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    • 3. 发明申请
    • DICYCLIC METAL COMPLEX FORMAZAN DERIVATIVES, PROCESS FOR PRODUCING THE SAME, COMPOSITION CONTAINING THE SAME AND DYEING PROCESS EMPLOYING THE SAME
    • 二元金属络合物衍生物,其制造方法,含有该组合物的组合物和使用其的染色方法
    • WO1996033240A2
    • 1996-10-24
    • PCT/KR1996000049
    • 1996-04-08
    • KYUNG-IN SYNTHETIC CORPORATIONKIM, Dong, GilCHO, Sung, Yong
    • KYUNG-IN SYNTHETIC CORPORATION
    • C09B00/00
    • C09B62/4407C09B50/00
    • The present invention relates to dicyclic metal formazan derivatives used for dye. To overcome these problems, the present invention provides a novel dicyclic metal formanan derivatives represented by formula (1) which has excellent dyeing property and fastness, wherein A is benzene or naphthalene having 1 to 3 substituent groups and sulfo group (-SO3M) in ortho-position for N-atom of hydrazone compound; B is straight- or branched-chain alkyl group, phenyl group, naphthyl group or substituent heterocyclic group; C is benzene or naphthalene having from 1 to 3 substituent groups; D is benzene or naphthalene; M is hydrogen atom, alkali metal or alkali earth metal; Me is metal ion of atomic number 27 to 29; Y is halogen; X is hydrogen atom or sulfo group, carboxyl group, phosphonic group providing solubility for water; R is straight- or branched-chain alkyl group; Q is -SO2CH=CH2, or -SO2CH2CH2L (L is a group which may be substituted by alkali); and l, m, n are independently an integer from 0 to 3.
    • 本发明涉及用于染料的二环金属甲an衍生物。 为了克服这些问题,本发明提供了一种具有优异的染色性和牢度的由式(1)表示的新型二环金属甲酰胺衍生物,其中A是苯或萘具有1至3个取代基和磺基(-SO 3 M) - 腙化合物的N-原子的位置; B是直链或支链烷基,苯基,萘基或取代基杂环基; C是具有1至3个取代基的苯或萘; D是苯或萘; M是氢原子,碱金属或碱土金属; Me是原子序数为27〜29的金属离子; Y为卤素; X是氢原子或磺基,羧基,提供水溶性的膦酸基; R是直链或支链烷基; Q为-SO 2 CH = CH 2,或-SO 2 CH 2 CH 2 L(L为可被碱取代的基团)。 并且l,m,n独立地为0-3的整数。