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    • 5. 发明申请
    • PROCESS FOR PRODUCING LIQUID HYDROCARBONS
    • 生产液体烃的方法
    • WO98042803A1
    • 1998-10-01
    • PCT/CA1998/000267
    • 1998-03-20
    • B01J12/00B01J19/12C10G1/02C10G1/10C10G15/12
    • B01J19/126B01J12/007B01J2219/0894C10G1/02C10G1/10C10G15/12
    • A process for producing liquid hydrocarbons from hydrocarbon materials is disclosed. The hydrocarbon materials are heated to a temperature above 350 DEG C thereby producing a hot cracked gas stream. The hot gas stream is saturated with an aqueous solution containing hydroxide ions and monatomic hydrogen to produce a saturated gas stream. The saturated gas stream is cooled to standard temperature and pressure and is condensed to produce liquid hydrocarbons and waste gases. The waste gases are induced through the microwave generator to form an ionized gas stream, or plasma, which is merged with the aforementioned hot cracked gas stream. The carbon or other residue is oxidized to form a gas stream, which is merged with the aforementioned hot cracked gas stream. Alternatively, initially a gaseous plasma is generated, the hot cracked gas stream is merged with or passed through the plasma to form an ionized gas stream which is then saturated with an aqueous solution.
    • 公开了一种从烃类材料制备液体烃的方法。 将烃类材料加热至350℃以上,从而产生热裂解气流。 热气流用含有氢氧根离子和单原子氢的水溶液饱和以产生饱和气流。 将饱和气流冷却至标准温度和压力并冷凝以产生液体烃和废气。 通过微波发生器诱导废气形成离子化气体流或与上述热裂解气流合并的等离子体。 碳或其他残余物被氧化以形成气流,其与上述热裂解气流合并。 或者,最初产生气态等离子体,热裂解气流与等离子体合并或通过等离子体,形成离子化气体流,然后用水溶液饱和。
    • 8. 发明申请
    • METHOD FOR DIRECT METHANE PYROLYSIS
    • 直接甲烷热解法
    • WO01070656A1
    • 2001-09-27
    • PCT/RU2000/000375
    • 2000-09-21
    • C07C2/76C10G15/08C10G15/12C07C11/02C07C11/24
    • C10G15/12C07C2/76C10G9/24C10G15/08C10G2400/20C10G2400/24Y02P30/40C07C11/24C07C11/04
    • The invention makes it possible to increase the ethylene content in reaction products during direct conversion of methane. The invention is characterized by the fact that pyrolysed natural gas is pre-heated to 900-1000 K and the conversion process is performed in two steps. In the first step, gas is heated to 1800-2100 K during 1-2 msec, and in the second step the heated mixture of the primary reaction products is conditioned at a pressure ranging from 2 to 5 MPa in an adiabatic state during 5-10 msec. In addition, the reaction products are tempered. Said range of temperatures at the first step of the conversion process is maintained by an outside energy supply. The inventive method makes it possible to perform the direct methane conversion process and obtain an ethylene content of 67.4 % and an acetylene content of 9.1 % in pyrolyzates. The degree of the direct methane conversion is equal to 88.1 %.
    • 本发明可以在甲烷的直接转化期间增加反应产物中的乙烯含量。 本发明的特征在于将热解天然气预热至900-1000K,转化过程分两步进行。 在第一步中,在1-2毫秒内将气体加热至1800-2100K,在第二步骤中,将主反应产物的加热混合物在绝热状态下在2至5MPa的压力下调节, 10毫秒 此外,反应产物被回火。 在转换过程的第一步骤的所述温度范围由外部能量供应来维持。 本发明的方法使得可以进行直接甲烷转化过程,并且在热解物中获得67.4%的乙烯含量和9.1%的乙炔含量。 直接甲烷转化的程度等于88.1%。
    • 9. 发明申请
    • PLASMA TRANSFORMER FOR THE TRANSFORMATION OF FOSSIL FUELS INTO HYDROGEN-RICH GAS
    • 用于将富油燃料转化为富氢气体的等离子体变压器
    • WO01009031A1
    • 2001-02-08
    • PCT/ES2000/000040
    • 2000-02-09
    • C01B3/34H05H1/24C10G15/12
    • C01B3/342H05H1/46H05H2001/4622
    • The invention relates to a device for the production of hydrogen-rich gas from fossil fuels. The device comprises a heater, a mixer and a MCW plasma reactor which are combined in series, as well as an MCW energy source. A pseudo-corona periodical impulse discharge at atmospheric pressure is produced in the reactor and initiates a low temperature plasma-catalytic fuel transformation process. The device enables to carry out the transformation reactions with steam, with steam-air and partial oxidation of fossil fuels for the production of a hydrogen-rich gas with high specific productivity (volumetric ratio) and with a minimum consumption of electric energy. Prior heating of the reagents provides a large part of the energy which is required by thermodynamics. Part of the thermal energy is recovered at the outlet of the plasma reactor. The device can be sufficiently compact in order to be used in internal combustion engines of transport vehicles. The device can be used also in stationary systems for the production of hydrogen-rich gas (power generating plants, etc.). Other fields related with the invention are the construction of microwave plasma equipments (plasma reactors) and the construction of vehicle engines. The present invention relates to the process for converting fossil fuels into hydrogen-rich gas (synthesis gas) through the use of plasma which is generated by microwaves with the addition of oxygen (or air) and with the possibility of water addition.
    • 本发明涉及一种用于从化石燃料生产富氢气体的装置。 该装置包括串联组合的加热器,混合器和MCW等离子体反应器,以及MCW能量源。 在反应器中产生大气压下的伪电晕周期冲击放电,开始低温等离子体催化燃料转化过程。 该装置能够用蒸汽进行转化反应,用蒸汽 - 空气和化石燃料的部分氧化来生产具有高比生产率(体积比)的富氢气体并且以最小的电能消耗。 试剂的先前加热提供了热力学所需的大部分能量。 部分热能在等离子体反应器的出口处被回收。 该装置可以足够紧凑以便用于运输车辆的内燃机。 该装置也可用于固定系统中用于生产富氢气体(发电厂等)。 与本发明有关的其他领域是微波等离子体设备(等离子体反应器)和车辆发动机的建造。 本发明涉及通过使用通过添加氧气(或空气)由微波产生的等离子体并且具有添加水的可能性的方式将化石燃料转化为富氢气体(合成气)的方法。