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    • 6. 发明申请
    • METHOD FOR PRODUCING PROPYLENE OXIDE
    • 生产丙烯氧化物的方法
    • WO2008156205A1
    • 2008-12-24
    • PCT/JP2008/061592
    • 2008-06-19
    • SUMITOMO CHEMICAL COMPANY, LIMITEDABEKAWA, HiroakiKAWABATA, TomonoriYAKO, Makoto
    • ABEKAWA, HiroakiKAWABATA, TomonoriYAKO, Makoto
    • C07D301/06
    • C07D301/06Y02P20/52
    • There is disclosed a method for producing propylene oxide, which includes: reacting propylene, oxygen, and hydrogen in the presence of a noble metal catalyst and a titanosilicate catalyst in a liquid phase containing a polycyclic compound, which is unsubstituted or substituted with at least one substituent selected from Group B below, wherein the polycyclic compound is composed of two or more identical or different ring compounds selected from Group A below and the ring compounds are fused, directly bonded, or bonded by a linkage group selected from the group consisting of an oxygen atom, carbon chain, and a group composed of oxygen atom(s) and a carbon chain, provided that said polycyclic compound is not a polycyclic compound having hydroxy groups or oxo groups at para or. ortho positions. Group A consisting of benzene, cyclopentadiene, cycloheptatriene, furane, pyrane, cyclopentene, cyclopentane, cyclohexane, cyclohexene, cyclohexadiene, cycloheptane, cycloheptene, and cycloheptadiene. Group B consisting of halogen atom, alkyl group, alkenyl group, alkoxy group, hydroxyalkyl group, acyl group, oxo group, hydroxy group, and cyano group.
    • 公开了一种生产环氧丙烷的方法,其包括:在贵金属催化剂和钛硅酸盐催化剂存在下,在含有多环化合物的液相中使丙烯,氧和氢反应,该多环化合物是未取代的或被至少一个 取代基,其中所述多环化合物由两种或更多种相同或不同的选自下述A组的环化合物组成,并且所述环化合物通过选自以下的连接基团进行稠合,直接键合或键合: 氧原子,碳链和由氧原子和碳链组成的基团,条件是所述多环化合物不是在对位或具有羟基或氧代基的多环化合物。 邻位。 A组由苯,环戊二烯,环庚三烯,呋喃,吡喃,环戊烯,环戊烷,环己烷,环己烯,环己二烯,环庚烷,环庚烯和环庚二烯组成。 B族由卤素原子,烷基,烯基,烷氧基,羟基烷基,酰基,氧代基,羟基和氰基组成。