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    • 31. 发明授权
    • Method of forming thin film using atomic layer deposition method
    • 使用原子层沉积法形成薄膜的方法
    • US06576053B1
    • 2003-06-10
    • US09679559
    • 2000-10-06
    • Yeong-kwan KimYoung-wook ParkJae-soon LimSung-je ChoiSang-in Lee
    • Yeong-kwan KimYoung-wook ParkJae-soon LimSung-je ChoiSang-in Lee
    • C30B2504
    • H01L21/31691C30B25/02C30B29/20H01L21/316
    • In a method of forming a thin film using an atomic layer deposition (ALD) method, a thin film is formed on a substrate in cycles. Each cycle includes injecting a first reactant including an atom that forms the thin film and a ligand into a reaction chamber that includes the substrate, purging the first reactant, injecting a second reactant into the reaction chamber, and purging the second reactant. The thin film is formed by a chemical reaction between the atom that forms the thin film and a second reactant whose binding energy with respect to the atom that forms the thin film is larger than the binding energy of the ligand with respect to the atom that forms the thin film and the generation of by-products is prevented. The generation of a hydroxide by-product in the thin film is suppressed by using a material that does not include a hydroxide as the second reactant, purging the second reactant, and reacting the second reactant with a third reactant that includes hydroxide. After purging the second reactant, the third reactant for removing impurities and improving the stoichiometry of the thin film is injected and purged. In this way, it is possible to obtain a thin film that does not include impurities and whose stoichiometry is excellent.
    • 在使用原子层沉积(ALD)法形成薄膜的方法中,在基板上循环形成薄膜。 每个循环包括将包括形成薄膜的原子和配体的第一反应物注入到包括基板的反应室中,清洗第一反应物,将第二反应物注入反应室,以及清除第二反应物。 薄膜由形成薄膜的原子与第二反应物之间的化学反应形成,第二反应物的结合能相对于形成薄膜的原子的结合能大于配体相对于形成的原子的结合能 防止了薄膜和副产物的产生。 通过使用不包含氢氧化物作为第二反应物的材料,吹扫第二反应物,并使第二反应物与包含氢氧化物的第三反应物反应,可以抑制薄膜中氢氧化物副产物的产生。 在清洗第二反应物之后,注入和清除用于除去杂质的第三反应物和改善薄膜的化学计量。 以这种方式,可以获得不含杂质的化学计量优异的薄膜。
    • 36. 发明授权
    • Manufacturing method of transistors
    • 晶体管的制造方法
    • US5837605A
    • 1998-11-17
    • US563082
    • 1995-11-27
    • Young-wook ParkDae-rok BaeMun-han Park
    • Young-wook ParkDae-rok BaeMun-han Park
    • H01L21/335H01L21/28H01L21/285H01L21/336H01L29/78H01L21/441
    • H01L21/28061
    • A manufacturing method for transistors wherein silicide is directed doped with a conductive impurity includes the steps of: forming a field oxide film defining an active region on a semiconductor substrate; forming transistors wherein a doped first silicide film is formed on gate electrodes on said active region; forming an interlayer dielectric film having contact holes on the whole surface of said semiconductor substrate; forming spacers on the innerwalls of each contact hole;p forming a thin doped polysilicon film on the whole surface of said semiconductor surface; and forming a doped second silicide film on the whole surface of said doped polysilicon film, filling each contact hole. The silicide film is directly doped with conductive impurity so that the conductive impurity of a polysilicon film can be prevented from being diffused to the outside. Therefore, the doped silicide film is useful to prevent the threshold voltage from increasing and the saturation current from reducing.
    • 其中硅化物被引导掺杂有导电杂质的晶体管的制造方法包括以下步骤:在半导体衬底上形成限定有源区的场氧化物膜; 形成晶体管,其中在所述有源区上的栅电极上形成掺杂的第一硅化物膜; 在所述半导体衬底的整个表面上形成具有接触孔的层间绝缘膜; 在每个接触孔的内壁上形成间隔物; p在所述半导体表面的整个表面上形成薄掺杂多晶硅膜; 以及在所述掺杂多晶硅膜的整个表面上形成掺杂的第二硅化物膜,填充每个接触孔。 硅化物膜直接掺杂有导电杂质,使得可以防止多晶硅膜的导电杂质扩散到外部。 因此,掺杂的硅化物膜可用于防止阈值电压升高,饱和电流降低。