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    • 9. 发明申请
    • NEW PROCESS FOR SYNTHESIS OF 2,3,3,3-TETRAFLUOROPROPENE (1234YF) AND 2,3-DICHLORO-1,1,1-TRIFLUOROPROPANE (243DB)
    • WO2021093029A1
    • 2021-05-20
    • PCT/CN2019/121443
    • 2019-11-28
    • FUJIAN YONGJING TECHNOLOGY CO., LTD
    • CUI, WeilongZHOU, ChangyueWANG, Yong
    • C07C17/25C07C21/18C07C17/07C07C19/10
    • A novel process of manufacturing the compound 2,3,3,3-tetrafluoropropene (1234yf) is provided. The compound 1234yf is the newest refrigerant with zero OPD (Ozone Depleting Potential) and zero GWP (Global Warming Potential). Thus, a process involving a carbene genereation route, for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf), of the compound 243db (2,3-dichloro-1,1,1-trifluoropropane), and optionally of the compound 2-chloro-1,1,1-trifluoropropene (1233xf) via carbene route and compound 243db (2,3-dichloro-1,1,1-trifluoropropane) is provided. A process for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf), wherein the compound 243db (2,3-dichloro-1,1,1-trifluoropropane) serves as a starting material, for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf) is shown. Further, a process for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf), and of the compound 243db (2,3-dichloro-1,1,1-trifluoropropane), wherein the initial starting materials are selected from the group consisting of compound 123 (2,2-dichloro-1,1,1-trifluoroethane), compound 124 (2-chloro-1,1,1,2-tetrafluoroethane), and compound 125 (pentafluoroethane) is provided. The compound 123 (2, 2-dichloro-1,1,1-trifluoroethane) is preferred as the initial starting material. In particular, the process involves a carbene generation step, and wherein the carbene formed is further reacted towards the targeted compounds, especially towards the compound 243db (2,3-dichloro-1,1,1-trifluoropropane), and finally towards the compound 2,3,3,3-tetrafluoropropene (1234yf).