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    • 5. 发明申请
    • FLAME RETARDANTS
    • 阻燃剂
    • WO1994011425A1
    • 1994-05-26
    • PCT/US1993010606
    • 1993-11-05
    • MINNESOTA MINING AND MANUFACTURING COMPANY
    • MINNESOTA MINING AND MANUFACTURING COMPANYPARSONS, Keith, P.LINDSAY, Alan
    • C08K03/32
    • C08K3/32C08F8/40C08F8/44C08L63/00C08L23/02
    • A non-halogen containing flame-retardant additive comprising a salt of an inorganic phosphorus-containing acid and a polymeric compound which is a homopolymer or copolymer and comprises a linear backbone formed of at least 10 repeat units and contains a plurality of basic nitrogen functionalities. The additives are suitable for use in polymer materials either alone or in combination with other flame-retardant additives, resulting in an additive having reduced smoke generation, reduced evolution of corrosive gases and improved flame-retarding properties. The flame-retardant additives of the invention are compatible with a variety of thermoplastic and thermoset polymers applicable for wire and cable insulation, heat recoverable items, electrical tape and moulded parts. The additives may also be formulated as a dispersion into coating compositions optionally comprising additional ingredients such as other flame-retardants, fillers, colourants etc. In addition the additives may be employed in caulks, mastics and sealants.
    • 一种不含卤素的阻燃添加剂,其包含无机含磷酸的盐和作为均聚物或共聚物的聚合物,并且包含由至少10个重复单元形成并含有多个碱性氮官能团的直链骨架。 添加剂可单独使用或与其它阻燃添加剂组合使用,从而产生具有减少烟雾产生,减少腐蚀性气体逸出和改善阻燃性能的添加剂。 本发明的阻燃添加剂与适用于电线和电缆绝缘的各种热塑性和热固性聚合物,可热回收物品,电气带和模制部件相容。 添加剂也可以配制成涂料组合物中的分散体,任选地包含另外的成分例如其它阻燃剂,填料,着色剂等。此外,添加剂可以用于填缝剂,胶粘剂和密封剂。
    • 9. 发明申请
    • A PROCESS FOR THE MANUFACTURE OF POLYMERIC MATERIALS WITH A HIGH CHEMICAL AND MECHANICAL RESISTANCE AND POLYMERIC MATERIALS WITH A HIGH CHEMICAL AND MECHANICAL RESISTANCE
    • 具有高化学和机械电阻的高分子材料和具有高化学和机械电阻的聚合材料的制备方法
    • WO1995028440A1
    • 1995-10-26
    • PCT/PL1995000005
    • 1995-03-15
    • CYRKIEWICZ, MarceliHERLING, ErwinKLESZCZEWSKI, JacekKLESZCZEWSKI, Jacek
    • C08K03/32
    • C08K3/32C08L67/06
    • The process for the manufacture of materials with a high chemical and mechanical resistance consists in that per each 100 parts by volume of vinylester resin treated with 0.85-1.47 parts by volume of an accelerant in the form of cobalt naphthenate, there are added at least in two batches 50-900 parts by volume of an inorganic filler constituting previously roasted at a temperature not lower than 470 K disintegrated to a particle size of at least 30 mu m phosphogypsum or a composition of phosphogypsum with glass-forming oxides or phosphogypsum with magnetite or phosphogypsum with microsphere, after which on continuous stirring there is added, if necessary, up to 60 parts by volume of styrene and/or up to 0.2 parts by volume of dimethylaniline, and then the whole is polymerized in the presence of known initiators such as organic peroxides. The materials with a high chemical and mechanical resistance constitute polymerized composition of synthetic resin and inorganic fillers, consisting of 7.5-88.1 % by weight of vinylester resin, styrene and/or a low-molecular-weight unsaturated polyester resin in a quantity up to 34.1 % by weight, and 14.3-86.6 % by weight of phosphogypsum or 0.4-46.6 % by weight of phosphogypsum and 6.4-44.8 % by weight of glass-forming oxides or 4.6-53.5 % by weight of microsphere or 5.5-42.1 % by weight of magnetite. The process for the manufacture of these materials makes it possible to utilize industrial wastes resulted from production of phosphoric acid, while the material itself in all its varieties is characterized by a very good resistance to aggresive media, also at elevated temperatures, and suitable for processing by mechanical methods as well as for combining with other materials by using to that end an incompletely polymerized composition of the material.
    • 用于制造具有高化学和机械阻力的材料的方法在于每100体积份用0.85-1.47体积份的环烷酸钴形式的促进剂处理的乙烯基酯树脂,至少加入 两批50-900份体积的预先在不低于470K的温度下焙烧的无机填料分散至至少30μm磷石膏的粒径或具有玻璃形成氧化物或磷石膏的磷石膏组合物或磁铁矿,或 磷石膏与微球,然后在连续搅拌下加入高达60体积份苯乙烯和/或最多0.2体积份二甲基苯胺,然后在已知的引发剂如 有机过氧化物。 具有高化学和机械阻力的材料构成合成树脂和无机填料的聚合组合物,由7.5-88.1重量%的乙烯基酯树脂,苯乙烯和/或低至34.1的量的低分子量不饱和聚酯树脂组成 ,磷石膏的重量百分比为14.3-86.6%,磷石膏为0.4-46.6重量%,玻璃形成氧化物为6.4-44.8重量%,微球为4.6-5.35重量%,重量为5.5-42.1重量% 的磁铁矿。 制造这些材料的过程使得可以利用由磷酸生产产生的工业废物,而其所有品种的材料本身的特征在于在高温下也具有非常好的抗侵蚀性介质,并且适用于加工 通过机械方法以及通过使用该材料的不完全聚合的组合物与其它材料结合。