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    • 22. 发明申请
    • RAMAN SPECTROSCOPY AS INTEGRATED CHEMICAL METROLOGY
    • 拉曼光谱作为一体化学计量学
    • US20080024762A1
    • 2008-01-31
    • US11830202
    • 2007-07-30
    • HONGBIN FANGJosh GoldenTimothy WeidmanYaxin WangArulkumar Shanmugasundram
    • HONGBIN FANGJosh GoldenTimothy WeidmanYaxin WangArulkumar Shanmugasundram
    • G01N21/00
    • G01N21/65
    • A method for measuring the concentration of the metal solution and reducing agent solution within the electroless plating solution is disclosed. Raman spectroscopy is used to measure the concentration of each solution within the electroless plating solution after they have been mixed together. By measuring the concentration of each solution prior to providing the solution to a plating cell, the concentration of the individual solutions can be adjusted so that the targeted concentration of each solution is achieved. Additionally, each solution can be individually analyzed using Raman spectroscopy prior to mixing with the other solutions. Based upon the Raman spectroscopy measurements of the individual solutions prior to mixing, the individual components that make up each solution can be adjusted prior to mixing so that the targeted component concentration can be achieved.
    • 公开了一种用于测量化学镀溶液中的金属溶液和还原剂溶液的浓度的方法。 拉曼光谱法用于测量化学镀溶液混合在一起后每种溶液的浓度。 通过在将溶液提供给电镀池之前测量每种溶液的浓度,可以调节各溶液的浓度,从而实现每种溶液的目标浓度。 此外,每个溶液可以在与其他溶液混合之前使用拉曼光谱单独分析。 基于混合前单个溶液的拉曼光谱测量,可以在混合之前调整组成每种溶液的各个组分,从而可以实现目标组分浓度。
    • 24. 发明申请
    • Apparatus and method for atomic layer cleaning and polishing
    • 用于原子层清洁和抛光的装置和方法
    • US20070095367A1
    • 2007-05-03
    • US11262445
    • 2005-10-28
    • Yaxin WangFang MeiVan NguyenArulkumar ShanmugasundramDmitry Lubomirsky
    • Yaxin WangFang MeiVan NguyenArulkumar ShanmugasundramDmitry Lubomirsky
    • B08B7/04B08B3/00B08B7/00
    • H01L21/67046
    • The present invention generally provides an apparatus and method of processing substrates to uniformly remove any residual contamination from the surface of a substrate by use of an appropriate cleaning chemistry and contact with a cleaning medium. In one embodiment, the cleaning medium, such as is a brush or a scrubbing component that is positioned in a cleaning module. In one embodiment, the process of cleaning the surface of a substrate W is completed by “scrubbing” the surface of the substrate while using a cleaning solution that is selected to chemically etch a material from the surface of the substrate. In one aspect, the amount of material removed from the surface of a substrate is only about 10-30 Angstroms (Å). In one embodiment, the substrate surface is cleaned by use of a scrubbing process that uses a fluid that doesn't react with the exposed materials on the surface of the substrate. The fluid is thus used to lubricate the surfaces in contact and to carry any abraded material away from the surface of the substrate. In one aspect, the fluid may be DI water. In one aspect, it may be desirable to add ultrasonic or megasonic agitation to the substrate during the cleaning process to help remove or dislodge material from the surface of the substrate.
    • 本发明总体上提供了一种加工基材的装置和方法,以通过使用适当的清洁化学品和与清洁介质的接触来均匀地除去基材表面的任何残余污染物。 在一个实施例中,清洁介质,例如位于清洁模块中的刷子或擦洗部件。 在一个实施例中,清洁衬底W的表面的过程通过“擦洗”衬底的表面而完成,同时使用选择用于从衬底的表面化学蚀刻材料的清洁溶液。 在一个方面,从衬底的表面去除的材料的量仅为约10-30埃()。 在一个实施例中,通过使用使用不与衬底表面上暴露的材料反应的流体的洗涤过程来清洁衬底表面。 因此,流体用于润滑接触表面并将任何磨损的材料携带离开基底的表面。 在一个方面,流体可以是去离子水。 在一个方面,可能期望在清洁过程中向基底添加超声波或兆声波搅拌以帮助从衬底的表面移除或移除材料。
    • 28. 发明授权
    • Chemical vapor deposition of ruthenium films for metal electrode applications
    • 用于金属电极应用的钌膜的化学气相沉积
    • US06440495B1
    • 2002-08-27
    • US09632497
    • 2000-08-03
    • Christopher P. WadeElaine PaoYaxin WangJun Zhao
    • Christopher P. WadeElaine PaoYaxin WangJun Zhao
    • C23C1606
    • C23C16/18
    • The present invention provides a method of depositing ruthenium films on a substrate via liquid source chemical vapor deposition wherein the source material is liquid at room temperature and utilizing process conditions such that deposition of the ruthenium films occurs at a temperature in the kinetic-limited temperature regime. Also provided is a method of depositing a thin ruthenium film on a substrate by liquid source chemical vapor deposition using bis-(ethylcyclopentadienyl) ruthenium by vaporizing the bis-(ethylcyclopentadienyl) ruthenium at a vaporization temperature of about 100-300° C. to form a CVD source material gas, providing an oxygen source reactant gas and forming a thin ruthenium film on a substrate in a reaction chamber using the CVD source material gas and the oxygen source reactant gas at a substrate temperature of about 100-500° C.
    • 本发明提供了一种通过液体源化学气相沉积在基片上沉积钌膜的方法,其中源材料在室温下为液体并且利用工艺条件使得钌膜的沉积在动态限制温度范围内的温度下发生 。 还提供了一种通过使用双 - (乙基环戊二烯基)钌的液体源化学气相沉积在基板上沉积薄钌膜的方法,其通过在约100-300℃的蒸发温度下汽化双 - (乙基环戊二烯基)钌来形成 CVD源材料气体,在基板温度为约100-500℃下,使用CVD源材料气体和氧源反应气体,在反应室中的基板上提供氧源反应气体并形成薄钌膜。
    • 29. 发明授权
    • Process gas distribution for forming stable fluorine-doped silicate glass and other films
    • 用于形成稳定的氟掺杂硅酸盐玻璃等膜的工艺气体分布
    • US06383954B1
    • 2002-05-07
    • US09361682
    • 1999-07-27
    • Yaxin WangDiana ChanTurgut SahinTetsuya IshikawaFarhad Moghadam
    • Yaxin WangDiana ChanTurgut SahinTetsuya IshikawaFarhad Moghadam
    • H01L2131
    • H01L21/02274C23C16/401C23C16/455H01J37/3244H01L21/02126H01L21/02129H01L21/02131H01L21/31625H01L21/31629
    • A substrate processing system includes a housing defining a chamber for forming a film on the substrate surface of a substrate disposed within the chamber. The system includes a first plurality of nozzles that extend into the chamber for injecting a first chemical at a first distance from a periphery of the substrate surface, and a second plurality of nozzles that extend into the chamber for injecting a second chemical at a second distance from the periphery of the substrate surface. The second distance is substantially equal to or smaller than the first distance. In one embodiment, the first chemical contains a dielectric material and the second chemical contains dopant species which react with the first chemical to deposit a doped dielectric material on the substrate. Injecting the dopant species closer to the substrate surface than previously done ensures that the dopant species are distributed substantially uniformly over the substrate surface and the deposition of a stable doped dielectric layer.
    • 衬底处理系统包括限定用于在设置在腔室内的衬底的衬底表面上形成膜的腔室。 该系统包括第一多个喷嘴,其延伸到腔室中,用于从衬底表面的周边第一距离处注入第一化学品;以及第二多个喷嘴,其延伸到室中,用于以第二距离注入第二化学品 从基板表面的周边。 第二距离基本上等于或小于第一距离。 在一个实施例中,第一化学品包含介电材料,第二化学品含有与第一化学物质反应以在衬底上沉积掺杂电介质材料的掺杂剂物质。 注入比以前更接近于衬底表面的掺杂剂物质确保掺杂剂物质基本均匀地分布在衬底表面上并沉积稳定的掺杂介电层。