-08-18
申请人： Stephen D. Pastor , John D. Spivack , Paul Odorisio
发明人： Stephen D. Pastor , John D. Spivack , Paul Odorisio
IPC分类号： C07C51/15
CPC分类号： C07C51/15
摘要： An improved process for the preparation of 3,5-dialkyl-4-hydroxybenzoic acid comprising the reaction of 2,6-dialkylphenol and carbon dioxide in the presence of a mono- or polyalkylene glycol ether.
摘要翻译：一种改进的制备3,5-二烷基-4-羟基苯甲酸的方法，其包括2,6-二烷基苯酚和二氧化碳在单 - 或聚亚烷基二醇醚存在下的反应。

6. 发明申请

US20050101759A1 Polyester and polyamide compositions of low residual aldehyde content 失效
标题翻译：低残留醛含量的聚酯和聚酰胺组合物
公开(公告)号：US20050101759A1
公开(公告)日：2005-05-12
申请号：US11009843
申请日：2004-12-02
申请人： Paul Odorisio , Stephen Andrews , Dario Lazzari , Dirk Simon , Roswell King , Melissa Stamp , Roger Reinicker , Michael Tinkl , Natacha Berthelon , Daniel Muller , Urs Hirt
发明人： Paul Odorisio , Stephen Andrews , Dario Lazzari , Dirk Simon , Roswell King , Melissa Stamp , Roger Reinicker , Michael Tinkl , Natacha Berthelon , Daniel Muller , Urs Hirt
IPC分类号： A23L1/00 , B29D22/00 , C08G63/78 , C08K5/16 , C08K5/17 , C08K5/32 , C08K5/34 , C08L67/02 , C08L77/00
CPC分类号： C08K5/32 , C08K5/053 , C08K5/17 , C08K5/34 , C08L23/0861 , C08L29/04 , C08L33/26 , C08L67/02 , C08L77/00 , C08L101/06 , Y10T428/1352 , Y10T428/1359 , Y10T428/1383 , Y10T428/1393 , Y10T428/1397 , Y10T428/31786 , C08L2666/04
摘要： A mixture of a polyester, such as poly(ethylene terephthalate) PET, or a polyamide, and a suitable stabilizer selected from the group consisting of hydroxylamine stabilizers, substituted hydroxylamine stabilizers, nitrone stabilizers and amine oxide stabilizers, when extrusion compounded exhibits a lower residual acetaldehyde content than does polyester or polyamide alone when similarly treated. The invention pertains to any polyester or polyamide used in the manufacture of molded articles, fibers or films, for instance bottles or containers which are used to store consumer materials, for example food, beverages and water.
摘要翻译：当挤出复合时，聚酯（例如聚对苯二甲酸乙二醇酯）PET或聚酰胺和选自羟胺稳定剂，取代羟胺稳定剂，硝酮稳定剂和氧化胺稳定剂的合适的稳定剂的混合物显示较低的残留类似处理时，单独使用聚酯或聚酰胺的乙醛含量。本发明涉及用于制造模制品，纤维或薄膜的任何聚酯或聚酰胺，例如用于储存消费材料（例如食品，饮料和水）的瓶子或容器。

7. 发明授权

US4642382A 1H-polyalkyl-phosphorinanes 失效
标题翻译： 1H-聚烷基 - 磷杂环己烷
公开(公告)号：US4642382A
公开(公告)日：1987-02-10
申请号：US756123
申请日：1985-07-18
申请人： John D. Spivack , Stephen D. Pastor , Paul Odorisio
发明人： John D. Spivack , Stephen D. Pastor , Paul Odorisio
IPC分类号： C07F9/6568 , C08K5/53 , C08K5/5398 , C09K15/32 , C10M137/12 , C10M137/14 , C07F9/50 , C07F9/53
CPC分类号： C07F9/6568 , C07F9/65685 , C08K5/53 , C08K5/5398 , C09K15/322 , C09K15/324 , C10M137/12 , C10M137/14 , C10M2223/065
摘要： The title compounds correspond to the formula ##STR1## and are useful as stabilizers for organic polymers and lubricating oils to counteract the degradative effects of heat, light and air.
摘要翻译：标题化合物对应于式（I），并且可用作有机聚合物和润滑油的稳定剂，以抵消热，光和空气的降解作用。

8. 发明申请

US20170143612A1 ORAL CARE COMPOSITIONS 审中-公开
公开(公告)号：US20170143612A1
公开(公告)日：2017-05-25
申请号：US15302940
申请日：2015-04-07
申请人： Ted DEISENROTH , Glen Thomas CUNKLE , Lauren JUNKER , Michael KUEPFERT , Paul ODORISIO , Steven N. SAUNDERS , Vishal RAMNARINE , Neethu ABRAHAM , BASF SE
发明人： Ted Deisenroth , Glen Thomas Cunkle , Lauren Junker , Michael Kuepfert , Paul Odorisio , Steven N. Saunders , Vishal Ramnarine , Neethu Abraham
IPC分类号： A61K8/85 , A61K8/73 , A61K8/88 , C08G63/685 , C08G63/668 , C08G63/12 , C08B3/12 , A61Q11/00 , A61K8/02
CPC分类号： A61K8/88 , A61K8/0204 , A61K8/21 , A61K8/27 , A61K8/463 , A61K8/4926 , A61K8/731 , A61K8/733 , A61K8/85 , A61K2800/594 , A61Q11/00 , C08B3/12 , C08G63/12 , C08G63/668 , C08G63/685 , C08G69/44
摘要： The application relates to oral care compositions comprising substantive polyesters formed from xylitol, polycarboxylic acids (or esters, acid halides or anhydrides thereof) and optionally arginine. The formed polyesters or polyesteramides are active in biofilm inhibition and dissolution to maintain clean teeth.

9. 发明申请

US20080108779A1 Process for producing polyester with metal phosphonic acid complex catalysts 审中-公开
标题翻译：用金属膦酸配合物催化剂生产聚酯的方法
公开(公告)号：US20080108779A1
公开(公告)日：2008-05-08
申请号：US11901478
申请日：2007-09-17
申请人： Stephen Andrews , Jianzhao Wang , Thomas Thompson , Paragkumar Thanki , Deepak Rane , Suhas Sahasrabudhe , Preetam Ghogale , Paul Odorisio , Si Wu
发明人： Stephen Andrews , Jianzhao Wang , Thomas Thompson , Paragkumar Thanki , Deepak Rane , Suhas Sahasrabudhe , Preetam Ghogale , Paul Odorisio , Si Wu
IPC分类号： C08G63/02
CPC分类号： C08G63/84 , C08G63/183 , C08G63/189
摘要： Disclosed is a method for the preparation of a polyester, which method comprises in a first step, reacting a dicarboxylic acid or a C1-C4 dicarboxylic diester with a diol at a suitable temperature and pressure to effect esterification or transesterification to prepare a precondensate and in a second step, reacting the precondensate to effect polycondensation at a suitable temperature and pressure to prepare a high molecular weight polyester, where a metal phosphonic acid complex compound of the formula is employed in the first step, in the second step or in both the first and second steps as a reaction catalyst; and wherein n is 0, 1, 2, 3, 4, 5 or 6; p is an integer from 1 to 30; M is a metal selected from the group consisting of Li, Na, K, Cs, Be, Ca, Mg, Sr, Ba, Al, Sb, Cd, Mn, Fe, Co, Ni, Cu and Zn; v is the valency of the metal M and is 1, 2 or 3; q is an integer from 1 to 20 where q=2p/v; and R1 is hydrogen, straight or branched chain alkyl of 1 to 36 carbon atoms, straight or branched chain alkenyl of 1 to 36 carbon atoms, cycloalkyl of 5 to 8 carbon atoms or aryl of 6 to 10 carbon atoms; or is said alkyl, alkenyl, cycloalkyl or aryl substituted by one to four hydroxyl, halogen, straight or branched chain alkoxy of 1 to 8 carbon atoms, straight or branched chain alkyl of 1 to 8 carbon atoms or amino groups. The metal complex catalyst compound is in particular
摘要翻译：公开了一种制备聚酯的方法，该方法包括在第一步中，使二羧酸或C 1 -C 4 - 二羧酸二酯与二醇反应合适的温度和压力以进行酯化或酯交换以制备预缩合物，并且在第二步中，使预缩合物在合适的温度和压力下进行缩聚以制备高分子量聚酯，其中式在第一步，第二步或第一步和第二步都用作反应催化剂; 并且其中n为0,1,2,3,4,5或6; p是1至30的整数; M是选自Li，Na，K，Cs，Be，Ca，Mg，Sr，Ba，Al，Sb，Cd，Mn，Fe，Co，Ni，Cu和Zn中的金属; v是金属M的化合价，为1,2或3; q是1至20的整数，其中q = 2p / v; R 1是氢，1至36个碳原子的直链或支链烷基，1至36个碳原子的直链或支链烯基，5至8个碳原子的环烷基或6至10个芳基碳原子或被1至4个羟基，卤素，1至8个碳原子的直链或支链烷氧基，1至8个碳原子的直链或支链烷基或氨基取代的烷基，链烯基，环烷基或芳基取代。特别是金属络合物催化剂化合物

10. 发明授权

US5162408A N-alkenyl substituted amine-N-oxide stabilizers 失效
标题翻译： N-烯基取代的胺-N-氧化物稳定剂
公开(公告)号：US5162408A
公开(公告)日：1992-11-10
申请号：US766497
申请日：1991-09-26
申请人： Paul Odorisio , Joseph E. Babiarz
发明人： Paul Odorisio , Joseph E. Babiarz
IPC分类号： C07C239/20 , C07C291/04 , C08K5/32 , C10L1/14 , C10L1/18 , C10L1/22 , C10L1/23 , C10L1/24 , C10M133/36
CPC分类号： C10L1/23 , C07C239/20 , C07C291/04 , C08K5/32 , C10L1/14 , C10L1/24 , C10M133/36 , C10L1/183 , C10L1/2406 , C10L1/2431 , C10L1/2437 , C10M2215/042 , C10M2215/08 , C10M2215/082 , C10M2215/28 , C10M2219/04 , C10M2219/084 , C10N2240/06 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/106 , C10N2240/12 , C10N2240/121 , C10N2240/14 , C10N2240/40
摘要： N-Alkenyl substituted hydroxylamines of formula I ##STR1## where R.sub.1 and R.sub.2 are independently hydrogen, alkyl, aryl or phenylalkyl, and R.sub.3 to R.sub.7 are independently hydrogen, alkyl or substituted alkyl are very effective process stabilizers for polymeric systems providing melt flow stabilization and resistance to discoloration during processing at elevated temperatures as well as effective stabilizers for lubricant compositions.
摘要翻译：式I的N-烯基取代的羟胺其中R 1和R 2独立地是氢，烷基，芳基或苯基烷基，且R 3至R 7独立地是氢，烷基或取代的烷基是提供熔体的聚合体系的非常有效的工艺稳定剂流动稳定性和耐高温加工过程中的变色以及润滑剂组合物的有效稳定剂。

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