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    • 1. 发明申请
    • NON-METAL TANNING PROCESS
    • 非金属鞣制工艺
    • WO2012055483A1
    • 2012-05-03
    • PCT/EP2011/004975
    • 2011-10-05
    • CLARIANT INTERNATIONAL LTDREINEKING, ClausGAMARINO, RobertaTRIMARCO, LiciaQUAGLIERINI, MaurizioGISLER, MarkusNUSSER, Rainer
    • REINEKING, ClausGAMARINO, RobertaTRIMARCO, LiciaQUAGLIERINI, MaurizioGISLER, MarkusNUSSER, Rainer
    • C14C3/26
    • C14C3/00C07D237/00C07D237/06C07D239/02C07D247/02C14C3/02C14C3/04C14C3/26
    • Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being at least a mixture of compounds of formula (I) and formula (II), wherein Hal signifies fluorine or chlorine, R1 signifies hydrogen, C 1-8 -alkyl or an alkyleneoxy radical of formula (III), - (- C 2-3 alkylene - O -) q - H (III) R2 signifies a) phenyl, mono- or di-substituted with SO 3 M or COOM and optionally substituted also with hydroxyl or C 1-4 -alkyl or C 1-4 alkoxy, or b) naphthyl, mono- or di- or tri-substituted with SO 3 M and optionally substituted also with hydroxyl, or c) C 1-8 -alkylene, substituted with (S0 3 M) or (COOM), or d) a radical of formula (IV), - (- C 2-3 alkylene - O -) p - Y (IV) e) or a radical of formula (IVa), -(C 2-3 alkylene - O) p -C 2-3 alkylene - SO 2 CH 2 CH2O -Y (IVa) m signifies 1 or 2, P signifies 0 or 1, Y signifies hydrogen or -SO 3 M, q is of from 1 to 10, M signifies hydrogen or an alkali metal cation or an ammonium cation, the ammonium cation being a protonated tertiary amine or a quaternary ammonium cation, R3 signifies hydrogen or chlorine, in a tanning bath, the tanning bath having a pH of from 6 to 10 at the beginning of tanning step.
    • 鞣制的皮革,皮肤或毛皮是通过非金属鞣制制成的,包括用鞣剂(A)鞣制皮肤,皮肤或皮肤的步骤,鞣制剂(A)至少是式 I)和式(II),其中Hal表示氟或氯,R1表示氢,C1-8 - 烷基或式(III)的亚烷基氧基, - ( - C2-3亚烷基-O - )q-H(III )R2表示a)苯基,被SO 3 M或COOM单取代或二取代,并任选也被羟基或C 1-4 - 烷基或C 1-4烷氧基取代,或b)萘基,被SO 3 M单取代或二取代或三取代 或任选地被羟基取代,或c)被(S03M)或(COOM)取代的C 1-8 - 亚烷基,或d)式(Ⅳ)基团, - ( - C 2-3亚烷基-O - ) - Y(IV)e)或式(Ⅳa)基团, - (C2-3亚烷基-O)p -C2-3亚烷基-SO2CH2CH2O -Y(Ⅳa)m表示1或2,P表示0或1,Y 表示氢或-SO 3 M,q为1至10,M表示氢或碱金属 铵阳离子是质子化叔胺或季铵阳离子,R3表示氢或氯,在鞣制浴中,鞣制浴在鞣制步骤开始时pH为6至10。
    • 3. 发明申请
    • TANNING PROCESS AND TANNING COMPOSITION
    • 鞣制工艺和鞣制组合物
    • WO2010130311A1
    • 2010-11-18
    • PCT/EP2010/001334
    • 2010-03-04
    • CLARIANT INTERNATIONAL LTDGAMARINO, RobertaTRIMARCO, Licia
    • GAMARINO, RobertaTRIMARCO, Licia
    • C14C3/26C07D251/44
    • C14C3/26C07D251/44Y10T428/4935
    • Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning with a tanning agent (A) of formula (I), wherein Hal signifies fluorine or chlorine, R1 signifies hydrogen, C 1-8 -alkyl or an alkyleneoxy radical of formula (Ia), −(−C 2-3 alkylene −O−)q−H R2 signifies C 1-4 -alkyl or C 1-4 -alkoxy, m signifies 1 or 2, n signifies O or 1, q is of from 1 to 10, M signifies hydrogen or an alkali metal cation or an ammonium cation, in a tanning bath, the tanning bath having a pH of from 6 to 10 at the beginning of tanning step, the invention relates to the defined tanning process, particular tanning agent compositions, the use of the tanned leather, skins or pelts for further processing and the produced tanned and optionally further processed leather, skins or pelts.
    • 鞣制的皮革,皮肤或皮肤由非金属鞣制制成,包括用式(I)的鞣剂(A)鞣制的步骤,其中Hal表示氟或氯,R1表示氢,C1-8烷基或 式(Ia)的亚烷基氧基, - ( - C2-3亚烷基-O-)qHR2表示C1-4 - 烷基或C1-4 - 烷氧基,m表示1或2,n表示O或1,q表示 1至10,M表示氢或碱金属阳离子或铵阳离子,在鞣制浴中,在鞣制步骤开始时,鞣制浴的pH为6至10,本发明涉及定义的鞣制过程,特别是 鞣制剂组合物,使用鞣制的皮革,皮革或毛皮进行进一步加工,以及生产的鞣制和任选进一步加工的皮革,皮革或毛皮。
    • 4. 发明申请
    • NON METAL TANNING
    • 非金属鞣制
    • WO2012062412A1
    • 2012-05-18
    • PCT/EP2011/005366
    • 2011-10-25
    • CLARIANT INTERNATIONAL LTDREINEKING, ClausGAMARINO, RobertaTRIMARCO, LiciaQUAGLIERINI, Maurizio
    • REINEKING, ClausGAMARINO, RobertaTRIMARCO, LiciaQUAGLIERINI, Maurizio
    • C14C3/26C07D237/32C07D241/44C07D237/14C07D237/30
    • C14C3/26C07D237/14C07D237/30C07D241/46
    • Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being a sulpho-group-containing dichloro-diazine selected from compounds of formula (I), of formula (II), and of formula (III), and mixtures of two or more thereof, wherein R1 signifies hydrogen, methyl, methoxy, benzoyl, naphthoyi, mono- or di(C 1-4 -alkyl)-aminocarbonyl, C 1-8 -alkoxy-carbonyl or oxy-mono- or oligo-(C 2-3 -alkyleneoxy)-carbonyl R2-(SO 3 M) n signifies a radical of formula a) or b) R3 signifies hydrogen, d-8-alkyl or d-s-alkoxy, m is 1 or 2, n is 1 or 2 and M signifies hydrogen or an alkali metal cation or an ammonium cation, the ammonium cation being a protonated tertiary amine or a quaternary ammonium cation, in a tanning bath, the tanning bath having a pH of from 6 to 10 at the beginning of tanning step.
    • 鞣制的皮革,皮肤或毛皮是通过非金属鞣制制成的,包括用鞣剂(A)鞣制皮肤,皮肤或皮肤的步骤,鞣剂(A)是含磺基的二氯二嗪 选自式(I),式(II)和式(III)的化合物及其两种或多种的混合物,其中R 1表示氢,甲基,甲氧基,苯甲酰基,萘甲基,单或二(C1- 4-烷基) - 氨基羰基,C 1-8 - 烷氧基 - 羰基或氧 - 单 - 或低 - (C 2-3亚烷氧基) - 羰基R 2 - (SO 3 M)n表示式a)或b)的基团,其中R 3表示氢 ,d-8-烷基或ds-烷氧基,m为1或2,n为1或2,M表示氢或碱金属阳离子或铵阳离子,铵阳离子为质子化叔胺或季铵阳离子, 在鞣制浴中,在鞣制步骤开始时,鞣制浴的pH为6至10。
    • 5. 发明申请
    • RETANNING AND FATLIQUORING AGENT FOR LEATHER
    • 皮革回收和破乳剂
    • WO2009080489A1
    • 2009-07-02
    • PCT/EP2008/067062
    • 2008-12-09
    • CLARIANT INTERNATIONAL LTDGAMARINO, RobertaTRIMARCO, LiciaGIANI, MicheleREINEKING, Claus
    • GAMARINO, RobertaTRIMARCO, LiciaGIANI, MicheleREINEKING, Claus
    • C14C9/02C14C3/28
    • C14C9/02C14C3/28
    • The invention relates to a composition for wet retanning and lubricating of pelts, skins, hides, leather intermediate products or non-finished leather, consisting of (A) a reaction product of an ethylenically unsaturated C 4 -C 8 -dicarboxylic anhydride with C 3 -C 40 -alpha-olefins, followed by partial or total neutralisation with a base, (B) a reaction product of ethylenically unsaturated C^Cs-dicarboxylic anhydrides with C 10 -C 40 -fatty acids or C 4 -C 30 polycarboxylic acids or C 10 -C 40 fatty alcohols or oxo-alcohols or glycols or polyglycols or C 3 -C 20 organic amines all being saturated or unsaturated, linear or branched and the fatty acids being ethoxylated and/or propoxylated and/or having been reacted with polyglycols or glycols, and the C 4 -C 30 polycarboxylic acids being ethoxylated and/or propoxylated and/or having been reacted with polyglycols or glycols at least with one carboxylic group, and (C) a reaction product of (B) with bisulphite or metabisulphite or sulphite or sulphuric acid or oleum preferably neutralised with a base where the base is an alkali or earth alkali hydroxide, ammonia or an organic amine.
    • 本发明涉及一种用于湿复性和润滑毛皮,皮革,皮革,皮革中间产品或非成品皮革的组合物,由(A)烯属不饱和C4-C8-二羧酸酐与C3-C40-二羧酸酐的反应产物组成, α-烯烃,然后用碱进行部分或全部中和,(B)烯键式不饱和C 1 -C 8 - 二羧酸酐与C 10 -C 40脂肪酸或C 4 -C 30多元羧酸或C 10 -C 40脂肪醇或氧代 醇或二醇或聚乙二醇或C 3 -C 20有机胺全部是饱和或不饱和的,直链或支链的,脂肪酸被乙氧基化和/或丙氧基化和/或已经与聚二醇或二醇反应,并且C4-C30多元羧酸是 乙氧基化和/或丙氧基化和/或已经与聚乙二醇或二醇至少与一个羧基反应,和(C)(B)与亚硫酸氢盐或偏亚硫酸氢盐或亚硫酸盐或硫酸或o 优选用碱与碱或碱土氢氧化物,氨或有机胺中和碱。
    • 9. 发明申请
    • NON METAL TANNING
    • 非金属鞣制
    • WO2012055480A1
    • 2012-05-03
    • PCT/EP2011/004972
    • 2011-10-05
    • CLARIANT INTERNATIONAL LTDREINEKING, ClausGAMARINO, RobertaTRIMARCO, LiciaQUAGLIERINI, MaurizioGISLER, MarkusNUSSER, Rainer
    • REINEKING, ClausGAMARINO, RobertaTRIMARCO, LiciaQUAGLIERINI, MaurizioGISLER, MarkusNUSSER, Rainer
    • C14C3/26C14C3/28C07D251/44
    • C14C3/26C07D251/44C14C3/28
    • Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being at least one compound of formula (I), wherein X signifies fluorine, chlorine and/or ( + NR 3 ) 0-1 ,, wherein R is a substituted C 1 to C 6 alkyl group or an unsubstituted C 1 to C 6 alkyl group, an unsubstituted C 6 to C 10 aryl group or a substituted C 6 to C- 1 0 aryl group or a C 5 to C 6 heteroaryl group, R1 signifies hydrogen, C 1-8 alkyl or an alkyleneoxy radical of formula (la), - (- C 2-3 alkylene - O -) q - H (la) R2 signifies substituted or unsubstituted C 2 to C 8 alkylenesulphonic acid, substituted or unsubstituted C 2 to C 8 alkylenecarboxylic acid or an alkyleneoxy radical of formula (lb), - (- C 2-3 alkylene - O -) m - Y (lb) or an alkylene sulfonyl alkyleneoxy radical of formula (Ic), - (C 2-3 alkylene - O) p -C 2-3 alkylene - SO 2 CH 2 CH 2 O-Y (Ic) m signifies 1 or 2, P signifies 0 or 1, q is of from 1 to 10, Y signifies hydrogen or -SO 3 M, M signifies hydrogen or an alkali metal cation or an ammonium cation, the ammonium cation being a protonated tertiary amine or a quaternary ammonium cation, in a tanning bath, the tanning bath having a pH of from 6 to 10 at the beginning of tanning step.
    • 鞣制的皮革,皮肤或毛皮是通过非金属鞣制制成的,包括用鞣剂(A)鞣制皮肤,皮肤或皮肤的步骤,鞣制剂(A)是至少一种式(I)化合物, 其中X表示氟,氯和/或(+ NR 3)0-1,其中R是取代的C1至C6烷基或未取代的C1至C6烷基,未取代的C6至C10芳基或取代的C6至 C 1-10芳基或C 5至C 6杂芳基,R 1表示氢,C 1-8烷基或式(Ia)的亚烷基氧基, - ( - C 2-3亚烷基-O - )q -H(Ia)R 2表示 取代或未取代的C2至C8亚烷基磺酸,取代或未取代的C2至C8亚烷基羧酸或式(Ib)的亚烷氧基, - ( - C2-3亚烷基-O - ) - Y(1b)或亚烷基磺酰基亚烷基氧基 式(Ic)中, - (C2-3亚烷基-O)p -C2-3亚烷基-SO2CH2CH2O-Y(Ic)m表示1或2,P表示0或1,q为1至10,Y 表示水压 n或-SO 3 M,M表示氢或碱金属阳离子或铵阳离子,铵阳离子是质子化叔胺或季铵阳离子,在鞣浴中,鞣制浴的pH为6至10 鞣制步骤开始
    • 10. 发明申请
    • PROCESS AND COMPOSITIONS FOR WET DEGREASING OF PELTS, SKINS, HIDES, LEATHER INTERMEDIATE PRODUCTS AND NON-FINISHED LEATHER
    • 皮肤,皮肤,隐形眼镜,皮革中间产品和非完整皮革的湿度去除方法和组合物
    • WO2006024629A1
    • 2006-03-09
    • PCT/EP2005/054200
    • 2005-08-26
    • CLARIANT INTERNATIONAL LTDGAMARINO, RobertaMORESCA, DanielaTRIMARCO, LiciaMALLON, Jon
    • GAMARINO, RobertaMORESCA, DanielaTRIMARCO, LiciaMALLON, Jon
    • C14C1/08C14C5/00C11D1/825
    • C14C1/08C11D1/72C11D1/722C11D1/8255C14C5/00
    • The invention relates to wet degreasing of pelts, skins, hides, leather intermediate products or non- finished leather, with emulsion degreasing agents (D) comprising a mixture (E) of ethoxylation and optionally propoxylation products of a mixture (A) of oxo- alcohols of formula C n H (2n+1) -CH 2 OH (I), in which n is a number from 9 to 15, and the alkyl radical C n H (2n+i) - is linear, wherein (A) comprises a mixture of positional isomers for at least one of the significances of n, and the proportion of primary linear component in (A) in which the alkyl radical C n H (2n+i) - is a normal primary radical is in the range of 25 to 70 % by weight of the mixture (A), and in (E) the average degree of ethoxylation is in the range of 5 to 12, and if the products (E) are also propoxylated the average degree of ethoxylation is superior to the average degree of propox¬ ylation, in the presence of at least one further non-ionic emulsifier which is (F) at least one ethoxylation and optionally propoxylation product of (B) an aliphatic saturated at least twice branched alcohol or mixture, and emulsion degreasing compositions (D') comprising mixtures (E) and products (F), and optionally one or more formulation additives (S).
    • 本发明涉及毛皮,皮革,皮革,皮革中间产品或非成品皮革的湿脱脂,其中乳液脱脂剂(D)包含乙氧基化的混合物(E)和任选的氧代 - (A)的混合物(A)的丙氧基化产物, 式(II)的化合物(II + 1)-CH 2 OH(I)的醇,其中n为9至15的数 ,并且烷基C n H(2n + 1) - 是直链的,其中(A)包含位置异构体的混合物,其中n个意义中的至少一个意义 ,并且其中烷基C 1 H 2n(2n + i) - (2n + i)) - (2n + i) - 的(A)中的初级线性成分的比例是正常的初级基团的范围在 混合物(A)的25〜70重量%,(E)的平均乙氧基化度在5〜12的范围内,如果产物(E)也被丙氧基化,则平均乙氧基化度优于 在至少一种另外的非离子型emu的存在下,丙醛的平均程度 (F)至少一种乙氧基化和任选的丙氧基化产物(B)脂肪族饱和的至少两次支化的醇或混合物,以及包含混合物(E)和产物(F)的乳液脱脂组合物(D')和任选的 一种或多种制剂添加剂(S)。