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    • 1. 发明申请
    • New compounds, a process for their preparation and their use as dyes and pigments
    • 新化合物,其制备方法及其作为染料和颜料的用途
    • US20060258784A1
    • 2006-11-16
    • US11487840
    • 2006-07-17
    • Jean-Marie AdamPramod DalviVadiraj EkkundiJean-Pierre BacherRamaswami SreenivasanDeepak Rane
    • Jean-Marie AdamPramod DalviVadiraj EkkundiJean-Pierre BacherRamaswami SreenivasanDeepak Rane
    • C07D413/04C08K5/34
    • C09D11/32C09D5/028C09D5/035C09D11/037
    • Compounds of formula (1) wherein R1 is hydrogen, hydroxy, halogen, nitro, cyano, amino, carboxy, carboxylic ester, sulfo, sulfonic ester, carboxylic amide, sulfonic amide, alkylthio, arylthio, alkoxy or aryloxy, R′1 is hydrogen, hydroxy, halogen, nitro, cyano, amino, carboxy, carboxylic ester, sulfo, sulfonic ester, carboxylic amide, sulfonic amide, alkylthio, arylthio, alkoxy or aryloxy, X is —O—, —S—, —NH— or —N(alkyl)—, X′ is —O—, —S—, —NH— or —N(alkyl)—, Y is hydrogen or carboxylic ester, Y′ is hydrogen or carboxylic ester, Z is ═C— or ═N—, Z′ is ═C— or ═N—, x is 0 or 1, when Z is ═N—, then x is 0, y is 0 or 1, when Z′ is ═N—, then y is 0, A is a conjugated linking bridge of the formula wherein n is 0, 1, 2 or 3, m is 0, 1, 2 or 3, B is a phenyl ring, T is ═C(R3)— or ═N—, wherein R3 is hydrogen, C1-C12alkyl or CN, W is a heterocyclic, or linear or polycondensed aromatic group which is unsubstituted or substituted by alkyl, halogen, hydroxy, alkoxy, alkylthio or amino, G is —CH═ or —N═, and R2 is hydrogen, alkyl, halogen, hydroxy, alkoxy, alkylthio or amino, their preparation and their use in the production of coloured plastics or polymeric colour particles.
    • 式(1)的化合物,其中R 1是氢,羟基,卤素,硝基,氰基,氨基,羧基,羧酸酯,磺基,磺酸酯,羧酸酰胺,磺酰胺,烷硫基,芳硫基,烷氧基 或芳氧基,R'1是氢,羟基,卤素,硝基,氰基,氨基,羧基,羧酸酯,磺基,磺酸酯,羧酸酰胺,磺酰胺,烷硫基,芳硫基,烷氧基或芳氧基, X是-O - , - S-,-NH-或-N(烷基) - ,X'是-O - , - S-,-NH-或-N(烷基) - ,Y是氢或羧酸酯, Y'是氢或羧酸酯,Z是-C-或-N-,Z'是-C-或-N-,x是0或1,当Z是-N-时,x是0,y是0 或1时,当Z'为-N-时,y为0,A为下式的共轭连接桥,其中n为0,1,2或3,m为0,1,2或3,B为苯基 环,T是-C(R 3) - 或-N-,其中R 3是氢,C 1 -C 3 - C12烷基或CN,W是未取代或被取代的杂环或直链或缩聚芳族基团 烷基,卤素,羟基,烷氧基,烷硫基或氨基,G是-CH-或-N-,R 2是氢,烷基,卤素,羟基,烷氧基,烷硫基或氨基,它们的制备和 它们用于生产有色塑料或聚合物色颗粒。
    • 2. 发明申请
    • New heterocyclic compounds, a process for their preparation and their use as dyes and pigments
    • 新的杂环化合物,其制备方法及其作为染料和颜料的用途
    • US20060124014A1
    • 2006-06-15
    • US10548358
    • 2004-03-10
    • Jean-Marie AdamPramod DalviVadiraj EkkundiJean-Pierre BacherRamaswami SreenivasanDeepak Rane
    • Jean-Marie AdamPramod DalviVadiraj EkkundiJean-Pierre BacherRamaswami SreenivasanDeepak Rane
    • B41F31/00
    • C09D11/32C09D5/028C09D5/035C09D11/037
    • Compounds of formula (I) wherein R1 is hydrogen, hydroxy, halogen, nitro, cyano, amino, carboxy, carboxylic ester, sulfo, sulfonic ester, carboxylic amide, sulfonic amide, alkylthio, arylthio, alkoxy or aryloxy, R′1 is hydrogen, hydroxy, halogen, nitro, cyano, amino, carboxy, carboxylic ester, sulfo, sulfonic ester, carboxylic amide, sulfonic amide, alkylthio, arylthio, alkoxy or aryloxy, X is —O—, —S—, —NH— or —N(alkyl)-, X′ is —O—, —S—, —NH— or —N(alkyl)-, Y is hydrogen or carboxylic ester, Y′ is hydrogen or carboxylic ester, Z is ═C— or ═N—, Z′ is ═C— or ═N—, x is 0 or 1, when Z is ═N—, then x is 0, y is 0 or 1, when Z′ is ═N—, then y is 0, A is a conjugated linking bridge of the formulae (II), (III), (IV), (V), or (VI), wherein n is 0, 1, 2 or 3, m is 0, 1, 2 or 3, B is a phenyl ring, T is ═C(R3)— or ═N—, wherein R3 is hydrogen, C1-C12alkyl or CN, W is a heterocyclic, or linear or polycondensed aromatic group which is unsubstituted or substituted by alkyl, halogen, hydroxy, alkoxy, alkylthio or amino, G is —CH═ or —N═, and R2 is hydrogen, alkyl, halogen, hydroxy, alkoxy, alkylthio or amino, their preparation and their use in the production of coloured plastics or polymeric color particles.
    • 式(I)化合物,其中R 1是氢,羟基,卤素,硝基,氰基,氨基,羧基,羧酸酯,磺基,磺酸酯,羧酸酰胺,磺酰胺,烷硫基,芳硫基,烷氧基 或芳氧基,R'1是氢,羟基,卤素,硝基,氰基,氨基,羧基,羧酸酯,磺基,磺酸酯,羧酸酰胺,磺酰胺,烷硫基,芳硫基,烷氧基或芳氧基, X是-O - , - S-,-NH-或-N(烷基) - ,X'是-O - , - S-,-NH-或-N(烷基) - ,Y是氢或羧酸酯, Y'是氢或羧酸酯,Z是-C-或-N-,Z'是-C-或-N-,x是0或1,当Z是-N-时,x是0,y是0 或者当Z'为-N-时,y为0,A为式(II),(III),(IV),(V)或(VI)的共轭连接桥,其中n为0 ,1,2或3,m为0,1,2或3,B为苯环,T为-C(R 3) - 或-N-,其中R 3 N是氢,C 1 -C 12烷基或CN,W是杂环或直链或缩聚芳族基,其中i 未取代或被烷基,卤素,羟基,烷氧基,烷硫基或氨基取代,G是-CH-或-N-,R 2是氢,烷基,卤素,羟基,烷氧基,烷硫基或 氨基,它们的制备及其在生产有色塑料或聚合物着色颗粒中的应用。
    • 3. 发明申请
    • Process for producing polyester with metal phosphonic acid complex catalysts
    • 用金属膦酸配合物催化剂生产聚酯的方法
    • US20080108779A1
    • 2008-05-08
    • US11901478
    • 2007-09-17
    • Stephen AndrewsJianzhao WangThomas ThompsonParagkumar ThankiDeepak RaneSuhas SahasrabudhePreetam GhogalePaul OdorisioSi Wu
    • Stephen AndrewsJianzhao WangThomas ThompsonParagkumar ThankiDeepak RaneSuhas SahasrabudhePreetam GhogalePaul OdorisioSi Wu
    • C08G63/02
    • C08G63/84C08G63/183C08G63/189
    • Disclosed is a method for the preparation of a polyester, which method comprises in a first step, reacting a dicarboxylic acid or a C1-C4 dicarboxylic diester with a diol at a suitable temperature and pressure to effect esterification or transesterification to prepare a precondensate and in a second step, reacting the precondensate to effect polycondensation at a suitable temperature and pressure to prepare a high molecular weight polyester, where a metal phosphonic acid complex compound of the formula is employed in the first step, in the second step or in both the first and second steps as a reaction catalyst; and wherein n is 0, 1, 2, 3, 4, 5 or 6; p is an integer from 1 to 30; M is a metal selected from the group consisting of Li, Na, K, Cs, Be, Ca, Mg, Sr, Ba, Al, Sb, Cd, Mn, Fe, Co, Ni, Cu and Zn; v is the valency of the metal M and is 1, 2 or 3; q is an integer from 1 to 20 where q=2p/v; and R1 is hydrogen, straight or branched chain alkyl of 1 to 36 carbon atoms, straight or branched chain alkenyl of 1 to 36 carbon atoms, cycloalkyl of 5 to 8 carbon atoms or aryl of 6 to 10 carbon atoms; or is said alkyl, alkenyl, cycloalkyl or aryl substituted by one to four hydroxyl, halogen, straight or branched chain alkoxy of 1 to 8 carbon atoms, straight or branched chain alkyl of 1 to 8 carbon atoms or amino groups. The metal complex catalyst compound is in particular
    • 公开了一种制备聚酯的方法,该方法包括在第一步中,使二羧酸或C 1 -C 4 - 二羧酸二酯与二醇反应 合适的温度和压力以进行酯化或酯交换以制备预缩合物,并且在第二步中,使预缩合物在合适的温度和压力下进行缩聚以制备高分子量聚酯,其中式 在第一步,第二步或第一步和第二步都用作反应催化剂; 并且其中n为0,1,2,3,4,5或6; p是1至30的整数; M是选自Li,Na,K,Cs,Be,Ca,Mg,Sr,Ba,Al,Sb,Cd,Mn,Fe,Co,Ni,Cu和Zn中的金属; v是金属M的化合价,为1,2或3; q是1至20的整数,其中q = 2p / v; R 1是氢,1至36个碳原子的直链或支链烷基,1至36个碳原子的直链或支链烯基,5至8个碳原子的环烷基或6至10个芳基 碳原子 或被1至4个羟基,卤素,1至8个碳原子的直链或支链烷氧基,1至8个碳原子的直链或支链烷基或氨基取代的烷基,链烯基,环烷基或芳基取代。 特别是金属络合物催化剂化合物