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1. 发明申请

WO2023036857A1 PROCESS FOR THE PRODUCTION OF HYDROGEN THROUGH ELECTRIFICATION OF WATER GAS SHIFT REACTION 审中-公开
公开(公告)号：WO2023036857A1
公开(公告)日：2023-03-16
申请号：PCT/EP2022/074934
申请日：2022-09-08
申请人： TOTALENERGIES ONETECH
发明人： NESTERENKO, Nikolai , VERYASOV, Gleb
IPC分类号： C01B3/12 , C01B7/09 , C25B1/02 , C25B1/24 , C25B1/04 , C25B9/21 , C25B15/08
摘要： The present invention relates to a process and a system for the production of hydrogen and carbon dioxide starting from a feed stream comprising carbon monoxide, which is reacted with water and a halogen reactant. The process in particular comprises the steps of: a) reacting in a first reaction zone a feed stream comprising carbon monoxide (CO) with water (H2O) and bromine (Br2) under reaction conditions effective to produce a gaseous CO2-containing effluent stream and an aqueous solution of hydrogen bromide (HBr); and, b) supplying said aqueous solution of hydrogen bromide (HBr) to a second reaction zone and decomposing said hydrogen bromide (HBr) under conditions effective to produce a gaseous H2-rich stream and a stream comprising bromine (Br2), wherein said hydrogen bromide is decomposed in step b) by means of electrolysis.

2. 发明申请

WO2022213053A1 METHOD OF PRODUCING A HYDROGEN-ENRICHED PRODUCT AND RECOVERING CO2 IN A HYDROGEN PRODUCTION PROCESS UNIT 审中-公开
公开(公告)号：WO2022213053A1
公开(公告)日：2022-10-06
申请号：PCT/US2022/071385
申请日：2022-03-28
申请人： UOP LLC
发明人： CRUZ, Addison , RUSSELL, Bradley , BENNETT III, Erick J. , KRAUS, Kurt , BIETTO, Stefano , CADY, William , CUELLAR, Kyle , KAYODE, Oluwaseyi
IPC分类号： C01B3/34 , C01B3/56 , C01B3/12 , B01D2256/16 , B01D2256/22 , B01D2257/102 , B01D2257/108 , B01D2257/11 , B01D2257/502 , B01D2257/504 , B01D2257/7025 , B01D2257/80 , B01D2259/40015 , B01D2259/4003 , B01D2259/40043 , B01D2259/40079 , B01D2259/40081 , B01D2259/402 , B01D3/143 , B01D53/0438 , B01D53/047 , B01D53/26 , C01B2203/0233 , C01B2203/0261 , C01B2203/0283 , C01B2203/042 , C01B2203/0833 , C01B2203/1241 , C01B2203/1288 , C01B2203/148 , C01B2203/1628 , C01B3/382 , C01B3/386 , C01B3/48 , C01B3/508 , C01B32/50
摘要： A process and apparatus for producing a hydrogen-enriched product and recovering CO2 from an effluent stream from a hydrogen production process unit are described. The process utilizes a CO2 recovery system integrated with a PSA system that produces at least two product streams to recover additional hydrogen and CO2 from the tail gas stream of a hydrogen PSA unit in the hydrogen production process.

3. 发明申请

WO2020044286A1 METHOD AND SYSTEM FOR SYNTHESIZING METHANOL 审中-公开
公开(公告)号：WO2020044286A1
公开(公告)日：2020-03-05
申请号：PCT/IB2019/057295
申请日：2019-08-29
申请人： SABIC GLOBAL TECHNOLOGIES B.V.
发明人： PANT, Atul
IPC分类号： C07C31/04 , C01B3/00 , C01B3/12 , C07C29/151
摘要： A method and system (10, 80, 90) for synthesizing methanol from a syngas feed gas source comprising hydrogen gas (H 2 ) and carbon oxides of CO and CO 2 utilizes a hydrogen recovery unit (52) for producing a hydrogen-rich stream (58) that is recycled to the methanol reactor (18) in combination with water gas shift treatments located either upstream and downstream from the reactor.

4. 发明申请

WO2019161776A1 一种燃料化学链制氢系统和方法审中-公开
公开(公告)号：WO2019161776A1
公开(公告)日：2019-08-29
申请号：PCT/CN2019/075792
申请日：2019-02-22
申请人：北京联力源科技有限公司
发明人：苏庆泉
IPC分类号： C01B3/16 , C01B3/12
摘要：提供一种燃料化学链制氢系统和方法。该系统包括两个完全相同的化学链燃烧反应器(10, 20)，该反应器包括外管(11)和内管(12)，内管充填有第一载氧体(13)，内外之间的夹层充填有第二载氧体或催化燃烧催化剂(14)；内管上端连接有水蒸气导入管道(41)和燃料导入管道(42)，内管下端连接有气体导出管道，气体导出管道通过第3三通阀(53)与氢气导出管道(43)和还原反应产物气体连通管道(44)连接，还原反应产物气体连通管道的另一端与夹层下端连接；夹层上端连接有燃烧烟气的导出管道(46)，夹层下端连接有助燃空气导入管道(45)；两个反应器的水蒸气导入管道通过第1三通阀(51)相连接，燃料导入管道通过第2三通阀(52)相连接，助燃空气导入管道通过第5三通阀(55)相连接。当第一反应器(10)进行氧化反应时，第二反应器(20)进行还原反应。该系统简单、反应器紧凑且易于小型化，可高效率地从气态或者液态燃料制取。

5. 发明申请

WO2019074431A1 PROCESS AND APPARATUS FOR HYDROTREATMENT OF PYROLYSIS OIL 审中-公开
公开(公告)号：WO2019074431A1
公开(公告)日：2019-04-18
申请号：PCT/SE2018/051032
申请日：2018-10-08
申请人： CORTUS AB
发明人： LJUNGGREN, Rolf
IPC分类号： C10B53/02 , C01B3/12 , C01B3/50 , C10G45/00
摘要： An apparatus and process are disclosed for producing hydrocarbons from biomass, the apparatus comprising: a pyrolysis reactor (2) in which dry biomass (Bd) is heated in an environment substantially free from oxygen and halogens, wherein a pyrolysis product (PP) and char (C) is produced; a gasification reactor (3) in which the separated char (C) is heated in an environment containing steam (Wst) so as to reduce said char (C) to produce a synthesis gas (Sh), a gas cooler (4) in which the produced synthesis gas (Sh) is cooled to a cooled synthesis gas (Srt); a conditioning and pressure system (5), in which the cooled synthesis gas (Srt) is refined so as to produce a purified synthesis gas (Sp); a separation device (6), in which hydrogen gas (H2) is separated from the purified synthesis gas (Sp).The apparatus also comprises a hydrogenation device (7), into which pyrolysis oil (PO) retrieved from the pyrolysis product (PP), and at least a portion of the separated hydrogen gas (H2) recuperated from the separation device (6) are introduced for a hydrogenation step, in which the pyrolysis oil (PO) is hydrogenated by the presence of the hydrogen gas (H2), wherein hydrocarbons (BO) that are substantially free from oxygen are produced.

6. 发明申请

WO2016145023A1 CHROMIUM-FREE WATER-GAS SHIFT CATALYST AND PROCESS FOR MAKING THE SAME 审中-公开
标题翻译：无铬水气转换催化剂及其制备方法
公开(公告)号：WO2016145023A1
公开(公告)日：2016-09-15
申请号：PCT/US2016/021473
申请日：2016-03-09
申请人： PH MATTER, LLC
发明人： HOLT, Christopher , MATTER, Paul , BEACHY, Michael
IPC分类号： C01B3/12 , C01B3/16
CPC分类号： B01J23/745 , B01J21/04 , B01J23/002 , B01J35/1014 , B01J35/1019 , B01J37/03 , B01J37/088 , B01J2523/00 , C01B3/16 , C01B2203/0283 , C01B2203/1047 , Y02P20/52 , B01J2523/17 , B01J2523/305 , B01J2523/31 , B01J2523/842
摘要： A chromium-free water-gas shift catalyst. In contrast to industry standard water-gas catalysts including chromium, a chromium-free water-gas shift catalyst is prepared using iron, boron, copper, aluminum and mixtures thereof. The improved catalyst provides enhanced thermal stability and avoidance of potentially dangerous chromium. Various embodiment's of a chromium-free water-gas catalyst including iron and boron are disclosed, some of which include copper, or aluminum and copper. The boron may reside substantially at the surface of the catalyst. In another series of embodiment's, a chromium-free water-gas catalyst may include boron and copper, and these embodiment's may further include aluminum or iron.
摘要翻译：无铬水煤气变换催化剂。与包括铬在内的工业标准水煤气催化剂相反，使用铁，硼，铜，铝及其混合物制备无铬水煤气变换催化剂。改进的催化剂提供增强的热稳定性和避免潜在的危险的铬。公开了包括铁和硼的无铬水煤气催化剂的各种实施方案，其中一些包括铜或铝和铜。硼可以基本上位于催化剂的表面。在另一系列实施方案中，无铬水煤气催化剂可包括硼和铜，并且这些实施方案还可包括铝或铁。

7. 发明申请

WO2013024141A3 CALCIUM SORBENT DOPING PROCESS 审中-公开
标题翻译：钙吸收剂掺杂法
公开(公告)号：WO2013024141A3
公开(公告)日：2013-05-02
申请号：PCT/EP2012066046
申请日：2012-08-16
申请人： IMP INNOVATIONS LTD , FENNELL PAUL , AL-JEBOORI MOHAMAD
发明人： FENNELL PAUL , AL-JEBOORI MOHAMAD
IPC分类号： B01J20/04 , B01J20/02 , B01J20/32 , B01J20/34 , C01B3/12 , C01B3/34
CPC分类号： B01J20/041 , B01J20/027 , B01J20/043 , B01J20/3204 , B01J20/3234 , B01J20/3433 , C01B3/12 , C01B3/38 , C01B2203/0233 , C01B2203/0283 , C01B2203/0425 , C01B2203/0475 , C01B2203/1058 , C01B2203/1241 , Y02C10/08 , Y02P20/134 , Y02P30/30
摘要： The invention relates to a method of increasing the CO2 carrying capacity of a CaO-based sorbent, the method comprising doping a sorbent with the mineral acid HBr or other Br- containing salt, methods of reacting CaO with CO2 at high temperature comprising the use of HBr-doped CaO-based sorbents and applications of the methods including CO2 capture, sorbent-enhanced water gas shift reactions and storage of heat in the form of chemical energy.
摘要翻译：本发明涉及提高CaO基吸收剂的CO 2承载能力的方法，所述方法包括用无机酸HBr或其它含Br盐掺杂吸附剂，在高温下使CaO与CO 2反应的方法，包括使用 HBr掺杂的CaO基吸附剂和包括CO2捕集，吸附剂增强的水煤气变换反应和化学能量形式的热储存在内的方法的应用。

8. 发明申请

WO2013010258A1 USE OF CHAR PARTICLES IN THE PRODUCTION OF SYNTHESIS GAS AND IN HYDROCARBON REFORMING 审中-公开
标题翻译：在生产合成气和油气改造中使用颗粒
公开(公告)号：WO2013010258A1
公开(公告)日：2013-01-24
申请号：PCT/CA2012/000679
申请日：2012-07-17
申请人： ENERKEM, INC. , PAQUET, Antonin , CHORNET, Esteban
发明人： PAQUET, Antonin , CHORNET, Esteban
IPC分类号： C01B3/32 , C01B3/02 , C01B3/12 , C01B3/26 , C01B3/34 , C01B3/00
CPC分类号： C01B3/02 , C01B3/38 , C01B3/384 , C01B3/48 , C01B2203/0233 , C01B2203/0238 , C01B2203/0283 , C10J3/463 , C10J3/54 , C10J3/721 , C10J3/84 , C10J2200/158 , C10J2300/0916 , C10J2300/0946 , C10J2300/0956 , C10J2300/0976 , C10J2300/0993 , C10J2300/1625 , C10J2300/1807 , C10J2300/1838 , C10K1/026 , C10K3/001 , Y02E60/324 , Y02P20/145
摘要： Processes for producing synthesis gas from biomass in which char particles, which are formed during the production of synthesis gas from biomass, are employed as catalysts. The char particles may be used as catalysts in a gasifier or in a thermal reformer, whereby gaseous components, formed as a result of the gasification of the biomass, such as methane, light alkyl and aromatic compounds, and phenolics, as well as tar, may be reformed and/or converted into synthesis gas.
摘要翻译：用于从生物质生产合成气的方法，其中在从生物质生产合成气期间形成的焦炭颗粒被用作催化剂。焦炭颗粒可以用作气化器或热重整器中的催化剂，由此气化组分由生物质如甲烷，轻质烷基和芳族化合物以及酚类物质以及焦油形成，可以重整和/或转化为合成气。

9. 发明申请

WO2012161726A1 COMPOSITION AND METHOD FOR DELIVERY OF SUBSTANCES IN A DRY MODE HAVING A SURFACE LAYER 审中-公开
标题翻译：用于在具有表面层的干燥模式中递送物质的组合物和方法
公开(公告)号：WO2012161726A1
公开(公告)日：2012-11-29
申请号：PCT/US2011/054891
申请日：2011-10-05
申请人： DAIRY MANUFACTURES, INC. , TREVINO, Ramino , ELLIS, Steven, R.
发明人： TREVINO, Ramino , ELLIS, Steven, R.
IPC分类号： A23L1/0562 , A23L1/30 , C01B3/12 , C11B9/00
CPC分类号： C12N11/04 , A01N25/26 , A01N25/34 , A01N63/00 , A23L27/70 , A23L27/77 , A23L29/06 , A23L29/065 , A23L33/10 , A23L33/105 , A23L33/115 , A23L33/135 , A23L33/14 , A23L33/16 , A23P10/30 , B09C1/002 , B09C1/10 , C05B7/00 , C05B17/00 , C05C9/00 , C05D1/00 , C05D9/02 , C05F11/08 , C11B9/00 , A01N2300/00 , A01N25/08
摘要： The present invention generally relates to compositions and methods of delivering substances in a dry mode, wherein the compositions include a surface layer disposed on the outer surface of the composition that is permeable to carbon dioxide and oxygen. The compositions may be used to deliver microorganisms to remove contaminates, such as oil, chemical, waste, or sewage, from soil, water, or air. In other embodiments, the compositions can also be used for delivering liquid food, liquid food additives, liquid biotech agricultural ingredients, conventional liquid agricultural ingredients, liquid human wellness and dietary supplements, and liquid fragrances and beauty products.
摘要翻译：本发明一般涉及以干燥方式输送物质的组合物和方法，其中组合物包括设置在组合物的外表面上的表面层，其可渗透二氧化碳和氧气。组合物可用于递送微生物以从土壤，水或空气中除去污染物，例如油，化学，废物或污水。在其它实施方案中，组合物还可用于输送液体食品，液体食品添加剂，液体生物技术农业成分，常规液体农业成分，液体人体健康和膳食补充剂以及液体香料和美容产品。

10. 发明申请

WO2011026943A1 PROCESS TO PREPARE A DILUTED HYDROGEN GAS MIXTURE 审中-公开
标题翻译：制备稀释氢气混合物的方法
公开(公告)号：WO2011026943A1
公开(公告)日：2011-03-10
申请号：PCT/EP2010/062966
申请日：2010-09-03
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DE GRAAF, Wouter David , PRINS, Mark Jan
发明人： VAN DE GRAAF, Wouter David , PRINS, Mark Jan
IPC分类号： C01B3/12 , C01B3/48 , C01B3/50 , C01B3/38
CPC分类号： C01B3/16 , C01B3/38 , C01B3/48 , C01B2203/0233 , C01B2203/0244 , C01B2203/0294 , C01B2203/0405 , C01B2203/041 , C01B2203/0475 , C01B2203/0485 , C01B2203/06 , C01B2203/147 , C01B2203/84 , C10J2300/1653 , C10K1/004 , C10K1/005 , C10K3/04 , Y02E20/18
摘要： Process to prepare a diluted hydrogen gas mixture starting from a gas mixture comprising hydrogen and carbon monoxide by (i) converting part of the carbon monoxide in said gas mixture to hydrogen and carbon dioxide by means of a catalysed water gas shift reaction to obtain a shifted gas and (ii) separating hydrogen from said shifted gas by means of a membrane to obtain the hydrogen comprising gas at the permeate side of the membrane and a carbon dioxide comprising gas at the retentate side of the membrane, wherein at the permeate side of the membrane a sweep gas is provided; (iii) cooling the carbon dioxide comprising gas to obtain liquid carbon dioxide and a gas mixture of non-condensable gasses and (iv) separating the liquid carbon dioxide from the non-condensable gasses; wherein the non-condensable gasses are fed into the hydrogen comprising gas.
摘要翻译：（i）通过催化的水煤气变换反应将所述气体混合物中的一氧化碳的一部分转化成氢气和二氧化碳从而制备包含氢气和一氧化碳的气体混合物的稀释的氢气混合物的方法，气体和（ii）通过膜从所述转移的气体中分离氢气以在膜的渗透侧获得包含气体的氢气和在膜的渗余侧包含气体的二氧化碳，其中在所述膜的渗透侧膜提供吹扫气体; （iii）冷却包含气体的二氧化碳以获得液态二氧化碳和不可冷凝气体的气体混合物和（iv）从不可冷凝气体中分离液态二氧化碳; 其中将不可冷凝气体进料到含氢气体中。

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