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    • 2. 发明申请
    • HYDROCARBON FUEL COMPOSITION CONTAINING AN ESTER
    • 含有ESTER的油料燃料组合物
    • WO0107540A2
    • 2001-02-01
    • PCT/US0019894
    • 2000-07-20
    • EXXON CHEMICAL PATENTS INC
    • SCHLOSBERG RICHARDYEZRIELEV ALBERT I
    • C10L1/02
    • C10L1/023
    • This invention relates to the use of esters with low water solubility as oxygenates in gasoline fuels. This invention relates to a gasoline fuel, comprising an ester and butane, wherein the ester contains 5 to 14 carbon atoms. This invention also relates to using a low water solubility ester as an oxygenate in automotive gasoline used in internal combustion engines. Additionally, the invention provides a gasoline fuel, comprising an ester, wherein the ester has a water solubility of less than about 15,000 mg/L at 20 DEG C, preferably less than about 6,500 mg/L at 20 DEG C and the fuel has an overall water solubility of less than about 5,000 mg/L at 20 DEG C.
    • 本发明涉及在汽油燃料中使用水溶性低的酯作为含氧化合物。 本发明涉及包含酯和丁烷的汽油燃料,其中酯含有5至14个碳原子。 本发明还涉及在内燃机中使用的汽车汽油中使用低水溶性酯作为含氧化合物。 另外,本发明提供了一种包含酯的汽油燃料,其中酯在20℃下的水溶解度小于约15,000mg / L,优选在20℃时小于约6500mg / L,并且燃料具有 总体水溶性在20℃下小于约5,000mg / L
    • 4. 发明申请
    • ELASTOMERIC POLYMER VEHICLE PARTS HAVING IMPROVED LOW-TEMPERATURE COMPRESSION SET
    • 具有改进的低温压缩设备的弹性聚合物车辆部件
    • WO0022015A9
    • 2000-10-12
    • PCT/US9922091
    • 1999-09-23
    • EXXON CHEMICAL PATENTS INC
    • LIOTTA RONRAVISHANKAR PERIAGARAM S
    • C08J5/00C08F4/659C08F10/00C08F210/18C08L23/16F16G5/04F16G5/00
    • F16G5/04C08F4/65908C08F10/00C08F210/18C08L23/16C08F4/65927C08F4/68C08F210/06C08F2500/25C08F2500/17
    • Motor vehicle parts based on an ethylene, alpha-olefin, diene monomer elastomeric polymers exhibit excellent low temperature compression set. Previously, such compression set performance in the amorphous region was believed to be non-responsive to ethylene content once the amorphous region was reached. However, within certain ranges, ethylene content has been shown to have an effect on low temperature compression set even in the amorphous region. These motor vehicle parts are particularly useful where extremes of ambient temperatures maybe incurred. In a preferred embodiment, the invention is a vehicle part, such a brake part or belt including an ethylene, alpha -olefin, diene elastomeric polymer. The elastomeric polymer has a low ethylene content, and the vehicle part made from a compound based on the elastomeric polymer will have improved low temperature compression set. The vehicle part comprises the elastomeric polymer where the polymer has ethylene present in the range of from 50-60 mole percent, ethyldiene norbornene present in the range of from 0.2-5 mole percent and an alpha -olefin, selected from propylene, hexene-1 and octene-1, where the alpha -olefin makes up the remainder of the elastomeric polymer. The ethylene composition distribution of the elastomeric polymer is such that the ethylene in 90 % of the polymer fractions varies by no more than +/- 4 % by weight. The Mw/Mn will be in the range of 2-4, the inherent viscosity in the range of 1.2-3.2 and the Mooney Viscosity (1+4) @ 125 DEG C in the range of from 10-80. The vehicle part will have an instantaneous compression set at -40 DEG C, less than 80 %.
    • 基于乙烯,α-烯烃,二烯单体弹性体聚合物的汽车零件表现出优异的低温压缩变定。 以前,一旦达到无定形区域,认为无定形区域中的这种压缩永久变形性能对乙烯含量无响应。 然而,在一定的范围内,即使在非晶区域,乙烯含量也显示出对低温压缩变定具有影响。 这些机动车辆部件在可能发生极端环境温度的情况下特别有用。 在一个优选的实施方案中,本发明是车辆部件,例如包括乙烯,α-烯烃,二烯弹性体聚合物的制动部件或带。 弹性体聚合物具有低的乙烯含量,并且由基于弹性体聚合物的化合物制成的载体部分将具有改进的低温压缩永久变形。 载体部分包含弹性体聚合物,其中聚合物的乙烯含量为50-60%(摩尔),乙二烯降冰片烯的含量为0.2-5%(摩尔),α-烯烃选自丙烯,己烯-1 和辛烯-1,其中α-烯烃构成弹性体聚合物的剩余部分。 弹性体聚合物的乙烯组成分布使得90%聚合物部分中的乙烯变化不超过+/- 4重量%。 Mw / Mn在2-4的范围内,特性粘度在1.2-3.2范围内,125℃时的门尼粘度(1 + 4)在10-80的范围内。 车辆部件将具有-40℃的瞬时压缩率,小于80%。
    • 7. 发明申请
    • PROCESS FOR SELECTIVELY SEPARATING HYDROGEN, OR BOTH HYDROGEN AND CARBON MONOXIDE FROM OLEFINIC HYDROCARBONS
    • 氢氧化氢,二氧化碳和二氧化碳的选择性分离方法
    • WO1998029368A1
    • 1998-07-09
    • PCT/US1997023875
    • 1997-12-31
    • EXXON CHEMICAL PATENTS INC.
    • EXXON CHEMICAL PATENTS INC.VAUGHN, Stephen, N.OU, John, D.DANIEL, Lawrence, G.
    • C07C07/148
    • B01D53/8671B01D53/864B01D53/869B01D2257/108B01D2257/504C07C7/14816Y02P20/152C07C11/00
    • A process for the separation, and removal, of hydrogen, or both hydrogen and carbon monoxide, from a mixture of these gases with olefinic hydrocarbons. In one embodiment, a mixture constituted of hydrogen and one or more reactive unsaturated hydrocarbons is contacted with oxygen or an oxygen-containing gas, over a catalyst at reaction conditions sufficient to oxidize the hydrogen component of the mixture to form water, while suppressing reaction of the reactive unsaturated hydrocarbon. In a second embodiment, there is included a two-reaction-zone series wherein effluent from the first reaction zone, wherein the mixture includes hydrogen, carbon monoxide and at least one reactive unsaturated hydrocarbon, is contacted with oxygen or an oxygen-containing gas, and reacted over an oxidation catalyst at conditions sufficient to oxidize the carbon monoxide component of the mixture to form carbon dioxide and suppress hydrogenation of the reactive unsaturated hydrocarbons. In a third embodiment, there is included a three-reaction-zone series wherein effluent from the second reaction zone, wherein the mixture includes carbon monoxide, water, and at least one reactive unsaturated hydrocarbon, is reacted over a water-gas-shift and hydrogenation catalyst at conditions sufficient to react carbon monoxide component of the mixture to form carbon dioxide and hydrogen, and hydrogenate said reactive unsaturated hydrocarbon with the resulting hydrogen. In each embodiment, reactive unsaturated hydrocarbons denuded of hydrogen, or both hydrogen and carbon monoxide are recovered.
    • 从这些气体与烯烃的混合物中分离和除去氢气或氢气和一氧化碳两者的方法。 在一个实施方案中,将由氢和一种或多种反应性不饱和烃组成的混合物与氧气或含氧气体在催化剂上接触,反应条件足以氧化混合物的氢组分以形成水,同时抑制 反应性不饱和烃。 在第二实施方案中,包括双反应区系列,其中来自第一反应区的流出物,其中混合物包括氢气,一氧化碳和至少一种反应性不饱和烃与氧气或含氧气体接触, 并在足以氧化混合物的一氧化碳组分以形成二氧化碳并抑制反应性不饱和烃氢化的条件下在氧化催化剂上反应。 在第三实施方案中,包括三反应区系列,其中来自第二反应区的流出物,其中混合物包括一氧化碳,水和至少一种反应性不饱和烃,通过水煤气变换和 氢化催化剂在足以使混合物的一氧化碳组分反应形成二氧化碳和氢气的条件下,并将所述反应性不饱和烃与所得氢气氢化。 在每个实施方案中,回收了被解释为氢或氢和一氧化碳的反应性不饱和烃。