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    • 2. 发明申请
    • MIXTURES OF REACTIVE DYES AND THEIR USE IN A METHOD FOR TRICHROMATIC DYEING OR PRINTING
    • 反应性染料的混合物及其在三色染色或印刷方法中的应用
    • WO2008055805A1
    • 2008-05-15
    • PCT/EP2007/061642
    • 2007-10-30
    • HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBHROENTGEN, GeorgTZIKAS, AthanassiosCHRISTNACHER, Hubert Jean Luc
    • ROENTGEN, GeorgTZIKAS, AthanassiosCHRISTNACHER, Hubert Jean Luc
    • C09B62/08C09B62/085C09B62/09C09B62/095C09B67/22
    • C09B62/4407C09B62/4413C09B62/4415C09B67/005C09B67/0059
    • Dye mixtures, comprising at least one dye of formula (1) and at least one dye from the group of formulae (2) and (3) wherein Q 1 is C 1 -C 4 alkyl, halogen or a radical -SO 2 -Z, Q 2 and Q 3 are each independently of the other C 1 -C 4 alkoxy, Q 4 is C 1 -C 4 alkoxy, C 1 -C 4 alkyl, halogen or sulfo, Q 5 is C 1 -C 4 alkoxy, C 1 -C 4 alkyl, C 1 -C 4 alkanoylamino, ureido, halogen or sulfo, R 1 , R 2 and R 3 are each independently of the others hydrogen or unsubstituted or substituted C 1 -C 4 alkyl, k and q are each independently of the other the number 0 or 1, n and p are each independently of the other the number 0, 1 or 2, m is the number 0, 1, 2 or 3, t is the number 1, 2 or 3, X 1 , X 2 and X 3 are each independently of the others halogen, 3-carboxypyridin-1-yl, 3- carbamoylpyridin-1-yl or a non-fibre-reactive substituent, and T 1 , T 2 and T 3 are each independently of the others a non-fibre-reactive substituent or a fibre- reactive radical of formula (4a): -NH-(CH 2 ) 2-3 -SO 2 -Z, (4b): -NH-(CH 2 ) 2-3 -O-(CH 2 ) 2-3 -SO 2 -Z, (4c), (4d), (4e), (4f) or (4g),wherein (R 4 ) 0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy and sulfo, Z is vinyl or a radical -CH 2 -CH 2 -U and U is a group removable under alkaline conditions, Q is a group -CH(Hal)-CH 2 -Hal or -C(Hal)=CH 2 , and Hal is halogen, are suitable especially for the dichromatic or trichromatic dyeing or printing of cellulosic fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.
    • 包含至少一种式(1)的染料和至少一种式(2)和(3)基团的染料的染料混合物,其中Q 1是C 1〜 -C 4 - 烷基,卤素或-SO 2 -S-基团,Q 2和Q 3个基团各自为 独立于其它C 1 -C 4烷氧基,Q 4是C 1 -C 4烷基 C 1 -C 4烷氧基,C 1 -C 4烷基,卤素或磺基,Q 5是C 1 -C 4烷基, -C 4烷氧基,C 1 -C 4烷基,C 1 -C 4烷基,C 1 -C 4烷基,C 1 -C 4烷基, 烷基氨基,脲基,卤素或磺基,R 1,R 2和R 3各自独立地为氢或未取代或取代的 C 1 -C 4烷基,k和q各自独立地为0或1的另一个,n和p各自独立地为数个0,1或2的数个 或2,m是数字0,1,2或3,t是数字1,2或3,X 1,X 2和X 3 各自独立于o 卤素,3-羧基吡啶-1-基,3-氨基甲酰基吡啶-1-基或非纤维反应性取代基,T 1,T 2和T 2, -NH-(CH 2 2)2,其中R 1和R 3各自独立地为非纤维反应性取代基或式(4a)的纤维反应性基团: -3-SO 2 -Z,(4b):-NH-(CH 2 2)2-3 - -O- (4c),(4d),(4e),(4f)或(4e)或(3) (4g),其中(R 4)0-2-2表示0-2个与卤素取代基相同或不同的取代基,C 1〜 C 4烷基,C 1 -C 4烷氧基和磺基,Z是乙烯基或基团-CH 2, -CH 2 -O-U,U是在碱性条件下可除去的基团,Q是基团-CH(Hal)-CH 2 -Hal或-C(Hal)= CH 2,Hal是卤素,特别适用于纤维素纤维材料的二色或三色染色或印花,并且具有良好重现性的产量染色或印花 良好的全面坚牢性。
    • 5. 发明申请
    • DICYCLIC METAL COMPLEX FORMAZAN DERIVATIVES, PROCESS FOR PRODUCING THE SAME, COMPOSITION CONTAINING THE SAME AND DYEING PROCESS EMPLOYING THE SAME
    • 二元金属络合物衍生物,其制造方法,含有该组合物的组合物和使用其的染色方法
    • WO1996033240A2
    • 1996-10-24
    • PCT/KR1996000049
    • 1996-04-08
    • KYUNG-IN SYNTHETIC CORPORATIONKIM, Dong, GilCHO, Sung, Yong
    • KYUNG-IN SYNTHETIC CORPORATION
    • C09B00/00
    • C09B62/4407C09B50/00
    • The present invention relates to dicyclic metal formazan derivatives used for dye. To overcome these problems, the present invention provides a novel dicyclic metal formanan derivatives represented by formula (1) which has excellent dyeing property and fastness, wherein A is benzene or naphthalene having 1 to 3 substituent groups and sulfo group (-SO3M) in ortho-position for N-atom of hydrazone compound; B is straight- or branched-chain alkyl group, phenyl group, naphthyl group or substituent heterocyclic group; C is benzene or naphthalene having from 1 to 3 substituent groups; D is benzene or naphthalene; M is hydrogen atom, alkali metal or alkali earth metal; Me is metal ion of atomic number 27 to 29; Y is halogen; X is hydrogen atom or sulfo group, carboxyl group, phosphonic group providing solubility for water; R is straight- or branched-chain alkyl group; Q is -SO2CH=CH2, or -SO2CH2CH2L (L is a group which may be substituted by alkali); and l, m, n are independently an integer from 0 to 3.
    • 本发明涉及用于染料的二环金属甲an衍生物。 为了克服这些问题,本发明提供了一种具有优异的染色性和牢度的由式(1)表示的新型二环金属甲酰胺衍生物,其中A是苯或萘具有1至3个取代基和磺基(-SO 3 M) - 腙化合物的N-原子的位置; B是直链或支链烷基,苯基,萘基或取代基杂环基; C是具有1至3个取代基的苯或萘; D是苯或萘; M是氢原子,碱金属或碱土金属; Me是原子序数为27〜29的金属离子; Y为卤素; X是氢原子或磺基,羧基,提供水溶性的膦酸基; R是直链或支链烷基; Q为-SO 2 CH = CH 2,或-SO 2 CH 2 CH 2 L(L为可被碱取代的基团)。 并且l,m,n独立地为0-3的整数。