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1. 发明申请

WO2018134221A1 COMPOSITION HAVING A MUGUET ODOR 审中-公开
公开(公告)号：WO2018134221A1
公开(公告)日：2018-07-26
申请号：PCT/EP2018/051058
申请日：2018-01-17
申请人： FIRMENICH SA
发明人： SAUDAN, Lionel , SANTORO, Francesco , WALTHER, Eric
IPC分类号： C11B9/00 , C07C45/50 , C07C33/30 , C07C47/27
摘要： The present invention relates to a composition of matter comprising a) at least one compound of formula (I) in the form of any one of its isomers or a mixture thereof; wherein R 1 represents a hydrogen atom or a C 1-2 alkyl group; and R represents a group of formula – CH 2 C(Me) 2 OH; said R being, relative to position 1, a meta, a para substituent of the aromatic ring or a mixture thereof; and b) at least one compound of formula (II) in the form of any one of its isomers or a mixture thereof; wherein R 1 and R have the same meaning as defined in formula (I); said R being, relative to position 1, an ortho, a meta, a para substituent of the aromatic ring or a mixture thereof; their uses as perfuming ingredients as well as the composition and consumer product including such a composition of matter and the process to prepare it.

2. 发明申请

WO2017114058A1 一种制备光学活性羰基化合物的方法审中-公开
公开(公告)号：WO2017114058A1
公开(公告)日：2017-07-06
申请号：PCT/CN2016/107590
申请日：2016-11-29
申请人：浙江新和成股份有限公司 , 山东新和成药业有限公司 , 浙江大学
发明人：周有桂 , 于明 , 袁金桃 , 赵雷 , 朱先冬 , 余光雄 , 苏伟伟 , 邵卫康 , 石兴兴 , 张印 , 丰明 , 陈志荣 , 李浩然 , 张玉红
IPC分类号： C07C45/62 , C07C47/21 , C07C47/27 , C07C49/21 , C07C201/12 , C07C205/44 , C07C67/303 , C07C69/73 , C07D333/22 , C07B53/00 , C07D307/46 , B01J31/02
CPC分类号： C07B53/00 , B01J23/462 , B01J23/464 , B01J23/468 , B01J31/02 , B01J31/0237 , C07C45/62 , C07C47/21 , C07C47/225 , C07C47/232 , C07C49/21 , C07C49/217 , C07C67/303 , C07C201/12 , C07C2601/08 , C07C2601/14 , C07C2602/10 , C07D307/46 , C07D333/22 , Y02P20/584 , C07C205/44 , C07C47/02 , C07C47/19 , C07C47/198 , C07C47/23 , C07C69/716 , C07C47/24 , C07C49/403 , C07C47/277 , C07C49/175 , C07C49/213 , C07C49/215 , C07C49/427
摘要：本发明公开了一种制备光学活性羰基化合物的方法，包括以下步骤：在手性胺盐和过渡金属催化剂的催化下，以氢气和催化量的二氢吡啶化合物为氢源，α，β-不饱和醛或α，β-不饱和酮化合物进行不对称催化氢化反应，得到所述的光学活性羰基化合物。该方法反应条件温和，操作简单，二氢吡啶化合物的用量为催化量，使得目标产物易于从反应体系中分离纯化，同时，金属催化剂可以实现回收套用，符合经济性要求。

3. 发明申请

WO2019141761A1 LILY OF THE VALLEY ODORANT 审中-公开
公开(公告)号：WO2019141761A1
公开(公告)日：2019-07-25
申请号：PCT/EP2019/051112
申请日：2019-01-17
申请人： FIRMENICH SA
发明人： COULOMB, Julien , ODDON, Gilles
IPC分类号： C11B9/00 , C07C47/267 , C07C47/27
摘要： The present invention concerns the use as perfuming ingredient of a compound of formula (I) in the form of any one of its stereoisomers or a mixture thereof, and wherein X represents a CHO group when R 1 represents a C 1-2 alkyl group or X represents a CH(R 6 )CHO group when R 1 represents a hydrogen atom or a C 1-2 alkyl group; each R 2 , R 3 , R 4 , R 5 and R 6 represents, independently from each other, a hydrogen atom or a C 1-2 alkyl group; or R 3 and R 4 represent, when taken together, a ethanediyl group; and -C(R 3 )(R 4 )-CH(R 5 )-OH group is, relative to position 1, an ortho, a meta, a para substituent of the aromatic ring or a mixture thereof. Moreover, the compound of formula (I) as part of a perfuming composition or of a perfumed consumer product is also part of the present invention.

4. 发明申请

WO00031015A1 METHOD OF MODIFYING COMPONENTS PRESENT IN CASHEW NUT SHELL LIQUID 审中-公开
标题翻译： CASHEW NUT SHELL LIQUID中的组分修饰方法
公开(公告)号：WO00031015A1
公开(公告)日：2000-06-02
申请号：PCT/GB1999/003913
申请日：1999-11-25
IPC分类号： C07C45/40 , C07C51/373 , C07C65/30 , C08G8/04 , C08G8/24 , C08L61/06 , C09J161/06 , C07C47/27 , C07C47/02 , C09J191/00
CPC分类号： C09J161/06 , C07C45/40 , C07C51/373 , C07C65/30 , C08G8/04 , C08G8/24 , C08L61/06
摘要： The invention provides a process for modifying CNSL comprising subjecting the CNSL to ozonolysis to form ozonolysis reaction products followed by reduction of the ozonolysis reaction products to give a mixture of phenolic components and aldehydes. In a preferred embodiment, the invention provides a process for modifying CNSL which comprises the steps of first reacting CNSL with ozone to form a mixture containing ozonolysis reaction products, and secondly treating the mixture under reducing conditions to form a further mixture containing phenolic components with an eight carbon chain having a terminal CHO group and alkyl components of varying lengths with either one or two terminal CHO groups. The resulting CNSL aldehydes can be used to form adhesives for use in the manufacture of composites such as wood particle board.
摘要翻译：本发明提供了一种改性CNSL的方法，包括使CNSL进行臭氧分解以形成臭氧分解反应产物，随后还原臭氧分解反应产物，得到酚类组分和醛的混合物。在优选的实施方案中，本发明提供了一种修饰CNSL的方法，其包括首先使CNSL与臭氧反应形成含有臭氧分解反应产物的混合物的步骤，其次在还原条件下处理该混合物以形成含有酚类组分的另外的混合物，具有末端CHO基团的八个碳链和具有一个或两个末端CHO基团的不同长度的烷基组分。所得到的CNSL醛可用于形成用于制造复合材料如木材刨花板的粘合剂。

5. 发明申请

WO2022073115A1 SUBSTITUTED AROMATIC COMPOUNDS AND PHARMACEUTICAL COMPOSITIONS THEREOF 审中-公开
公开(公告)号：WO2022073115A1
公开(公告)日：2022-04-14
申请号：PCT/CA2021/051395
申请日：2021-10-05
申请人： BIOPHARMACEUTIQUES INGENEW INC.
发明人： GAGNON, Lyne
IPC分类号： C07C33/22 , A61K31/045 , A61K31/05 , A61K31/075 , A61K31/11 , A61K31/12 , A61K31/136 , A61K31/165 , A61K31/216 , A61P35/00 , C07C215/68 , C07C235/34 , C07C39/11 , C07C43/178 , C07C47/27 , C07C49/245 , C07C69/732
摘要： Compounds of Formula I or II, methods of preparation and of use thereof. Formula I has a core aromatic group with substituents as follows: Formula (I) wherein G1 is -(CH2)nC(R1)(R2)OH, -(CH2)n-CHO, -(CH2)nC(O)NR1R2, -(CH2)nCH (R1)NR1R2, -(CH2)nC(O)OR3, -(CH2)n-CH(R1)O-R3, or -(CH2)nC(O)R3; G2 and G4 are independently H, OH, F, or Cl, where G2 can also be NH2; G3 and G5 are independently H, F, Cl, OH, -(CH2)n-optionally substituted heterocycle,-(CH2)n-optionally substituted phenyl, -(CH2)nC3H5, optionally substituted C1-C6 alkyl, optionally substituted C2-C6 alkenyl, -C(O)-R3, or CH(OH)-R3; and G6 is H, F, Cl, OH, -(CH2)n-optionally substituted heterocycle, -(CH2)n-optionally substituted phenyl, or (CH2)nCOOH, wherein • n is an integer selected from 0 to 5, • R1 and R2 are independently selected from H and optionally substituted C1-C6 alkyl group, and • R3 is an optionally substituted C1-C6 alkyl group or when present on G1 forms a lactone with the core aromatic group, or a pharmaceutically acceptable salt thereof.

6. 发明申请

WO2021032590A1 NEW BED MATERIAL FOR THERMOLYTIC FRAGMENTATION OF SUGARS 审中-公开
公开(公告)号：WO2021032590A1
公开(公告)日：2021-02-25
申请号：PCT/EP2020/072756
申请日：2020-08-13
申请人： HALDOR TOPSØE A/S
发明人： OSMUNDSEN, Christian Mårup , TAARNING, Esben , LARSEN, Morten Boberg
IPC分类号： C07C45/60 , C07C47/19 , C07C47/04 , C07C47/27 , C07C49/17 , C07C49/185
摘要： The present invention relates to a process for thermolytic fragmentation of a sugar into a composition comprising C1-C3 oxygenates. In particular, it relates to the use of heat carrying particles providing improved yields of C1-C3 oxygenates and improved fluidization characteristics making it suitable for industrial scale production of e.g. glycolaldehyde. It also regards a circulating fluidized bed system comprising the heat carrying particles.

7. 发明申请

WO2018066005A1 NOVEL COMPOUNDS AND PROCESS FOR PREPARARTION OF THE SAME FROM CASHEW NUT SHELL LIQUID (CNSL) 审中-公开
标题翻译： CASHEW坚果壳液体（CNSL）制备新化合物及其制备方法
公开(公告)号：WO2018066005A1
公开(公告)日：2018-04-12
申请号：PCT/IN2017/050454
申请日：2017-10-06
申请人： COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH
发明人： CHIKKALI, Samir Hujur , PANDEY, Swechchha
IPC分类号： C07C37/00 , C07C45/50 , C07C47/27 , C07C47/277 , C07C39/06
摘要： The present invention relates to isomerizing hydroformylation of plant oils to feedstock chemicals and monomers. More particularly, the present invention relates to compound of formula (I) and process for preparation thereof using isomerizing functionalization of cashew nut shell liquid (CNSL).
摘要翻译：本发明涉及将植物油加氢甲酰化异构化为原料化学品和单体。更具体地说，本发明涉及式（I）化合物及其使用腰果壳油（CNSL）的异构化官能化制备其的方法。

8. 发明申请

WO2018066005A9 NOVEL COMPOUNDS AND PROCESS FOR PREPARARTION OF THE SAME FROM CASHEW NUT SHELL LIQUID (CNSL) 审中-公开
公开(公告)号：WO2018066005A9
公开(公告)日：2018-04-12
申请号：PCT/IN2017/050454
申请日：2017-10-06
申请人： COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH
发明人： CHIKKALI, Samir Hujur , PANDEY, Swechchha
IPC分类号： C07C37/00 , C07C45/50 , C07C47/27 , C07C47/277 , C07C39/06
摘要： The present invention relates to isomerizing hydroformylation of plant oils to feedstock chemicals and monomers. More particularly, the present invention relates to compound of formula (I) and process for preparation thereof using isomerizing functionalization of cashew nut shell liquid (CNSL).

9. 发明申请

WO2017009175A1 COMPOUND HAVING A MUGUET ODOR 审中-公开
标题翻译：具有多种气味的化合物
公开(公告)号：WO2017009175A1
公开(公告)日：2017-01-19
申请号：PCT/EP2016/066142
申请日：2016-07-07
申请人： FIRMENICH SA
发明人： COULOMB, Julien
IPC分类号： C11B9/00 , A61Q13/00 , C07C47/27 , C11D3/50
CPC分类号： C11B9/0061 , A61Q13/00 , C07C47/225 , C07C47/27 , C11D3/50
摘要： The present invention relates to phenylpropanal derivatives of formula (I) in the form of any one of its stereoisomers or a mixture thereof, and wherein the dotted line represents a carbon-carbon single or double bond; X represents a CN or CHO group; each R 1 , R 2 and R 3 independently from each other, represents a hydrogen atom or a C 1-2 alkyl group; and R represents a group of formula -[CH 2 ] n C(Me) 2 OH, wherein n is 1 or 2; said R being a meta or para substituent of the aromatic ring, relative position 1; and their uses as perfuming ingredients as well as the composition and consumer product including such derivatives.
摘要翻译：本发明涉及其立体异构体或其混合物中任何一种形式的式（I）的苯基丙醛衍生物，其中虚线表示碳 - 碳单键或双键; X表示CN或CHO基团; 每个R 1，R 2和R 3彼此独立地表示氢原子或C 1-2烷基; 并且R表示式 - [CH 2] n C（Me）2 OH的基团，其中n为1或2; 所述R是芳环的间位或对位取代基，相对位置1; 及其作为加香成分的用途以及包含这些衍生物的组合物和消费品。

10. 发明申请

WO01087813A1 PROCESS FOR PRODUCING CINNAMYLALDEHYDE DERIVATIVES, USE THEREOF AND THE LIKE 审中-公开
标题翻译：生产甲基戊二酸衍生物的方法及其用途
公开(公告)号：WO01087813A1
公开(公告)日：2001-11-22
申请号：PCT/JP2001/003545
申请日：2001-04-24
IPC分类号： A23L27/30 , C07C45/62 , C07C45/73 , C07C45/74 , C07C47/277 , C07K5/072 , C07K5/075 , C07C47/27 , C07K1/02
CPC分类号： C07C45/62 , C07C45/73 , C07C45/74 , C07C47/277 , C07K5/06113 , C07C47/27
摘要： An industrial process for conveniently and efficiently producing highly pure cinnamylaldehyde derivatives such as (2E)-(3-hydroxy-4-methoxy)cinnamylaldehyde which comprises reacting a benzaldehyde derivative (for example, isovanillin) with acetaldehyde in the presence of an alkali, preferably dropping acetaldehyde in portions in an aqueous solution at a low temperature. The cinnamylaldehyde derivatives thus obtained are selectively reduced into 3-(3-hydroxy-4-substituted(methoxy, etc.)phenyl)propionaldehydes. These compounds are further subjected to reductive alkylation with aspartame. Thus N-[N-[3-(3-hydroxy-4-substituted(methoxy, etc.)phenyl)propyl]-L- alpha -aspartyl]-L-phenylalanine 1-methyl esters, which are useful as sweeteners with high sweetness, can be efficiently produced. These processes are also provided.
摘要翻译：方便和有效地生产高纯度肉桂醛衍生物如（2E） - （3-羟基-4-甲氧基）肉桂醛的工业方法，其包括在碱存在下使苯甲醛衍生物（例如异喹啉腈）与乙醛反应在低温下在水溶液中部分滴加乙醛。由此得到的肉桂醛衍生物选择性还原为3-（3-羟基-4-取代的（甲氧基等）苯基）丙醛。这些化合物进一步用阿斯巴甜进行还原烷基化。因此，可用作高甜度甜味剂的N- [N- [3-（3-羟基-4-取代的（甲氧基等）苯基）丙基] -L-α-天冬氨酰基] -L-苯丙氨酸1-甲基酯甜蜜，可以有效地生产。还提供了这些过程。

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