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    • 11. 发明授权
    • Low leakage, low capacitance isolation material
    • 低泄漏,低电容隔离材料
    • US06465370B1
    • 2002-10-15
    • US09105633
    • 1998-06-26
    • Martin SchremsRolf-Peter VollertsenJoachim Hoepfner
    • Martin SchremsRolf-Peter VollertsenJoachim Hoepfner
    • H01L21469
    • H01L27/10861H01L21/3003H01L29/66181H01L2924/0002Y10S438/918H01L2924/00
    • A method for reducing a capacitance formed on a silicon substrate includes the step of introducing hydrogen atoms into a portion of said surface to increase the dielectric constant of such portion of the surface increasing the effective thickness of the dielectric material and hence reducing said capacitance. The method includes the step of forming the silicon dioxide layer with a thickness greater than two nanometers. The step of introducing hydrogen includes forming hydrogen atoms in the surface with concentrations of 1017 atoms per cubic centimeter, or greater. In one embodiment the hydrogen atoms are introduced by baking in hydrogen at a temperature of 950° C. to 1100° C. and pressure greater than 100 Torr. A trench capacitor DRAM cell is provided wherein the hydrogen provides a passivation layer to increase the effective capacitance around a collar region and thereby reduce unwanted transistor action.
    • 减少形成在硅衬底上的电容的方法包括将氢原子引入所述表面的一部分以增加表面部分的介电常数增加介电材料的有效厚度从而减小所述电容的步骤。 该方法包括形成厚度大于2纳米的二氧化硅层的步骤。 引入氢的步骤包括在表面上形成浓度为1017原子/立方厘米或更大的氢原子。 在一个实施方案中,氢原子通过在氢气中在950℃至1100℃的温度和大于100托的压力下进行烘烤而引入。 提供了一种沟槽电容器DRAM单元,其中氢提供钝化层以增加环绕区域周围的有效电容,从而减少不需要的晶体管作用。
    • 17. 发明授权
    • Method for filling trenches in integrated semiconductor circuits
    • 在集成半导体电路中填充沟槽的方法
    • US06677218B2
    • 2004-01-13
    • US10210374
    • 2002-07-31
    • Markus KirchhoffMartin Schrems
    • Markus KirchhoffMartin Schrems
    • H01L21762
    • H01L27/1087H01L21/02238H01L21/02258H01L21/31675H01L21/76224
    • A method in which a recess is formed in the surface of a semiconductor substrate and a material is grown on the inner wall of the recess, includes the steps of producing an electrically insulating layer on the surface of the substrate outside the recess, and selectively growing the material on the inner wall of the recess as a result of the substrate, as an electrode, being brought into contact with an electrolysis liquid and electrolysis being carried out, during which the insulating layer prevents the material from growing outside the recess. Before the electrolysis is carried out, a reserve material is epitaxially deposited on the inner wall of the recess and, during the electrolysis, the reserve material is converted into the material being grown by electrolysis.
    • 一种在半导体衬底的表面上形成凹槽并且在凹部的内壁上生长材料的方法包括以下步骤:在凹部外部的衬底表面上制造电绝缘层,并且选择性地生长 作为电极的作为电极的基板的内壁上的材料与电解液体接触并进行电解,在此期间绝缘层防止材料在凹部外生长。 在进行电解之前,将储备材料外延地沉积在凹槽的内壁上,并且在电解期间,储备材料被转化为通过电解生长的材料。
    • 20. 发明授权
    • Process for improving the thickness uniformity of a thin oxide layer in semiconductor wafer fabrication
    • 用于改善半导体晶片制造中的薄氧化物层的厚度均匀性的方法
    • US06537926B1
    • 2003-03-25
    • US09638309
    • 2000-08-14
    • Martin SchremsHelmut Horst Tews
    • Martin SchremsHelmut Horst Tews
    • H01L2131
    • H01L21/02238H01L21/02255H01L21/31662
    • A two-step progressive thermal oxidation process is provided to improve the thickness uniformity of a thin oxide layer in semiconductor wafer fabrication. A semiconductor wafer, e.g., of silicon, with a surface subject to formation of an oxide layer thereon but which is substantially oxide layer-free, is loaded, e.g., at room temperature, into an oxidation furnace maintained at a low loading temperature, e.g., of 400-600° C., and the wafer temperature is adjusted to a low oxidizing temperature, e.g., of 400-600° C., all while the wafer is under an inert, e.g., nitrogen, atmosphere. The wafer is then subjected to initial oxidation, e.g., in dry oxygen, at the low oxidizing temperature to form a uniform initial thickness oxide, e.g., silicon dioxide, layer, e.g., of up to 10 angstroms, on the surface, after which the furnace temperature is increased to a high oxidizing temperature, e.g., of 700-1200° C., while the wafer is under an inert atmosphere. The wafer is next subjected to final oxidation, e.g., in oxygen and/or water vapor, at the high oxidizing temperature to increase uniformly the oxide layer to a selective final thickness, e.g., of 20-100 angstroms, whereupon the resultant uniform final thickness oxide layer-containing wafer is recovered from the furnace.
    • 提供了两步逐步热氧化工艺以改善半导体晶片制造中薄氧化物层的厚度均匀性。 诸如硅的半导体晶片,具有在其上形成氧化物层但基本上不含氧化物层的表面,例如在室温下被加载到维持在低负载温度的氧化炉中,例如 ,400-600℃,并且将晶片温度调节至低氧化温度,例如400-600℃,同时晶片处于惰性,例如氮气氛下。 然后将晶片在低氧化温度下进行初始氧化,例如在干燥的氧气中,以在表面上形成均匀的初始厚度氧化物,例如二氧化硅,例如至多10埃的层,之后 炉温升高到高的氧化温度,例如700-1200℃,同时晶片处于惰性气氛。 接着在高氧化温度下将晶片进行最终氧化,例如在氧气和/或水蒸气中,以将氧化物层均匀地增加至选择性最终厚度,例如20-100埃,由此得到均匀的最终厚度 从炉中回收含氧化物层的晶片。