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    • 12. 发明授权
    • Cationic phthalocyanine compounds
    • 阳离子酞菁化合物
    • US4845209A
    • 1989-07-04
    • US229789
    • 1988-08-04
    • Jean-Marie Adam
    • Jean-Marie Adam
    • C07D487/22C09B47/08C09B47/26C09B47/32D06P1/14D06P1/42D21H19/10D21H21/28
    • D21H21/28C09B47/32D06P1/14
    • The invention relates to phthalocyanine compounds of the formula ##STR1## wherein MePc is a copper, cobalt or nickel phthalocyanine radical,R.sub.1 is hydrogen or alkyl,X is alkylene, andR.sub.2, R.sub.3 and R.sub.4, are each independently alkyl which is unsubstituted or substituted by hydroxy, alkoxy, phenyl or amino, or R.sub.1 and R.sub.2, when taken together, are methylene, ethylene or propylene if X is methylene or ethylene, or two or three of R.sub.2, R.sub.3 and R.sub.3, together with the nitrogen atom, form a 5- to 7-membered unsubstituted or substituted heterocyclic ring which may contain one or two additional hetero atoms selected from the group consisting of O, N and S as ring members,An.sup..crclbar. is a cation and M is a cation, and x is greater than y and y is greater than 0, and the sum of x+y is 4 or less than 4.These compounds can be used as dyes, in particular for dyeing and printing cellulosic materials and polyacrylonitrile materials, especially paper.
    • 本发明涉及式(I)的酞菁化合物,其中MePc是铜,钴或镍酞菁基,R 1是氢或烷基,X是亚烷基,R 2,R 3和R 4各自独立地是烷基, 如果X是亚甲基或亚乙基,或者R 2,R 3和R 3的两个或三个与氮原子一起,则它们被羟基,烷氧基,苯基或氨基取代,或者R 1和R 2一起是亚甲基,亚乙基或丙烯 形成5至7元未取代或取代的杂环,其可以含有一个或两个另外的选自O,N和S的杂原子作为环成员,An( - )是阳离子,M是阳离子 ,x大于y且y大于0,x + y之和为4或小于4.这些化合物可用作染料,特别用于染色和印花纤维素材料和聚丙烯腈材料,特别是纸张 。
    • 14. 发明授权
    • Basic dioxazine compounds
    • 基本二恶嗪化合物
    • US4336377A
    • 1982-06-22
    • US116196
    • 1980-01-28
    • Jean-Marie AdamPierre Galafassi
    • Jean-Marie AdamPierre Galafassi
    • C09B19/00C09B19/02C09B62/44C09B69/00
    • C09B19/02C09B69/001
    • Novel dioxazine compounds of the formula ##STR1## in which Z is a basic group, which can be quaternized, Y is an anionic group and X and X.sub.1 independently of one another are identical or different substituents from the category comprising: hydrogen, halogen, CN, substituted or unsubstituted alkyl (C.sub.1 -C.sub.4); substituted or unsubstituted phenyl; NHCOR.sub.1 in which R.sub.1 is alkyl (C.sub.1 -C.sub.4), cycloalkyl, substituted or unsubstituted aryl or a heterocyclic radical; and OCOR.sub.2 in which R.sub.2 is substituted or unsubstituted alkyl (C.sub.1 -C.sub.4) or cycloalkyl; or X and X.sub.1 are the group ##STR2## in which R.sub.4 and R.sub.5 independently of one another are: hydrogen, substituted or unsubstituted alkyl (C.sub.1 -C.sub.4), cycloalkyl or aryl, or R.sub.4 together with R.sub.5 and with the inclusion of the N atom forms a heterocyclic ring, or X and X.sub.1 are the group COOR.sub.6, in which R.sub.6 is hydrogen, substituted or unsubstituted alkyl or cycloalkyl; n is a number from 1 to 4 and m is a number from 0 to 2, with the proviso that the number m is smaller than n, and in which the benzo radicals A and A.sub.1 can be identical or different and can have one or more further substituents, their preparation and their use as dyes, in particular for dyeing and printing natural and regenerated cellulose materials without the addition of salt, are described.
    • 式(Ⅰ)的新型二嗪类化合物,其中Z为碱性基团,其可季铵化,Y为阴离子基团,X和X1彼此独立地为相同或不同的取代基,其类别包括:氢, 卤素,CN,取代或未取代的烷基(C1-C4); 取代或未取代的苯基; NHCOR1,其中R1是烷基(C1-C4),环烷基,取代或未取代的芳基或杂环基; 和OCOR2,其中R2是取代或未取代的烷基(C1-C4)或环烷基; 或者X和X 1是其中R 4和R 5彼此独立的基团是:氢,取代或未取代的烷基(C 1 -C 4),环烷基或芳基,或R 4与R 5一起并包括N原子 形成杂环,或X和X 1为COOR 6基团,其中R 6为氢,取代或未取代的烷基或环烷基; n是1至4的数,m是0至2的数,条件是数m小于n,其中苯并基A和A1可以相同或不同,并且可以具有一个或多个 描述了进一步的取代基,它们的制备及其作为染料的用途,特别是用于染色和印刷天然和再生纤维素材料而不添加盐的用途。
    • 17. 发明申请
    • New compounds, a process for their preparation and their use as dyes and pigments
    • 新化合物,其制备方法及其作为染料和颜料的用途
    • US20060258784A1
    • 2006-11-16
    • US11487840
    • 2006-07-17
    • Jean-Marie AdamPramod DalviVadiraj EkkundiJean-Pierre BacherRamaswami SreenivasanDeepak Rane
    • Jean-Marie AdamPramod DalviVadiraj EkkundiJean-Pierre BacherRamaswami SreenivasanDeepak Rane
    • C07D413/04C08K5/34
    • C09D11/32C09D5/028C09D5/035C09D11/037
    • Compounds of formula (1) wherein R1 is hydrogen, hydroxy, halogen, nitro, cyano, amino, carboxy, carboxylic ester, sulfo, sulfonic ester, carboxylic amide, sulfonic amide, alkylthio, arylthio, alkoxy or aryloxy, R′1 is hydrogen, hydroxy, halogen, nitro, cyano, amino, carboxy, carboxylic ester, sulfo, sulfonic ester, carboxylic amide, sulfonic amide, alkylthio, arylthio, alkoxy or aryloxy, X is —O—, —S—, —NH— or —N(alkyl)—, X′ is —O—, —S—, —NH— or —N(alkyl)—, Y is hydrogen or carboxylic ester, Y′ is hydrogen or carboxylic ester, Z is ═C— or ═N—, Z′ is ═C— or ═N—, x is 0 or 1, when Z is ═N—, then x is 0, y is 0 or 1, when Z′ is ═N—, then y is 0, A is a conjugated linking bridge of the formula wherein n is 0, 1, 2 or 3, m is 0, 1, 2 or 3, B is a phenyl ring, T is ═C(R3)— or ═N—, wherein R3 is hydrogen, C1-C12alkyl or CN, W is a heterocyclic, or linear or polycondensed aromatic group which is unsubstituted or substituted by alkyl, halogen, hydroxy, alkoxy, alkylthio or amino, G is —CH═ or —N═, and R2 is hydrogen, alkyl, halogen, hydroxy, alkoxy, alkylthio or amino, their preparation and their use in the production of coloured plastics or polymeric colour particles.
    • 式(1)的化合物,其中R 1是氢,羟基,卤素,硝基,氰基,氨基,羧基,羧酸酯,磺基,磺酸酯,羧酸酰胺,磺酰胺,烷硫基,芳硫基,烷氧基 或芳氧基,R'1是氢,羟基,卤素,硝基,氰基,氨基,羧基,羧酸酯,磺基,磺酸酯,羧酸酰胺,磺酰胺,烷硫基,芳硫基,烷氧基或芳氧基, X是-O - , - S-,-NH-或-N(烷基) - ,X'是-O - , - S-,-NH-或-N(烷基) - ,Y是氢或羧酸酯, Y'是氢或羧酸酯,Z是-C-或-N-,Z'是-C-或-N-,x是0或1,当Z是-N-时,x是0,y是0 或1时,当Z'为-N-时,y为0,A为下式的共轭连接桥,其中n为0,1,2或3,m为0,1,2或3,B为苯基 环,T是-C(R 3) - 或-N-,其中R 3是氢,C 1 -C 3 - C12烷基或CN,W是未取代或被取代的杂环或直链或缩聚芳族基团 烷基,卤素,羟基,烷氧基,烷硫基或氨基,G是-CH-或-N-,R 2是氢,烷基,卤素,羟基,烷氧基,烷硫基或氨基,它们的制备和 它们用于生产有色塑料或聚合物色颗粒。