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    • 1. 发明申请
    • AN ENVIRONMENTALLY FRIENDLY TANNING METHOD
    • 环境友好的TANNING方法
    • WO2014162059A1
    • 2014-10-09
    • PCT/FI2014/050234
    • 2014-04-01
    • TAMINCO FINLAND OY
    • VAN DER BURGH, StefanBRENDLER, Dominicus
    • C14C3/04C01B39/02C11D3/12
    • C14C3/04
    • The present invention provides a system for tanning leather comprising from at least two tanning compositions to be used in sequence. First composition consists of zeolite having a Si to Al ratio from 0.7 to 2.5, treated with concentrated aliphatic monocarboxylic acid, the concentration of said monocarboxylic acid being more than 84% by weight, resulting in a zeolite structure which remains intact after said treatment; acidic metal salt; and a complexing agent. This first composition is in a form of a powdery solid having moisture content less than 25 %. The second composition consists of the mere zeolite treated with concentrated aliphatic monocarboxylic acid. Moreover, a method for tanning leather using said system is provided subjecting the hide to be treated to a beam house treatment followed by a modified pickling stage using a solution having a baume value less than 5 and pH from 3 to 6.
    • 本发明提供了一种用于鞣制皮革的系统,其包括由至少两种鞣制组合物按顺序使用。 第一组成由Si至Al比为0.7至2.5的沸石组成,用浓缩的脂族一元羧酸处理,所述一元羧酸的浓度大于84重量%,导致在所述处理后保持完整的沸石结构; 酸性金属盐; 和络合剂。 该第一组合物是水分含量小于25%的粉状固体的形式。 第二组合物由仅用浓缩的脂族一元羧酸处理的沸石组成。 此外,使用所述系统来对皮革进行鞣制的方法,其特征在于,使用具有小于5和pH为3至6的波导值的溶液对皮革进行处理以进行梁屋处理,然后进行改性酸洗阶段。
    • 6. 发明申请
    • AN ENVIRONMENTALLY FRIENDLY CHROME-TANNING METHOD
    • 环境友好的色谱方法
    • WO2016131894A1
    • 2016-08-25
    • PCT/EP2016/053403
    • 2016-02-18
    • TAMINCO FINLAND
    • VAN DER BURGH, StefanARMENGOL ESTEBAN, Jordi
    • C14C3/06C14C3/04
    • C14C3/06C14C3/04
    • A method for tanning a hide wherein said method comprises treating a tannable hide with a tanning composition comprising from 25 to 75 % by weight (wt. %) of at least one chromium(lll) salt; from 5 to 70 % by weight (wt. %) of at least one zeolite having the general formula (1): Mx/n [(AIO 2 )x(SiO 2 )y] wH 2 O, wherein M is an alkali metal cation, a bivalent cation, a trivalent cation or a mixture thereof, n is the valence of the cation, w is the number of water molecules per unit cell, y is a number from 0.8 to 50 and the ratio y to x is ranging from 0.7 to 100, treated with at least one acid selected from the group consisting of a monocarboxylic acid and a polycarboxylic acid; and from 1 to 70 wt. % of at least one aluminium(lll) salt; wherein all wt. % are relative to the total weight of the composition (T).
    • 一种用于鞣皮的方法,其中所述方法包括用包含25至75重量%(wt。%)至少一种铬(III)盐的鞣制组合物处理可晒黑的皮肤; 至少一种具有通式(1)的沸石的5-70重量%(wt。%):Mx / n [(AIO2)x(SiO2)y] wH2O,其中M是碱金属阳离子,二价 阳离子,三价阳离子或其混合物,n是阳离子的价数,w是每单位电池的水分子数,y是0.8至50的数,y与x的比率范围为0.7至100, 用选自一元羧酸和多元羧酸的至少一种酸处理; 和1-70wt。 %的至少一种铝(III)盐; 其中所有wt。 %相对于组合物(T)的总重量。
    • 9. 发明申请
    • METHOD FOR TANNING SKINS OR MATERIALS CONTAINING COLLAGEN, WITH A DENSE FLUID UNDER PRESSURE
    • 包含胶原蛋白的皮肤或材料的方法,压力下的渗液
    • WO01031067A1
    • 2001-05-03
    • PCT/FR2000/003004
    • 2000-10-27
    • C14C3/04C14C3/30
    • C14C3/04C14C3/30
    • The invention concerns a method for tanning skins and materials containing collagen comprising the following successive steps: (a) contacting said skins or said materials containing collagen, in a chamber, with a dense fluid under pressure containing at least a tanning agent insoluble or hardly soluble in said dense pressurised fluid, but soluble in water; (b) bringing said chamber to atmospheric pressure so as to eliminate said fluid in gas form; then following step b), directly introducing into the chamber at least a basification agent; then pressurising the chamber again with said fluid; and carrying out step (c) which consists in contacting said skins or said materials containing collagen with the dense pressurised fluid containing said basification agent; and finally in a step (d) bringing the chamber back to atmospheric pressure so as to eliminate said fluid in gas form.
    • 本发明涉及一种鞣制含有胶原蛋白的皮肤和材料的方法,包括以下连续步骤:(a)将包含胶原蛋白的所述皮肤或所述材料在室内与压力下的致密流体接触至少含有不溶或难溶的鞣剂 在所述致密加压流体中,但溶于水; (b)使所述室达到大气压,以消除气体形式的所述流体; 然后在步骤b)之后,直接将至少一种碱化剂引入该室; 然后用所述流体再次对腔室加压; 并执行步骤(c),其包括将含有胶原蛋白的所述皮肤或所述材料与含有所述碱化剂的致密加压流体接触; 并且最后在步骤(d)中使腔室恢复到大气压力,以便消除气体形式的所述流体。