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1. 发明申请

WO2017037176A1 PROCESS TO PREPARE PARAFFINS AND WAXES 审中-公开
标题翻译：准备参与和浪费的过程
公开(公告)号：WO2017037176A1
公开(公告)日：2017-03-09
申请号：PCT/EP2016/070616
申请日：2016-09-01
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL OIL COMPANY
发明人： BEZEMER, Gerrit, Leendert , BOERRIGTER, Harold , TAN, Hai, Ming
IPC分类号： C10G2/00 , C10G73/44 , C10G45/00 , C10G45/02 , C10G65/04
CPC分类号： C10G2/331 , C10G2/341 , C10G45/00 , C10G45/02 , C10G65/04 , C10G73/44 , C10G2300/1022 , C10G2300/1085
摘要： The present invention relates to a process to prepare paraffins and waxes from a gaseous feed stream comprising hydrogen and carbon monoxide in a Fischer-Tropsch reactor comprising a fixes bed of reduced Fischer-Tropsch catalyst that comprises cobalt as catalytically active metal, said process at least comprises the following steps : (a) adding to the gaseous feed stream a nitrogen- containing compound such that the nitrogen-containing compound is present in the gaseous feed stream in a concentration of up to 10 ppmV to obtain a mixture, wherein the nitrogen-containing compound is a compound selected from ammonia, HCN, NO, amines, organic cyanides (nitriles), and a heterocyclic compound containing at least one nitrogen atom as ring member of a heterocyclic ring; (b) feeding the mixture of step (a) to the Fischer- Tropsch reactor to obtain a Fischer-Tropsch product comprising paraffins having from 5 to 300 carbon atoms; (c) subjecting the Fischer-Tropsch product of step (b) to a hydrogenation step, thereby obtaining hydrogenated fraction comprising 5 to 300 carbon atoms; (d) separating the hydrogenated Fischer-Tropsch product stream of step (c), thereby obtaining at least a fraction comprising 5 to 9 carbon atoms, a fraction comprising 10 to 17 carbon atoms and a fraction comprising 18 to 300 carbon atoms; (e) separating the hydrogenated fraction comprising 18 to 300 carbon atoms of step (d), thereby obtaining one or more first light waxes having a congealing point in the range of 30 to 75 °C and a second heavy wax having a congealing point in the range of 75 to 120°C.
摘要翻译：本发明涉及一种在费 - 托反应器中从包含氢和一氧化碳的气态进料流中制备链烷烃和蜡的方法，该方法包括包含钴作为催化活性金属的还原费 - 托催化剂的固定床，所述方法至少包括以下步骤：（a）向气态进料流中加入含氮化合物，使得含氮化合物以高达10ppmV的浓度存在于气态进料流中以获得混合物，其中，含氮化合物是选自氨，HCN，NO，胺，有机氰化物（腈）的化合物和含有至少一个氮原子作为杂环环的杂环化合物; （b）将步骤（a）的混合物加入到费 - 托反应器中以获得包含具有5至300个碳原子的链烷烃的费 - 托产品; （c）使步骤（b）的费 - 托产物进行氢化步骤，由此获得含有5至300个碳原子的氢化部分; （d）分离步骤（c）的氢化费 - 托产物流，从而得到至少一个含有5至9个碳原子的馏分，含10至17个碳原子的馏分和包含18至300个碳原子的馏分; （e）分离步骤（d）中含有18至300个碳原子的氢化馏分，从而得到一种或多种具有凝固点在30至75℃范围内的第一轻质蜡和具有凝固点的第二重蜡范围为75至120°C。

2. 发明申请

WO2014001550A1 PROCESS TO PREPARE MIDDLE DISTILLATES AND BASE OILS 审中-公开
标题翻译：制备中间馏分和基础油的方法
公开(公告)号：WO2014001550A1
公开(公告)日：2014-01-03
申请号：PCT/EP2013/063734
申请日：2013-06-28
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL OIL COMPANY
发明人： KIEFFER, Eduard Philip , RIGUTTO, Marcello Stefano , SIETSMA, Jelle Rudolf Anne
IPC分类号： C10G65/12 , C10G65/04 , C10G73/02 , C10G73/44 , C10G45/62 , C10G45/64 , C10L1/08
CPC分类号： C10G67/02 , C10G45/62 , C10G45/64 , C10G65/00 , C10G65/043 , C10G65/12 , C10G65/16 , C10G73/02 , C10G73/44 , C10G2300/1022 , C10G2300/301
摘要： The present invention provides a process to prepare a first middle distillates fraction, a second middle distillates fraction and one or more base oils, which process at least comprises the following steps: (a) providing a Fischer-Tropsch product stream; (b) separating the Fischer-Tropsch product stream of step (a), thereby obtaining at least a low boiling fraction, boiling below a temperature in the range of from 300 to 450°C, and a high boiling fraction, boiling above a temperature in the range of from 300 to 450°C; (c) subjecting the high boiling fraction of step (b) to a hydrocracking/hydroisomerization step to obtain an at least partially isomerised product stream; (d) separating the product stream of step (c), thereby obtaining a first middle distillates fraction and a residual fraction, wherein the residual fraction has a T10wt.% boiling point of between 200 and 450°C; (e) dewaxing the low boiling fraction of step (b) to obtain a second middle distillates fraction; and f) dewaxing the residual fraction of step (d) to obtain one or more base oils.
摘要翻译：本发明提供了制备第一中间馏分馏分，第二中间馏分和一种或多种基础油的方法，该方法至少包括以下步骤：（a）提供费 - 托产物流; （b）分离步骤（a）的费 - 托产物流，从而得到至少沸点低于300-450℃的沸点，沸点高于沸点在300〜450℃的范围内; （c）使步骤（b）的高沸点馏分进行加氢裂化/加氢异构化步骤以获得至少部分异构化的产物流; （d）分离步骤（c）的产物流，从而获得第一中间馏分和残余馏分，其中残余馏分的T10重量％沸点在200-450℃之间; （e）将步骤（b）的低沸点馏分脱蜡得到第二中间馏分; 和f）使步骤（d）的残余馏分脱蜡得到一种或多种基础油。

3. 发明申请

WO99010098A1 SUPPORTED Ni-Cu HYDROCONVERSION CATALYST 审中-公开
标题翻译：支持Ni-Cu氢化催化剂
公开(公告)号：WO99010098A1
公开(公告)日：1999-03-04
申请号：PCT/US1998/017091
申请日：1998-08-18
IPC分类号： B01J21/12 , B01J23/755 , B01J35/00 , C10G1/00 , C10G45/60 , C10G47/12 , C10G65/00 , C10G73/44
CPC分类号： C10G73/44 , B01J21/12 , B01J23/755 , B01J35/0026 , B01J35/1019 , B01J35/1038 , C10G1/002 , C10G45/60 , C10G47/12 , C10G65/00
摘要： Nickel-copper catalysts supported on an amorphous silica-alumina acidic carrier, preferably containing a binder, and having an iso-electric point of >/=6.5 are used to hydroisomerize paraffins, particularly Fischer-Tropsch paraffins, boiling at 350 DEG F into lighter, more valuable products.
摘要翻译：负载在无定形二氧化硅 - 氧化铝酸性载体上的镍 - 铜催化剂，优选含有粘合剂，并且具有> = = 6.5的等电点，用于使在350°F +沸点下沸腾的链烷烃，特别是费 - 托烷烃加氢异构化 >更轻，更有价值的产品。

4. 发明申请

WO2016144761A1 HIGH OIL CONTENT WAXES FOR FOOD GRADE AND HIGH QUALITY USES AND THE METHODS OF MAKING THE SAME 审中-公开
标题翻译：用于食品级和高质量用途的高油含量及其制备方法
公开(公告)号：WO2016144761A1
公开(公告)日：2016-09-15
申请号：PCT/US2016/020907
申请日：2016-03-04
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
发明人： AGRAWAL, Sarvesh, K. , YOHE, Sara, L. , HOCH, Larry, E. , TURNER, Elizabeth, A. , WANG, Frank, C.
IPC分类号： C08L91/08 , C10G69/02 , C10M101/02
CPC分类号： C08L91/06 , C08L91/08 , C08L2205/02 , C10G73/44
摘要： Finished wax compositions with low aromatic content and high oil contents may be suitable for use in candle applications and/or food packaging and other food grade quality applications despite such high oil contents. Such wax compositions can reduce the need for wax refinement and/or post- processing, such as de-oiling, and increase the ease and efficiency of batch preparation and large volume manufacture.
摘要翻译：具有低芳香含量和高油含量的成品蜡组合物可能适用于蜡烛应用和/或食品包装和其他食品级质量应用，尽管油含量高。这种蜡组合物可以减少蜡精制和/或后处理的需要，例如脱油，并且增加了批量制备和大批量制造的容易性和效率。

5. 发明申请

WO2016107860A1 PROCESS TO PREPARE A PARAFFIN WAX 审中-公开
标题翻译：处理PARAFFIN WAX的过程
公开(公告)号：WO2016107860A1
公开(公告)日：2016-07-07
申请号：PCT/EP2015/081328
申请日：2015-12-29
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL OIL COMPANY
发明人： HOEK, Arend , ROOVERS, Antonius, Adrianus, Maria , MAJUMDER, Kaushik
IPC分类号： C10G45/02 , C10G65/04 , C10G73/36 , C10G73/44 , C10G2/00 , C08L91/08
CPC分类号： C10G73/36 , C08L91/08 , C10G2/32 , C10G45/02 , C10G65/04 , C10G73/44 , C10G2300/1022 , C10G2300/30
摘要： The present invention provides a paraffin wax having a congealing point according to ASTM D938 of at least 75°C and a Saybolt colour according to ASTM D156 of at least 25 cm.
摘要翻译：本发明提供一种具有至少75℃的根据ASTM D938的凝结点和至少25cm的根据ASTM D156的Saybolt颜色的石蜡。

6. 发明申请

WO2004009739A2 PROCESS TO PREPARE A MICROCRYSTALLINE WAX AND A MIDDLE DISTILLATE FUEL 审中-公开
标题翻译：制备微波炉和中等蒸馏燃料的方法
公开(公告)号：WO2004009739A2
公开(公告)日：2004-01-29
申请号：PCT/EP2003/007785
申请日：2003-07-17
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , HOEK, Arend
发明人： HOEK, Arend
IPC分类号： C10G73/44
CPC分类号： C10G45/58 , C10G73/44 , C10G2300/1022 , C10G2300/301 , C10G2400/04 , Y10S208/95
摘要： Process to prepare a microcrystalline wax and a middle distillate fuel by (a) hydrocracking/hydroisomerisating a Fischer-Tropsch product, wherein weight ratio of compounds having at least 60 or more carbon atoms and compounds having at least 30 carbon atoms in the Fischer-Tropsch product is at least 0.2 and wherein at least 30 wt% of compounds in the Fischer-Tropsch product have at least 30 carbon atoms, (b) performing one or more distillate separations on the effluent of step (a) to obtain a middle distillate fuel fraction and a microcrystalline wax having an initial boiling point of between 500 and 600 °C.
摘要翻译：（a）费 - 托产物的加氢裂化/加氢异构化制备微晶蜡和中间馏分燃料的方法，其中在费 - 托中具有至少60个或更多个碳原子的化合物和具有至少30个碳原子的化合物的重量比产物至少为0.2，并且其中至少30wt％的费 - 托产物中的化合物具有至少30个碳原子，（b）在步骤（a）的流出物上进行一种或多种馏出物分离以获得中间馏分燃料馏分和初始沸点为500-600℃的微晶蜡。

7. 发明申请

WO02102941A3 PROCESS FOR PREPARING A MICROCRYSTALLINE WAX 审中-公开
标题翻译：制备微晶WAX的方法
公开(公告)号：WO02102941A3
公开(公告)日：2003-03-20
申请号：PCT/EP0206584
申请日：2002-06-13
申请人： SHELL INT RESEARCH , HOEK AREND , SCHADENBERG HENDRIK
发明人： HOEK AREND , SCHADENBERG HENDRIK
IPC分类号： A61K8/30 , A61K8/02 , A61K8/31 , C09J191/06 , C10G45/62 , C10G73/44 , C10M101/02 , C10M105/04 , C10M177/00 , C10N40/00 , C10N70/00
CPC分类号： C10G45/62 , C10G73/44 , C10G2300/1022 , C10G2300/301 , C10G2300/4018 , C10G2400/10
摘要： Process to prepare a microcrystalline wax by contacting under hydroisomerisation conditions a feed, comprising at least 80 wt % of normal-paraffins and having a congealing point of above 60 DEG C, with a catalyst comprising a noble metal and a porous silica-alumina carrier.
摘要翻译：通过在加氢异构化条件下使包含至少80重量％的正链烷烃并且具有高于60℃的凝固点的进料与包含贵金属和多孔二氧化硅 - 氧化铝载体的催化剂接触来制备微晶蜡的方法。

8. 发明申请

WO2014095813A1 PROCESS FOR PREPARING A HYDROWAX 审中-公开
标题翻译：制备HYDROWAX的方法
公开(公告)号：WO2014095813A1
公开(公告)日：2014-06-26
申请号：PCT/EP2013/076837
申请日：2013-12-17
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL OIL COMPANY
发明人： BARIC, John Joseph , VAN DIJK, Nicolaas , HUVE, Laurent Georges
IPC分类号： C10G65/12 , B01J21/12 , B01J23/888 , B01J37/20 , B01J29/08 , C10G73/44
CPC分类号： C10M101/025 , B01J23/882 , B01J29/076 , B01J29/166 , C10G47/16 , C10G65/12 , C10G73/44 , C10G2300/301
摘要： The invention provides a process for preparing a hydrowax comprising the steps of: (a) providing a hydrocarbonaceous feedstock which contains more than 4% by weight of hydrocarbons boiling in the range of from 550 to 800 °C; (b) hydrotreating the hydrocarbonaceous feedstock with a hydrotreating catalyst in the presence of a hydrogen- containing gas under hydrotreating conditions to obtain a hydrotreated product; (c) hydrocracking at least part of the hydrotreated product as obtained in step (b) with a hydrocracking catalyst in the presence of a hydrogen-containing gas under hydrocracking conditions to obtain a hydrocracked product, which hydrocracking catalyst contains a zeolitic component which is present in an amount of at least 14 wt%, based on the total weight of the hydrocracking catalyst, and wherein the volume ratio of the hydrotreating catalyst as used in step (b) and the hydrocracking catalyst is more than 1; and (d) recovering from the hydrocracked product as obtained in step (c) the hydrowax.
摘要翻译：本发明提供了一种制备水合物的方法，包括以下步骤：（a）提供含烃原料，其含有超过4重量％的沸点为550-800℃的烃; （b）在加氢处理条件下在含氢气体存在下，用加氢处理催化剂加氢处理含烃原料，得到加氢处理产物; （c）在加氢裂化条件下，在含氢气体存在下，用加氢裂化催化剂加氢裂化步骤（b）中得到的加氢处理产物的至少一部分，得到加氢裂化催化剂，该催化剂含有存在的沸石组分相对于加氢裂化催化剂的总重量为至少14重量％，其中步骤（b）中使用的加氢处理催化剂与加氢裂化催化剂的体积比大于1; 和（d）从在步骤（c）获得的加氢裂化产物中回收氢氟烃。

9. 发明申请

WO2004009739A3 PROCESS TO PREPARE A MICROCRYSTALLINE WAX AND A MIDDLE DISTILLATE FUEL 审中-公开
标题翻译：制备微晶蜡和中间馏分燃料的方法
公开(公告)号：WO2004009739A3
公开(公告)日：2004-03-25
申请号：PCT/EP0307785
申请日：2003-07-17
申请人： SHELL INT RESEARCH , HOEK AREND
发明人： HOEK AREND
IPC分类号： C10G65/12 , C10G45/58 , C10G45/62 , C10G47/14 , C10G65/14 , C10G73/44
CPC分类号： C10G45/58 , C10G73/44 , C10G2300/1022 , C10G2300/301 , C10G2400/04 , Y10S208/95
摘要： Process to prepare a microcrystalline wax and a middle distillate fuel by (a) hydrocracking/hydroisomerisating a Fischer-Tropsch product, wherein weight ratio of compounds having at least 60 or more carbon atoms and compounds having at least 30 carbon atoms in the Fischer-Tropsch product is at least 0.2 and wherein at least 30 wt% of compounds in the Fischer-Tropsch product have at least 30 carbon atoms, (b) performing one or more distillate separations on the effluent of step (a) to obtain a middle distillate fuel fraction and a microcrystalline wax having an initial boiling point of between 500 and 600 °C.
摘要翻译：通过（a）费 - 托产物的加氢裂化/加氢异构化制备微晶蜡和中间馏分燃料的方法，其中费 - 托的具有至少60个或更多个碳原子的化合物与具有至少30个碳原子的化合物的重量比产物为至少0.2，并且其中费 - 托产物中至少30wt％的化合物具有至少30个碳原子，（b）对步骤（a）的流出物进行一次或多次馏分分离以获得中间馏分燃料馏分和初沸点为500-600℃的微晶蜡。

10. 发明申请

WO2003102115A1 MIKROKRISTALLINES PARAFFIN, VERFAHREN ZUR HERSTELLUNG VON MIKROKRISTALLINEN PARAFFINEN UND VERWENDUNG DER MIKROKRISTALLINEN PARAFFINE 审中-公开
标题翻译：微晶石蜡，用于生产微晶石蜡和微晶石蜡的用途
公开(公告)号：WO2003102115A1
公开(公告)日：2003-12-11
申请号：PCT/EP2003/005236
申请日：2003-05-19
申请人： SASOL WAX GMBH , SCHULZE-TRAUTMANN, Helmuth , MATTHÄI, Michael , BUTZ, Thorsten , HILDEBRAND, Günter
发明人： SCHULZE-TRAUTMANN, Helmuth , MATTHÄI, Michael , BUTZ, Thorsten , HILDEBRAND, Günter
IPC分类号： C10G45/58
CPC分类号： C10G73/44 , A61K8/31 , A61K2800/412 , A61Q19/00 , B01J23/42 , B01J29/7007 , B01J29/7415 , B01J35/0006 , B01J37/0009 , B01J2229/42 , C10G2/30 , C10G45/58 , C10G45/62 , C10G45/64 , C10G2300/1022
摘要： Es wird ein neues, vollsynthetisches, mikrokristallines Paraffin beschrieben, das durch katalytische Hydroisomerisierung von FT-Paraffinen mit 20 bis 105 Kohlenstoffatomen auf einfache Weise and mit hohen Ausbeuten erhalten werden kann. Sie sind bei Raumtemperatur pastös bis fest and haben einen höheren Anteil an isoParaffine als an n-Paraffinen. Sie enthalten keine Aromaten. Daher eignen sie sich insbesondere für pharmazeutische and kosmetische Anwendungen sowie in der Lebensmittelindustrie.
摘要翻译：它描述了一种新的，完全合成的，微晶蜡，其可以通过具有以简单的方式和以高的产率为20〜105个碳原子的链烷烃FT的催化加氢异构化而获得。他们是膏状固体在室温下具有异构烷烃比正构烷烃的比例较高。它们不含芳烃。因此，它们特别适用于医药和化妆品应用和食品工业。

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