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    • 2. 发明申请
    • MOULDINGS MADE OF THERMOPLASTIC MOULDING MASSES
    • TRIMS,热塑性模塑料制成
    • WO1997041174A2
    • 1997-11-06
    • PCT/EP1997002099
    • 1997-04-24
    • BASF AKTIENGESELLSCHAFTLINDENSCHMIDT, GerhardROSENAU, BernhardMC KEE, Graham, EdmundFISCHER, Wolfgang
    • BASF AKTIENGESELLSCHAFT
    • C08L00/00
    • C08L25/12C08L51/003C08L51/04C08L2666/24C08L2666/04
    • Mouldings made of thermoplastic moulding masses contain (A) 30 to 99 wt %, relative to the total weight of the moulding mass, of a thermoplastic polymer, comprising, relative to (A): (a1) 50 to 100 wt % of a styrene compound of general formula (I), in which R1 and R2 stand for hydrogen or C1-C8 alkyl, or a (C1-C8-alkyl)ester of acrylic or methacrylic acid, or mixtures of the styrene compound and of the (C1-C8-alkyl)ester of acrylic or methacrylic acid; (a2) 0 to 40 wt % acryl nitrile or methacryl nitrile or their mixtures; and (a3) 0 to 40 wt % of one or several other monoethylenically unsaturated monomers different from (a2); (b) 1 to 70 wt %, with respect to the total weight of the moulding mass, of a graft polymer comprising, relative to (B): (b1) 30 to 90 wt % of a rubber-elastic grafted core made of a polymer with a glass transition temperature below 0 DEG C and obtained by copolymerising (b11) 50 to 99.99 wt %, with respect to (b1), of a (C1-C10-alkyl)ester of acrylic acid; (b12) 0.01 to 10 wt % of a polyfunctional, cross-linking monomer; and (b13) 0 to 40 wt % of one or several others monoethylenically unsaturated monomers different from (b11); and (b2) 10 to 70 wt % of a grafted sheath which contains, relative to (b2): (b21) 50 to 100 wt % of a styrene compound of general formula (I), in which R and R stand for hydrogen or C1-C8-alkyl; or a (C1-C8-alkyl)ester of acrylic acid or methacrylic acid; or mixtures of the styrene compound and of the (C1-C8-alkyl)ester of acrylic or methacrylic acid; (b22) 0 to 40 wt % acryl nitrile or methacryl nitrile or their mixtures; and (b23) 0 to 40 wt % of one or several other monoethylenically unsaturated monomers.
    • A))30至99重量%,基于模塑组合物的总重量计,的热塑性聚合物,基于A A1)50〜100重量通式的苯乙烯化合物的%:从含有热塑性模塑化合物制备的模制品 (I),<1>和R <2>是R代表氢或C1-C8烷基,或(C1-C8烷基)丙烯酸或甲基丙烯酸,或苯乙烯类化合物的混合物和(C1-C8的酯 烷基)丙烯酸或甲基丙烯酸的酯,A2)0〜40重量丙烯腈或甲基丙烯腈或它们的混合物的%和a3)0〜40重量%的一种或多种选自A2其它单烯键式不饱和不同)单体,B的% )1〜70重量%,基于模塑组合物的总重量计,其包括,基于B的接枝聚合物的,),B1)为30〜90重量具有低于0℃的玻璃化转变温度的聚合物的橡胶弹性接枝芯%,可获得由 共聚,基于b 1),B11)50〜99.99重量一(C1-C10烷基的%)丙烯酸的酯,B12)0.01至10重量重量的多官能团的%,交联单体,和B13)0至40 .-的一种或多种其它单烯属不饱和的,从B11)不同的单体,和b2)为10〜70重量的接枝壳的基础上,b2的%),B21)50〜100重量通式的苯乙烯化合物的%% (I),<1>和R <2>是R代表氢或C1-C8烷基,或(C1-C8烷基)丙烯酸或甲基丙烯酸,或苯乙烯类化合物的混合物和(C1-C8的酯 烷基)丙烯酸或甲基丙烯酸的酯,B22)0至40重量丙烯腈或甲基丙烯腈或它们的混合物的%和B23)从0至40重量的一种或多种其它单烯属不饱和单体的%。
    • 6. 发明申请
    • FLUOROCARBON ADDITIVE FOR USE IN PROTECTIVE RESINOUS COMPOSITIONS AND ANTIGRAFFITI PAINTS
    • 用于保护性树脂组合物和抗腐蚀剂的氟代添加剂
    • WO1996011981A2
    • 1996-04-25
    • PCT/US1995012883
    • 1995-10-06
    • A.T.G., INC.
    • A.T.G., INC.MAIER, Bruce, R.VAN DE MARK, Michael
    • C08L00/00
    • C07D251/34C08K5/34924
    • A fluorocarbon additive that may be added to any resinous composition including aqueous and solvent based paints and coatings to improve the soil resistance and stain release characteristics of the composition. The additive is a mixture of discrete non-polymeric oligomers with each oligomer comprising a central core molecule having one or more fluorocarbon chains extending from and bound to the oligomer core by a mainly covalent bond, and having one or more non-fluorinated appendages extending from the core. In a preferred embodiment, the inventive oligomer is comprised of a polyfunctional core molecule having two or more functional groups, wherein a fluorocarbon chain is covalently bound to less than all of the functional groups. Particularly useful polyfunctional core molecules are selected from the group of tri-aziridines, trimers of isocyanates and/or tri-epoxy systems.
    • 可以添加到任何树脂组合物中的氟碳添加剂,包括水性和溶剂型涂料和涂料,以改善组合物的耐污性和脱色特性。 所述添加剂是离散的非聚合低聚物的混合物,其中每个低聚物包含具有一个或多个氟化烃链的中心核心分子,所述碳氟化合物链通过主要共价键从低聚物核心延伸并结合到低聚物核心,并且具有一个或多个非氟化附属物 核心。 在优选的实施方案中,本发明的低聚物由具有两个或更多个官能团的多官能核心分子组成,其中碳氟化合物链与小于所有官能团共价结合。 特别有用的多官能核心分子选自三氮丙啶,异氰酸酯和/或三环氧体系的三聚体。
    • 9. 发明申请
    • ALKANOLYSIS OF POLYETHER POLYOL ESTERS BY REACTIVE DISTILLATION
    • 通过反应性蒸馏分离聚醚多糖酯
    • WO1997023559A2
    • 1997-07-03
    • PCT/US1996019464
    • 1996-12-05
    • E.I. DU PONT DE NEMOURS AND COMPANY
    • E.I. DU PONT DE NEMOURS AND COMPANYDORAI, Suriyanarayan
    • C08L00/00
    • C08G65/20C08G65/3312Y02P20/127
    • A method for converting the diester of a polyether polyol (e.g., the diacetate ester of polytetramethylene ether, PTMEA) to a corresponding dihydroxy polyether polyol (e.g., polytetramethylene ether glycol, PTMEG) involving reactive distillation wherein a diester of polyether polyol is fed to the top portion of the column along with an effective amount of at least one alkali metal oxide or alkaline earth metal oxide, hydroxide or alkoxide catalyst (e.g., sodium methoxide) and with a C1 to C4 alkanol (e.g., methanol) while simultaneously adding to the bottom of the reactive distillation column hot alkanol vapor to sweep any alkanol ester formed by alkanolysis of the diester of polyether polyol upwardly. Such a process is useful for achieving high levels of conversion PTMEA to PTMEG on a commercial scale with the overhead from the column being amenable to azeotropic separation of the methyl acetate and recycle of the methanol.
    • 将聚醚多元醇(例如,聚四亚甲基醚的二乙酸酯,PTMEA)的二酯转化为涉及反应性蒸馏的相应的二羟基聚醚多元醇(例如聚四亚甲基醚二醇,PTMEG)的方法,其中将聚醚多元醇的二酯加入到 塔的顶部以及有效量的至少一种碱金属氧化物或碱土金属氧化物,氢氧化物或醇盐催化剂(例如甲醇钠)和C1-C4链烷醇(例如甲醇),同时加入到 底部的反应蒸馏塔热链烷醇蒸气洗涤通过向上聚醚多元醇的二酯的链烷分解形成的任何链烷醇酯。 这种方法对于实现高水平的商业规模的PTMEA到PTMEG的转化是有用的,其中塔的塔顶馏分适于乙酸甲酯的共沸分离和甲醇的再循环。