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11. 发明申请

US20080306215A1 Functionalization of olefin/diene copolymers 审中-公开
标题翻译：烯烃/二烯共聚物的官能化
公开(公告)号：US20080306215A1
公开(公告)日：2008-12-11
申请号：US11810499
申请日：2007-06-06
申请人： Abhimanyu Onkar Patil , Stephen Zushma , Steven P. Rucker , Christian Peter Mehnert , Raymond A. Cook , Lisa Saunders Baugh , Enock Berluche
发明人： Abhimanyu Onkar Patil , Stephen Zushma , Steven P. Rucker , Christian Peter Mehnert , Raymond A. Cook , Lisa Saunders Baugh , Enock Berluche
IPC分类号： C08C19/34
CPC分类号： C08F8/00 , C08F2800/20 , C08F210/18 , C08F210/02 , C08F210/16 , C08F8/46 , C08F8/06 , C08F8/04 , C08F8/08
摘要： A process is described for functionalizing a copolymer comprising units derived from at least one α-olefin and units derived from at least one diene, which copolymer contains at least one double bond. The process comprises reacting the copolymer with at least one functionalizing agent to introduce polar pendant oxygen-containing functional groups onto the copolymer.
摘要翻译：描述了一种用于使包含至少一种α-烯烃的单元和源自至少一种二烯的单元的共聚物官能化的方法，该共聚物含有至少一个双键。该方法包括使共聚物与至少一种官能化试剂反应以将极性侧链含氧官能团引入到共聚物上。

12. 发明申请

US20080015314A1 Ethylene/dicyclopentadiene copolymers and functionalized derivatives thereof 有权
标题翻译：乙烯/二环戊二烯共聚物及其官能化衍生物
公开(公告)号：US20080015314A1
公开(公告)日：2008-01-17
申请号：US11801633
申请日：2007-05-10
申请人： Lisa Saunders Baugh , Abhimanyu Onkar Patil , Christian Peter Mehnert , Kevin R. Squire , Kenneth A. Cook , Caiguo Gong , Enock Berluche , Karla Schall Colle , Alan J. Oshinski , Stephen Zushma , Beverly J. Poole
发明人： Lisa Saunders Baugh , Abhimanyu Onkar Patil , Christian Peter Mehnert , Kevin R. Squire , Kenneth A. Cook , Caiguo Gong , Enock Berluche , Karla Schall Colle , Alan J. Oshinski , Stephen Zushma , Beverly J. Poole
IPC分类号： C08L45/00
CPC分类号： C08F210/02 , C08F8/04 , C08F8/08 , C08F232/00
摘要： Disclosed is a selected type of copolymer composition comprising copolymers having units derived from ethylene and dicyclopentadiene (DCPD) co-monomers. Such copolymer compositions: a) have a DCPD-derived comonomer unit content of from about 25 mole % to about 45 mole %; b) have a Weight Average Molecular Weight, Mw, of greater than about 170,000; c) comprise amorphous material and have glass transition temperatures, Tg, of from about 8° C. to about 129° C., which also fit the equation Tg (in ° C.)≧[(mole % DCPD×3.142)−4.67]; and d) comprise no significant amount of crystalline polyethylene homopolymer or crystallizable polyethylene segments within the ethylene-dicylopentadiene copolymers. Such copolymers can be readily derivatized by hydrogention and/or epoxidation to provide polymeric materials suitable for use as engineering thermoplastics.Also disclosed are processes for preparing and optionally further derivatizing ethylene/dicyclopentadiene copolymers having the characteristics hereinbefore described. Such processes comprise: a) contacting ethylene with a polymerization mixture comprising greater than about 4.0 molar dicyclopentadiene, in the presence of a selected activated cyclopentadienyl-fluorenyl metallocene catalyst bearing a substituent, preferably a methyl substituent, at the 3-position of the cyclopentadienyl ring, under specific polymerization conditions including relatively high ethylene pressures to thereby form the desired ethylene-dicyclopentadiene copolymers within the polymerization mixture. Such copolymers are then recovered and/or further hydrogenated or functionalized.
摘要翻译：公开了一种选择类型的共聚物组合物，其包含具有衍生自乙烯和二环戊二烯（DCPD）共聚单体的单元的共聚物。这种共聚物组合物：a）具有约25摩尔％至约45摩尔％的DCPD衍生的共聚单体单元含量; b）具有大于约170,000的重均分子量，M < c）包含非晶材料，并且具有约8℃至约129℃的玻璃化转变温度，其也适合方程式T（g）（℃）] = [（摩尔％DCPDx 3.142）-4.67]; 和d）在乙烯 - 二茂二烯共聚物内不含有显着量的结晶聚乙烯均聚物或可结晶的聚乙烯链段。这样的共聚物可以通过水合和/或环氧化来容易地衍生，以提供适合用作工程热塑性塑料的聚合材料。还公开了制备和任选地进一步衍生具有上述特征的乙烯/二环戊二烯共聚物的方法。这样的方法包括：a）在选择的活化的环戊二烯基 - 芴基茂金属催化剂存在下，在含有大于约4.0摩尔二环戊二烯的聚合混合物的存在下，使乙烯与环戊二烯基环的3位具有取代基，优选甲基取代基接触在包括相对较高的乙烯压力的特定聚合条件下，从而在聚合混合物内形成所需的乙烯 - 二环戊二烯共聚物。然后回收和/或进一步氢化或官能化此类共聚物。

13. 发明授权

US08426529B2 Ethylene/dicyclopentadiene copolymers and functionalized derivatives thereof 有权
标题翻译：乙烯/二环戊二烯共聚物及其官能化衍生物
公开(公告)号：US08426529B2
公开(公告)日：2013-04-23
申请号：US11801633
申请日：2007-05-10
申请人： Lisa Saunders Baugh , Abhimanyu Onkar Patil , Christian Peter Mehnert , Kevin R. Squire , Kenneth A. Cook , Caiguo Gong , Enock Berluche , Karla Schall Colle , Alan J. Oshinski , Stephen Zushma , Beverly J. Poole
发明人： Lisa Saunders Baugh , Abhimanyu Onkar Patil , Christian Peter Mehnert , Kevin R. Squire , Kenneth A. Cook , Caiguo Gong , Enock Berluche , Karla Schall Colle , Alan J. Oshinski , Stephen Zushma , Beverly J. Poole
IPC分类号： C08F8/04 , C08F8/08 , C08F236/20 , C08F232/06
CPC分类号： C08F210/02 , C08F8/04 , C08F8/08 , C08F232/00
摘要： Disclosed is a selected type of copolymer composition comprising copolymers having units derived from ethylene and dicyclopentadiene (DCPD) co-monomers. Such copolymer compositions: a) have a DCPD-derived comonomer unit content of from about 25 mole % to about 45 mole %; b) have a Weight Average Molecular Weight, Mw, of greater than about 170,000; c) comprise amorphous material and have glass transition temperatures, Tg, of from about 8° C. to about 129° C., which also fit the equation Tg (in ° C.)≧[(mole % DCPD×3.142)−4.67]; and d) comprise no significant amount of crystalline polyethylene homopolymer or crystallizable polyethylene segments within the ethylene-dicyclopentadiene copolymers. Such copolymers can be readily derivatized by hydrogenation and/or epoxidation to provide polymeric materials suitable for use as engineering thermoplastics. Also disclosed are processes for preparing and optionally further derivatizing ethylene/dicyclopentadiene copolymers having the characteristics hereinbefore described.
摘要翻译：公开了一种选择类型的共聚物组合物，其包含具有衍生自乙烯和二环戊二烯（DCPD）共聚单体的单元的共聚物。这种共聚物组合物：a）具有约25摩尔％至约45摩尔％的DCPD衍生的共聚单体单元含量; b）重均分子量Mw大于约170,000; c）包含无定形材料并且具有约8℃至约129℃的玻璃化转变温度Tg，其也符合方程式Tg（℃）= [（摩尔％DCPD×3.142） - 4.67]; 和d）在乙烯 - 二环戊二烯共聚物内不含有显着量的结晶聚乙烯均聚物或可结晶的聚乙烯链段。这样的共聚物可以通过氢化和/或环氧化来容易地衍生化，以提供适合用作工程热塑性塑料的聚合材料。还公开了制备和任选地进一步衍生具有上述特征的乙烯/二环戊二烯共聚物的方法。

14. 发明申请

US20120322948A1 PRODUCTION OF ELASTOMERIC FUNCTIONALIZED OLEFIN POLYMERS 有权
标题翻译：生产弹性功能烯烃聚合物
公开(公告)号：US20120322948A1
公开(公告)日：2012-12-20
申请号：US13596567
申请日：2012-08-28
申请人： Lisa Saunders Baugh , Enock Berluche , Karla Schall Colle
发明人： Lisa Saunders Baugh , Enock Berluche , Karla Schall Colle
IPC分类号： C08F20/42 , C08F4/80
CPC分类号： C08C19/02 , C08F4/80 , C08F232/00 , C08G61/08
摘要： In a process for producing a functionalized polyalkenamer, at least one monomer comprising a monocyclic olefin having at least one pendant alkyl group bonded thereto, wherein the pendant alkyl group has at least two carbon atoms and is substituted with a polar moiety spaced by at least one carbon atom from the monocyclic olefin, is contacted with a polymerization catalyst under conditions effective to effect ring opening polymerization of the monocyclic olefin and produce the functionalized polyalkenamer.
摘要翻译：在制备官能化的聚链烯聚合物的方法中，至少一种包含具有至少一个与其键合的侧链烷基的单环烯烃的单体，其中所述侧基烷基具有至少两个碳原子并且被极性部分取代，所述极性部分被至少一个来自单环烯烃的碳原子在有效地实现单环烯烃的开环聚合的条件下与聚合催化剂接触并产生官能化的聚链烷醇。

15. 发明授权

US08148472B1 Polymer compositions comprising cyclic olefin polymers, polyolefin modifiers and non-functionalized plasticizers 有权
标题翻译：包含环烯烃聚合物，聚烯烃改性剂和非官能化增塑剂的聚合物组合物
公开(公告)号：US08148472B1
公开(公告)日：2012-04-03
申请号：US12012380
申请日：2008-02-01
申请人： Lisa Saunders Baugh , Bryan R. Chapman , Enock Berluche
发明人： Lisa Saunders Baugh , Bryan R. Chapman , Enock Berluche
IPC分类号： C08L45/00 , C08L23/00 , C08L23/04 , C08F8/00
CPC分类号： C08L23/0823 , C08L23/16 , C08L53/00 , C08L2314/06 , C08L2666/24 , C08L2666/06
摘要： This invention relates to a polymer composition comprising a blend comprising: (a) greater than 30 wt (based upon the weight of the composition) of a cyclic olefin polymer having a Tg greater than 60° C. and having a Tm heat of fusion (ΔHf) of 40 J/g or less selected from the group consisting of: i) copolymers comprising at least one acyclic olefin and at least 15 mole % of one or more cyclic olefins; ii) partially or completely hydrogenated copolymers comprising at least one acyclic olefin and at least 15 mole % of one or more cyclic olefins; iii) metathesis copolymers comprising two or more cyclic olefins; iv) partially or completely hydrogenated metathesis copolymers comprising two or more cyclic olefins; v) metathesis homopolymers comprising cyclic olefins; vi) partially or completely hydrogenated metathesis homopolymers comprising cyclic olefins; and vii) mixtures thereof; (b) from 1 to 50 wt % (based upon the weight of the composition) of an acyclic olefin polymer modifier having a glass transition temperature of less than 0° C.; (c) from 0.1 to 50 wt % (based upon the weight of the composition) of a non-functionalized plasticizer having a kinematic viscosity at 100° C. of 3 to 3000 cSt, a viscosity index of 120 or more, a pour point of 0° C. or less and a flash point of 200° C. or more.
摘要翻译：本发明涉及一种包含共混物的聚合物组合物，其包含：（a）大于30重量％（基于组合物的重量）的Tg大于60℃并具有Tm熔化热的环状烯烃聚合物 40J / g或更低，选自：i）包含至少一种非环烯烃和至少15摩尔％的一种或多种环烯烃的共聚物; ii）部分或完全氢化的共聚物，其包含至少一种非环烯烃和至少15摩尔％的一种或多种环烯烃; iii）包含两个或更多个环烯烃的复分解共聚物; iv）包含两种或多种环烯烃的部分或完全氢化的复分解共聚物; v）包含环烯烃的复分解均聚物; vi）包含环状烯烃的部分或完全氢化的复分解均聚物; 和vii）其混合物; （b）1至50重量％（基于组合物的重量）的玻璃化转变温度低于0℃的无环烯烃聚合物改性剂; （c）0.1至50重量％（基于组合物的重量）的在100℃下的运动粘度为3至3000cSt，粘度指数为120或更大的非官能化增塑剂，倾点为0℃以下，闪点为200℃以上。

16. 发明申请

US20110257317A1 TETRACARBOXYLIC ESTER PLASTICIZERS 有权
标题翻译：四甲氧基硅烷增塑剂
公开(公告)号：US20110257317A1
公开(公告)日：2011-10-20
申请号：US13085905
申请日：2011-04-13
申请人： Lisa Saunders Baugh , Enock Berluche , Karla Schall Colle , Manika Varma-Nair , Ramzi Yanni Saleh , Jon Edmond Randolph Stanat , Stephen Zushma , Victor DeFlorio
发明人： Lisa Saunders Baugh , Enock Berluche , Karla Schall Colle , Manika Varma-Nair , Ramzi Yanni Saleh , Jon Edmond Randolph Stanat , Stephen Zushma , Victor DeFlorio
IPC分类号： C08K5/11 , C07C69/604 , C07C69/74 , C08K5/12 , C08L27/06
CPC分类号： C07C69/34 , C07C69/74 , C07C2601/08 , C08K5/11 , C08K5/12
摘要： Tetraesters of a C4-C5 aliphatic tetracarboxylic acid and OXO-alcohols and plasticized compositions containing said tetraesters are provided.
摘要翻译：提供C4-C5脂族四羧酸和OXO-醇的四酯和含有所述四酯的增塑组合物。

17. 发明授权

US07479531B2 Olefin polymerization catalyst system useful for polar monomers 有权
标题翻译：烯烃聚合催化剂体系可用于极性单体
公开(公告)号：US07479531B2
公开(公告)日：2009-01-20
申请号：US11786487
申请日：2007-04-12
申请人： Lisa Saunders Baugh , Enock Berluche , Paul Veinbergs Hinkle , Francis Charles Rix , Donald Norman Schulz
发明人： Lisa Saunders Baugh , Enock Berluche , Paul Veinbergs Hinkle , Francis Charles Rix , Donald Norman Schulz
IPC分类号： C08F4/44 , B01J31/38
CPC分类号： C07F15/04 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/02 , C08F210/16 , C08F232/08 , C08F2500/03 , C08F2500/09 , C08F2500/10 , C08F4/80 , C08F232/00 , C08F216/04 , C08F210/14 , C08F2500/05 , C08F4/7031 , C08F4/7022
摘要： This invention relates to copolymers produced by a polymerization method comprising contacting at least one olefin monomer, at least one polar monomer, an optional activator, and a catalyst compound represented by the formula: wherein M is selected from groups 3-11 of the periodic table; L1 represents a formal anionic ligand, L2 represents a formal neutral ligand, a is an integer greater than or equal to 1; b is greater than or equal to 0; c is greater than or equal to 1, E is nitrogen or phosphorus, Ar0 is arene, R1-R4 are, each independently, selected from hydrogen, hydrocarbyl, substituted hydrocarbyl or functional group, provided however that R3 and R4 do not form a naphthyl ring, N is nitrogen and O is oxygen.
摘要翻译：本发明涉及通过聚合方法制备的共聚物，其包括使至少一种烯烃单体，至少一种极性单体，任选的活化剂和由下式表示的催化剂化合物：其中M选自周期表的第3-11组 ; L 1表示正式的阴离子配体，L 2表示正式的中性配体，a为大于或等于1的整数; b大于或等于0; c大于或等于1，E是氮或磷，Ar 0是芳烃，R 1 -R 4各自独立地选自氢，烃基，取代的烃基或官能团，但是R 3和R 4不形成萘基环，N为氮，O为氧。

18. 发明申请

US20080300363A1 Blends of co-precipitated hydrogenated ethylene-dicyclpentadiene and elastomeric polymers to provide impact modified structural polyolefins 有权
标题翻译：共沉淀的氢化乙烯 - 二环戊二烯和弹性体聚合物的共混物以提供冲击改性的结构聚烯烃
公开(公告)号：US20080300363A1
公开(公告)日：2008-12-04
申请号：US11809573
申请日：2007-06-01
申请人： Lisa Saunders Baugh , Enock Berluche
发明人： Lisa Saunders Baugh , Enock Berluche
IPC分类号： C08F136/06 , C08F8/00
CPC分类号： C08F236/20 , C08F8/04 , C08L23/0823 , C08L23/16 , C08L23/26 , C08L2205/02 , C08F210/02 , C08L2666/06 , C08L2666/04
摘要： Disclosed is the preparation of compositions which are blends of certain types of hydrogenated ethylene-dicyclopentadiene (E/DCPD) copolymers in combination with elastomeric polymers. An E/DCPD copolymer and an elastomeric polymer are co-dissolved in a common liquid reaction medium which is then subjected to hydrogenation conditions. These hydrogenation conditions serve to hydrogenate in-situ at least a portion of the residual double bonds of the E/DCPD copolymer component and possibly also eliminate any residual unsaturation which might be present in the elastomeric polymers. This combination of materials which has been hydrogenated in-situ can then be co-precipitated to form a polymer composition which can be molded into polyolefin materials of improved structural, thermal and mechanical properties with desirable impact resistance.
摘要翻译：公开了组合物的制备，其是某些类型的氢化乙烯 - 二环戊二烯（E / DCPD）共聚物与弹性体聚合物的组合的共混物。将E / DCPD共聚物和弹性体聚合物共溶于通常的液体反应介质中，然后将其进行氢化条件。这些氢化条件用于原位氢化E / DCPD共聚物组分的残余双键的至少一部分，并且还可以消除可能存在于弹性体聚合物中的任何残余不饱和度。然后可将这种原位氢化的材料的组合共沉淀形成聚合物组合物，该聚合物组合物可以模塑成具有改善的结构，热和机械性能并具有期望的耐冲击性的聚烯烃材料。

19. 发明申请

US20060047094A1 Late transition metal catalysts for olefin polymerization and oligomerization 有权
标题翻译：用于烯烃聚合和低聚的后期过渡金属催化剂
公开(公告)号：US20060047094A1
公开(公告)日：2006-03-02
申请号：US10517104
申请日：2003-07-17
申请人： Vladimir Cherkasov , Michael Bubnov , Nikolay Druzhkov , Valentina Glushakova , Irina Teplova , Nina Skorodumova , Gleb Abakumov , Cynthia Ballinger , Kevin Squire , Jo Ann Canich , Enock Berluche , Lisa Baugh , Donald Schulz , Baiyi Zhao
发明人： Vladimir Cherkasov , Michael Bubnov , Nikolay Druzhkov , Valentina Glushakova , Irina Teplova , Nina Skorodumova , Gleb Abakumov , Cynthia Ballinger , Kevin Squire , Jo Ann Canich , Enock Berluche , Lisa Baugh , Donald Schulz , Baiyi Zhao
IPC分类号： C08F4/06 , B01J31/00 , C07F15/02
CPC分类号： B01J31/0214 , B01J31/1805 , B01J31/1815 , B01J2231/12 , B01J2531/845 , B01J2531/847 , C07F15/0066 , C07F15/045 , C07F15/065 , C08F10/00 , C08F210/16 , C08F2410/03 , C08F4/025 , C08F210/06 , C08F2500/03 , C08F210/14 , C08F4/7037 , C08F4/7027 , C08F4/7006 , C08F4/52 , C08F4/7042 , C08F4/7004
摘要： This invention relates to a transition metal compound represented by the formula LMX wherein M is a Group 3 to 11 metal L is a bulky bidentate or tridentate neutral ligand that is bonded to M by two or three heteroatoms and at least one heteroatom is nitrogen; X is a substituted or unsubstituted catecholate ligand provided that the substituted catecholate ligand does not contain a 1,2-diketone functionality.
摘要翻译：本发明涉及由式LMX表示的过渡金属化合物，其中M为第3至11族金属，L为通过两个或三个杂原子与至少一个杂原子与氮键合至M的体积大的二齿或三齿中性配体; X是取代或未取代的儿茶酚酸酯配体，条件是取代的儿茶酚酸配体不含有1,2-二酮官能团。

20. 发明申请

US20050137369A1 Linear functional copolymers of ethylene with precise and minimum run length distributions and method of making thereof 失效
标题翻译：具有精确和最小游程长度分布的乙烯的线性官能团共聚物及其制备方法
公开(公告)号：US20050137369A1
公开(公告)日：2005-06-23
申请号：US10962086
申请日：2004-10-08
申请人： Lisa Baugh , Stephen Lehman , Kenneth Wagener , Donald Schulz , Enock Berluche
发明人： Lisa Baugh , Stephen Lehman , Kenneth Wagener , Donald Schulz , Enock Berluche
IPC分类号： C08F210/02 , C08F210/16 , C08F4/80
CPC分类号： C08F210/02 , C08F210/16 , C08F4/80 , C08F236/20 , C08F2500/02 , C08F2500/03 , C08F220/10 , C08F218/00 , C08F218/08 , C08F232/00
摘要： The present invention is related to a linear functional polymer having repeating units A, B and D. Unit A represents —CH2—, unit B represents and unit D represents where R1 represents a polar functional group. There are at least four A units separating each B unit, each D unit, and each B and D unit. The value y represents the total number of B units and is an integer greater than or equal to 1. The total number of D units is represented by h and is an integer greater than or equal to 0. And x represents the total number of A units and is an integer sufficient that the molar fraction of the B and D units in the linear functional polymer is represented by a value j defined by the equation: j = y + h x + y + h ≤ 0.032 . The present invention is also directed to a method for preparing such linear functional polymers by copolymerizing a first polar substituted monomer and a second non-polar unsubstituted monomer.
摘要翻译：本发明涉及具有重复单元A，B和D的线性官能聚合物。单元A表示-CH 2 - ，单元B表示，单元D表示其中R 1 表示极性官能团。每个B单元，每个D单元和每个B和D单元分开至少四个A单元。值y表示B个单位的总数，并且是大于或等于1的整数.D单位的总数由h表示，并且是大于或等于0的整数。x表示A的总数单元，并且是足以使线性官能聚合物中B和D单元的摩尔分数由以下等式定义的值j表示的整数： < MATH OVERFLOW =“SCROLL”> j = y + h x + y + > <= 0.032

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