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1. 发明申请

WO2003000415A1 CATALYTIC REFORMING CATALYST ACTIVATION 审中-公开
标题翻译：催化重整催化剂活化
公开(公告)号：WO2003000415A1
公开(公告)日：2003-01-03
申请号：PCT/US2002/015270
申请日：2002-05-10
申请人： PHILLIPS PETROLEUM COMPANY , LIN, Fan-Nan , PARSONS, John, S. , MACAHAN, Don, H. , LIMOGES, Brian
发明人： LIN, Fan-Nan , PARSONS, John, S. , MACAHAN, Don, H. , LIMOGES, Brian
IPC分类号： B01J38/04
CPC分类号： B01J37/22 , B01J23/62 , B01J23/6567 , C10G35/06 , C10G35/09
摘要： A reforming catalyst containing a Group VIII metal, or a Group VII B metal, or tin or germanium, or copper, or selenium or combinations of any two or more metals or oxides thereof is activated by: a) continuously flowing a reducing gas over the catalyst for contact with the catalyst; (b) during step a), flowing a halogen-containing compound over the catalyst for contact with the catalsyt for a first time period, wherein the first time period is greater than about 1 minute, and wherein the first time period is less than about 60 minutes; and (c) following step b), and during step a), substantially discontinuing the flow of the halogen-containing compound over the catalyst for a second time period, wherein the second time period is greater than about 1 minute. Alternatively, the catalyst can be activated in an activation zone by: 1) removing water from the activation zone; 2) reducing iron oxide contained in the activation zone in the presence of a reducing gas thereby forming reduced iron and water; 3) removing water from the activation zone; 4) reducing the metal oxide of the catalyst in the presence of a reducing gas thereby forming reduced metal and water; 5) removing water from the activation zone; 6) during step 4), flowing a halogen-containing compound over the catalyst for contact with the catalyst for a first time period; and 7) following step 6) and during step 4), substancially discontinuing the flow of halogen- containing compound over the catalyst for a second time period.
摘要翻译：含有第Ⅷ族金属或ⅦB族金属，锡或锗，铜或硒或其任何两种或多种金属或其氧化物的组合的重整催化剂通过以下方式活化：a）将还原气体连续流过与催化剂接触的催化剂; （b）在步骤a）期间，使含卤素化合物在所述催化剂上与所述催化剂接触第一时间段，其中所述第一时间段大于约1分钟，并且其中所述第一时间段小于约 60分钟; 和（c）在步骤b）之后，并且在步骤a）期间，基本上使催化剂上的含卤素化合物在第二时间段内停止，其中第二时间段大于约1分钟。或者，催化剂可以通过以下方式在活化区中活化：1）从活化区除去水; 2）在还原气体存在下还原活化区中所含的氧化铁，从而形成还原的铁和水; 3）从活化区去除水分; 4）在还原气体的存在下还原催化剂的金属氧化物，从而形成还原的金属和水; 5）从活化区去除水; 6）在步骤4）期间，使含卤素化合物在催化剂上与催化剂接触第一次; 和7）在步骤6）之后和在步骤4）期间，使催化剂中的含卤素化合物的流动在第二时间段内逐渐停止。

2. 发明申请

WO01038273A1 A PROCESS FOR THE CONVERSION OF ETHYLENE TO VINYL CHLORIDE, AND NOVEL CATALYST COMPOSITIONS USEFUL FOR SUCH PROCESS 审中-公开
标题翻译：乙烯转化为氯乙烯的方法和用于此过程的新型催化剂组合物
公开(公告)号：WO01038273A1
公开(公告)日：2001-05-31
申请号：PCT/US2000/027272
申请日：2000-10-03
IPC分类号： C07C17/152 , B01J23/10 , B01J23/72 , B01J23/83 , B01J27/06 , B01J27/10 , B01J27/122 , B01J27/125 , B01J27/135 , B01J27/138 , B01J27/32 , B01J35/10 , B01J37/03 , B01J37/22 , B01J37/24 , B01J38/16 , C07B61/00 , C07C1/30 , C07C11/06 , C07C17/15 , C07C17/154 , C07C17/156 , C07C17/158 , C07C17/25 , C07C17/38 , C07C19/045 , C07C21/04 , C07C21/06 , C07C21/067 , C07C21/073
CPC分类号： C07C17/25 , B01J23/10 , B01J23/72 , B01J23/83 , B01J27/10 , B01J27/122 , B01J35/10 , B01J37/03 , B01J37/031 , B01J37/036 , B01J37/22 , C07C17/15 , C07C17/152 , C07C17/154 , C07C17/156 , C07C17/158 , C07C21/06 , C07C19/045 , C07C21/073 , C07C21/067 , C07C21/04
摘要： This invention is a process for producing vinyl chloride from an ethylene-containing feed, oxygen, and a chlorine source in the presence of a catalyst. The process permits direct production of vinyl chloride in a single reactor system, and further permits ethane to be used as the C2 hydrocarbon feed with recycle of ethylene from the product stream to constitute the ethylene specified for the feed. This invention in another aspect concerns also a composition of matter, and a method for making the composition, wherein the composition is useful as a catalyst for the vinyl chloride process. The composition comprises a rare earth-containing material, with the proviso that the catalyst prepared therefrom is substantially free of iron and copper and with the further proviso that when cerium is present the catalyst further comprises at least one more rare earth element other than cerium.
摘要翻译：本发明是在催化剂存在下由含乙烯的进料，氧气和氯源生产氯乙烯的方法。该方法允许在单个反应器系统中直接生产氯乙烯，并且进一步允许乙烷用作C2烃进料，其中乙烯从产物流中再循环以构成为进料指定的乙烯。在另一方面，本发明还涉及一种物质组合物和一种制备该组合物的方法，其中该组合物可用作氯乙烯方法的催化剂。所述组合物包含含稀土材料，条件是由其制备的催化剂基本上不含铁和铜，另外条件是当存在铈时，催化剂还包含至少一种除铈以外的至少一种稀土元素。

3. 发明申请

WO2010151231A1 DOPED CATALYTIC CARBONACEOUS COMPOSITE MATERIALS AND USES THEREOF 审中-公开
标题翻译： DOPED催化碳纳米复合材料及其用途
公开(公告)号：WO2010151231A1
公开(公告)日：2010-12-29
申请号：PCT/SG2010/000233
申请日：2010-06-22
申请人： NANYANG TECHNOLOGICAL UNIVERSITY , LIM, Teik Thye , YAP, Pow Seng , SRINIVASAN, Madhavi , FANE, Anthony Gordon
发明人： LIM, Teik Thye , YAP, Pow Seng , SRINIVASAN, Madhavi , FANE, Anthony Gordon
IPC分类号： B01J37/02 , B01J21/06 , B01J21/18 , B01J23/00 , B01J27/20 , B01J33/00 , B01J37/08 , C02F1/30 , C02F1/32
CPC分类号： C02F1/32 , B01J21/06 , B01J21/063 , B01J21/18 , B01J23/755 , B01J27/24 , B01J32/00 , B01J35/002 , B01J35/004 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1061 , B01J37/0219 , B01J37/024 , B01J37/036 , B01J37/08 , B01J37/20 , B01J37/22 , B01J37/28 , B82Y30/00 , C02F1/44 , C02F1/725 , C02F2101/301 , C02F2101/305 , C02F2103/343 , Y02W10/37
摘要： The present invention is directed to a composite material of a carbonaceous substance comprising a doped catalytic compound obtained by a sol-gel method. In one embodiment, the method comprises mixing a hydrolyzed solution comprising a precursor of a catalytic material with a carbonaceous material to obtain a sol. The sol is afterwards incubated while at the same time it is mixed. After incubation the sol is condensated to form a gel. After condensation the gel formed is subjected to a first calcination carried out in an oxidizing environment followed by a second calcination carried out in a non-oxidizing environment. The non-oxidizing environment comprises a second dopant comprising precursor material. Also, a solution of a first dopant comprising precursor material is added to the solution comprising an organometallic precursor of a catalytic material before hydrolyzation or before subjecting the gel to calcination, i.e. after hydrolyzation. In a further aspect, the present invention can refer to a method of removing pollutants comprised in a liquid stream by subjecting the liquid stream to a composite material described herein. In another aspect, the present invention is directed to a photocatalytic oxidation reactor comprising a composite material including a doped photocatalytic material.
摘要翻译：本发明涉及包含通过溶胶 - 凝胶法获得的掺杂催化剂的含碳物质的复合材料。在一个实施方案中，该方法包括将包含催化材料的前体的水解溶液与含碳材料混合以获得溶胶。然后将溶胶同时孵育，同时混合。孵育后，将溶胶冷凝形成凝胶。在冷凝后，将形成的凝胶在氧化环境中进行第一次煅烧，然后在非氧化环境中进行第二次煅烧。非氧化环境包括包含前体材料的第二掺杂物。此外，将包含前体材料的第一掺杂剂的溶液加入到包含催化材料的有机金属前体的溶液中，然后水解或在使凝胶进行煅烧之前，即水解后。在另一方面，本发明可以通过使液体流经由本文所述的复合材料来去除包含在液体流中的污染物的方法。另一方面，本发明涉及包含掺杂的光催化材料的复合材料的光催化氧化反应器。

4. 发明申请

WO2006053135A2 DESULFURIZATION AND NOVEL PROCESS FOR SAME 审中-公开
标题翻译：相同的脱硫和新工艺
公开(公告)号：WO2006053135A2
公开(公告)日：2006-05-18
申请号：PCT/US2005/040759
申请日：2005-11-09
申请人： CONOCOPHILLIPS COMPANY , TURAGA, Uday, T. , CHOUDHARY, Tushar, V.
发明人： TURAGA, Uday, T. , CHOUDHARY, Tushar, V.
IPC分类号： C10G25/00 , C10G25/12 , B01J27/125
CPC分类号： B01J37/22 , B01J23/80 , B01J37/0045 , B01J37/16 , C10G25/003 , C10G2300/104 , C10G2300/1055 , C10G2300/202 , C10G2400/02 , C10G2400/04
摘要： A composition comprising a metal oxide and a promoter and a halogen, wherein at least a portion of the promoter is present as a reduced valence promoter and methods of preparing such composition are disclosed. The thus-obtained composition is employed in a desulfurization zone to remove sulfur from a hydrocarbon stream.
摘要翻译：包含金属氧化物和助催化剂和卤素的组合物，其中至少一部分促进剂作为还原价促进剂存在，并且公开了制备该组合物的方法。由此获得的组合物用于脱硫区以从烃流中除去硫。

5. 发明申请

WO2004002971A1 A METHOD FOR THE START-UP OF AN EPOXIDATION PROCESS, A CATALYST AND A PROCESS FOR THE EPOXIDATION OF AN OLEFIN 审中-公开
标题翻译：环氧化方法的启动方法，催化剂和烯烃环氧化方法
公开(公告)号：WO2004002971A1
公开(公告)日：2004-01-08
申请号：PCT/US2003/019828
申请日：2003-06-24
申请人： SHELL OIL COMPANY , EVANS, Wayne, Errol
发明人： EVANS, Wayne, Errol
IPC分类号： C07D301/10
CPC分类号： B01J23/66 , B01J21/04 , B01J23/50 , B01J23/688 , B01J37/22 , C07D301/10
摘要： A method for the start-up of a process for the epoxidation of an olefin, which method process comprises(a) pre-soaking a silver-based highly selective epoxidation catalyst with an organic halide, and (b) passing over the pre-soaked catalyst a feed which is free of organic halide or which comprises an organic halide at a concentration of at most 2´10 -4 mole-%, calculated on the basis of the halogen content relative to the total feed, for a period of more than 16 hours up to 200 hours; a catalyst suitable for the epoxidation of an olefin, which catalyst is obtainable by the said method; anda process for the epoxidation of an olefin, which process comprises the said method and wherein subsequently the catalyst is contacted with a feed comprising the olefin, oxygen and an organic halide wherein the concentration of the organic halide is at least 0.2´10 -4 mole-% higher than the concentration applied in step (b), calculated on the basis of the halogen content relative to the total feed.
摘要翻译：一种用于烯烃环氧化方法启动的方法，该方法包括（a）用有机卤化物预浸泡银基高选择性环氧化催化剂，和（b）经过预浸渍催化剂不含有机卤化物的进料，或者包含基于相对于总进料的卤素含量计算的浓度至多为2×10 -4摩尔％的有机卤化物，持续一段时间超过16小时多达200小时; 适用于烯烃环氧化的催化剂，该催化剂可通过所述方法获得; 以及烯烃的环氧化方法，该方法包括所述方法，其中随后将催化剂与包含烯烃，氧和有机卤化物的进料接触，其中有机卤化物的浓度为至少0.2'10 <-4 基于相对于总进料的卤素含量计算，步骤（b）中施加的浓度高于摩尔％。

6. 发明申请

WO01005501A1 SUPPORTED METAL CATALYST, PREPARATION AND APPLICATIONS FOR DIRECTLY MAKING HYDROGEN PEROXIDE 审中-公开
标题翻译：支持金属催化剂，直接制造过氧化氢的制备和应用
公开(公告)号：WO01005501A1
公开(公告)日：2001-01-25
申请号：PCT/FR2000/001552
申请日：2000-06-07
IPC分类号： B01J8/00 , B01J8/22 , B01J19/18 , B01J23/10 , B01J23/38 , B01J23/40 , B01J23/44 , B01J27/185 , B01J35/10 , B01J37/02 , C01B15/029
CPC分类号： B01J27/13 , B01J8/006 , B01J8/222 , B01J8/228 , B01J19/1881 , B01J23/38 , B01J23/40 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J37/0201 , B01J37/22 , B01J2208/00176 , B01J2208/00212 , B01J2219/185 , C01B15/029
摘要： The invention concerns a supported metal catalyst based on at least one metal selected in the group M consisting of palladium, platinum, ruthenium, rhodium, iridium, holmium, osmium and gold, used for directly making hydrogen peroxide from hydrogen and oxygen. The invention also concerns a method for making said catalyst comprising successively an impregnating step with a solution based on one or several salt(s) of at least one metal of group M on a support, and a reduction step characterised in that at the end of the reduction step, the catalyst is treated with an aqueous acid solution comprising bromine and bromide ions. The catalyst is characterised by metal or crystallised metal aggregates with size ranging between 0.1 and 20 microns and preferably between 0.1 and 10 microns. The supported bimetal catalyst is preferred, for example Pd-Pt, Au-Pt, Pd-Ho and Pd-Au.
摘要翻译：本发明涉及一种载体金属催化剂，其基于选自由钯，铂，钌，铑，铱，钬，锇和金组成的组M中的至少一种金属，用于从氢气和氧气直接制备过氧化氢。本发明还涉及一种制备所述催化剂的方法，其包括基于载体上至少一种M族金属的一种或多种盐的溶液的浸渍步骤，以及还原步骤，其特征在于在末端还原步骤，用包含溴和溴离子的酸性水溶液处理催化剂。催化剂的特征在于金属或结晶的金属聚集体，其尺寸范围为0.1至20微米，优选为0.1至10微米。优选负载的双金属催化剂，例如Pd-Pt，Au-Pt，Pd-Ho和Pd-Au。

7. 发明申请

WO00030748A1 HYDROCARBON REFORMING PROCESS USING A BOUND HALIDED ZEOLITE CATALYST 审中-公开
标题翻译：碳氢化合物催化剂的碳氢化合物改性方法
公开(公告)号：WO00030748A1
公开(公告)日：2000-06-02
申请号：PCT/US1999/004161
申请日：1999-02-25
IPC分类号： B01J29/064 , B01J29/068 , B01J29/62 , B01J37/06 , B01J37/22 , C10G35/06 , C10G35/095
CPC分类号： B01J29/61 , B01J29/064 , B01J29/62 , B01J37/06 , B01J37/22 , C10G35/095
摘要： A catalytic reforming process comprising the catalytic conversion of hydrocarbons to aromatics, said process comprising treating a halided zeolite catalyst (hiz-cat) containing a Group VIII metal at commercial startup conditions and then reforming hydrocarbons, wherein said catalyst is prepared by washing a bound zeolite catalyst base or a bound zeolite catalyst before halide addition. A preferred hiz-cat is a non-acidic Pt K L-zeolite catalyst prepared by a process that includes the steps of preparing a calcined silica-bound K L-zeolite catalyst base; washing said bound zeolite catalyst base with a liquid comprising water; and incorporating Pt and halogen-containing compound(s) comprising chlorine and fluorine into said washed catalyst base. Ammonium chloride and ammonium fluoride are preferred halide sources.
摘要翻译：一种催化重整方法，包括将烃催化转化成芳族化合物，所述方法包括在商业启动条件下处理含有第Ⅷ族金属的卤化沸石催化剂（氢氧化钾），然后重整烃，其中所述催化剂是通过洗涤结合的沸石催化剂底物或结合的沸石催化剂。优选的咪唑是通过包括以下步骤制备的非酸性Pt K L-沸石催化剂，所述方法包括制备煅烧二氧化硅结合的KL-沸石催化剂基质的步骤; 用包含水的液体洗涤所述结合的沸石催化剂基质; 并将含有氯和氟的Pt和含卤素的化合物掺入所述洗涤的催化剂基质中。氯化铵和氟化铵是优选的卤化物源。

8. 发明申请

WO2015026805A1 PtCu AND PtNi ELECTROCATALYSTS DOPED WITH IODINE 审中-公开
标题翻译： PtCu和PtNi电解质与碘化合物
公开(公告)号：WO2015026805A1
公开(公告)日：2015-02-26
申请号：PCT/US2014/051661
申请日：2014-08-19
申请人： GEORGETOWN UNIVERSITY
发明人： TONG, Yuye, J. , WANG, Honghui
IPC分类号： B01J23/40
CPC分类号： H01M4/8657 , B01J23/89 , B01J27/13 , B01J35/0013 , B01J35/0033 , B01J35/0086 , B01J37/10 , B01J37/22 , H01M4/8663 , H01M4/921 , H01M4/925 , H01M4/926 , H01M4/94 , H01M8/0202
摘要： Disclosed are metal alloy materials comprising iodine adsorbed onto the catalyst surface exhibiting surprisingly improved performance and durability in comparison with known electrocatalysts. Methods of preparation of the catalysts and methods of use thereof are also described. The materials include a core/shell structure that include a platinum alloy and layers of platinum atoms alloyed with up to about 10% metals, such as Mn, Fe, Co, Ni, Cu, Ru, Pd, Ag, or Au.
摘要翻译：公开了与已知的电催化剂相比，吸收到催化剂表面上的碘的金属合金材料表现出惊人的改善的性能和耐久性。还描述了制备催化剂的方法及其使用方法。这些材料包括核/壳结构，其包括铂合金和与高达约10％的金属如Mn，Fe，Co，Ni，Cu，Ru，Pd，Ag或Au合金的铂原子层。

9. 发明申请

WO2012022852A2 PROCEDE D'HYDROCRAQUAGE D'UNE CHARGE HYDROCARBONEE EN PRESENCE D'UN CATALYSEUR SULFURE PREPARE AU MOYEN D'UN OLIGOSACCHARIDE CYCLIQUE 审中-公开
标题翻译：在使用环状低聚物制备的硫化物催化剂存在下对烃类进料进行水解的方法
公开(公告)号：WO2012022852A2
公开(公告)日：2012-02-23
申请号：PCT/FR2011/000371
申请日：2011-06-24
申请人： IFP ENERGIES NOUVELLES , DIEHL, Fabrice , BONDUELLE, Audrey
发明人： DIEHL, Fabrice , BONDUELLE, Audrey
IPC分类号： C10G47/20 , B01J23/652 , B01J23/85 , B01J37/08 , C10G47/12 , C10G47/06 , B01J37/03 , B01J37/20 , B01J23/883 , B01J27/19
CPC分类号： B01J29/146 , B01J21/12 , B01J23/883 , B01J35/1019 , B01J35/1042 , B01J37/0201 , B01J37/0203 , B01J37/20 , B01J37/22 , B01J37/28 , C10G47/02 , C10G47/20 , C10G2300/1011 , C10G2300/202 , C10G2300/301 , C10G2300/4018 , C10G2300/703 , Y02P30/20
摘要： On décrit un procédé d'hydrocraquage d'une charge hydrocarbonée en présence d'un catalyseur comprenant un support acide et une phase active formée d'au moins un métal du groupe VIII et d'au moins un métal du groupe VIB, ledit catalyseur étant préparé selon un procédé comprenant successivement : i) une des étapes choisies parmi; i1 ) une étape de mise en contact d'un précatalyseur comprenant ledit métal du groupe VIII, ledit métal du groupe VIB et ledit support acide avec un oligosaccharide cyclique composé d'au moins 6 sous- unités glucopyranose liées en α-(1,4), i2) une étape de mise en contact dudit support acide avec une solution contenant un précurseur dudit métal du groupe VIII, un précurseur dudit métal du groupe VIB et un oligosaccharide cyclique composé d'au moins 6 sous-unités glucopyranose liées en α-(1,4), et i3) une première étape de mise en contact dudit support acide avec un oligosaccharide cyclique composé d'au moins 6 sous-unités glucopyranose liées en α-(1,4) suivie d'une deuxième étape de mise en contact du solide acide issu de ladite première étape avec un précurseur dudit métal du groupe VIII et un précurseur dudit métal du groupe VIB; ii) une étape de séchage, iii) une étape de traitement thermique, iv) une étape de sulfuration.
摘要翻译：本发明涉及在包含酸性载体和由至少一种第Ⅷ族金属和至少一种VIB族金属组成的活性相的催化剂存在下加氢裂解烃原料的方法，所述催化剂是根据包括 i）从以下各项中选择的步骤之一：i1）将包含所述VIII族金属，所述VIB族金属和所述酸性载体的预催化剂与由至少六个组成的环状低聚糖接触的步骤 α-（1,4）键合的吡喃葡萄糖亚基; i2）将所述酸性载体与含有所述VIII族金属的前体，所述第ⅥB族金属的前体的溶液和由至少六个在-1-（1,4）上键合的吡喃葡萄糖亚基组成的环状寡糖接触的步骤）; 和i3）将所述酸性载体与由至少六个在 - （1,4）键合的至少六个吡喃葡萄糖亚基组成的环状低聚糖接触的第一步骤，随后是将来自所述第一步骤的酸性固体置于接触中的第二步骤具有所述VIII族金属的前体和所述VIB族金属的前体; ii）干燥步骤; iii）热处理步骤; 和iv）硫化步骤。

10. 发明申请

WO2010008515A1 HALF-METALLOCENE CATALYST COMPOSITIONS AND THEIR POLYMER PRODUCTS 审中-公开
标题翻译：半金属催化剂组合物及其聚合物产品
公开(公告)号：WO2010008515A1
公开(公告)日：2010-01-21
申请号：PCT/US2009/004047
申请日：2009-07-13
申请人： CHEVRON PHILLIPS CHEMICAL COMPANY LP , MCDANIEL, Max, P. , THORN, Matthew, G. , BENHAM, Elizabeth, A.
发明人： MCDANIEL, Max, P. , THORN, Matthew, G. , BENHAM, Elizabeth, A.
IPC分类号： B01J31/22 , C08F4/6592 , C08F10/00 , C07F17/00
CPC分类号： C08F10/02 , B01J21/12 , B01J27/053 , B01J31/143 , B01J31/146 , B01J31/1616 , B01J31/1805 , B01J31/1845 , B01J31/2226 , B01J31/226 , B01J31/2291 , B01J31/2295 , B01J37/22 , B01J37/26 , B01J2531/0294 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08F2420/04 , Y10S526/943 , C08F4/6592 , C08F210/14
摘要： The present invention provides polymerization catalyst compositions employing half-metallocene compounds with a heteroatom-containing ligand bound to the transition metal. Methods for making these hybrid metallocene compounds and for using such compounds in catalyst compositions for the polymerization and copolymerization of olefins are also provided.
摘要翻译：本发明提供了采用具有与过渡金属结合的含杂原子的配体的半茂金属化合物的聚合催化剂组合物。还提供了制备这些杂化茂金属化合物和在催化剂组合物中用于烯烃聚合和共聚的方法。

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