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1. 发明申请

WO2007035442A2 CONDUCTIVE SILICONE AND METHODS FOR PREPARING SAME 审中-公开
标题翻译：导电硅胶及其制备方法
公开(公告)号：WO2007035442A2
公开(公告)日：2007-03-29
申请号：PCT/US2006/035922
申请日：2006-09-15
申请人： HYPERION CATALYSIS INTERNATIONAL, INC. , ZHOU, Chaohui , FISCHER, Alan
发明人： ZHOU, Chaohui , FISCHER, Alan
IPC分类号： H01L21/02
CPC分类号： H01B1/24 , B82Y30/00 , C08J5/005 , C08J2383/04 , C08K3/041 , C08K7/00 , C08L83/04
摘要： Methods of preparing conductive silicones containing carbon nanotubes is provided. The carbon nanotubes may be in individual form or in the form of aggregates having a macromorpology resembling the shape of a cotton candy, bird nest, combed yarn or open net. Preferred multiwalled carbon nanotubes have diameters no greater than 1 micron and preferred single walled carbon nanotubes have diameters less than 5 nm. Carbon nanotubes may be adequately dispersed in a silicone base resin by known conventional equipments and processes to prepare conductive silicone base resins. The conductive silicone base resin is then mixed with a curing agent to form conductive silicone elastomers.
摘要翻译：提供了制备含有碳纳米管的导电硅氧烷的方法。碳纳米管可以是具有类似于棉花糖，鸟巢，精梳纱或开放网的形状的大体积学的聚集体的单独形式或形式。优选的多壁碳纳米管的直径不大于1微米，优选的单壁碳纳米管的直径小于5nm。可以通过已知的常规设备和方法将碳纳米管充分分散在硅树脂基树脂中以制备导电硅树脂基树脂。然后将导电硅树脂基树脂与固化剂混合以形成导电硅橡胶。

2. 发明申请

WO2006130150A2 FUNCTIONALIZED SINGLE WALLED CARBON NANOTUBES 审中-公开
标题翻译：功能齐全的单壁碳纳米管
公开(公告)号：WO2006130150A2
公开(公告)日：2006-12-07
申请号：PCT/US2005/022413
申请日：2005-06-23
申请人： HYPERION CATALYSIS INTERNATIONAL, INC. , HOCH, Robert , FISCHER, Alan , TENNENT, Howard
发明人： HOCH, Robert , FISCHER, Alan , TENNENT, Howard
CPC分类号： B01J31/003 , B01J21/185 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/36 , D01F11/12 , D01F11/14 , H01M4/587 , H01M4/625 , H01M8/18 , Y02E60/528
摘要： Graphitic nanotubes, which includes tubular fullerenes (commonly called "buckytubes") and fibrils, which are functionalized by chemical substitution or by adsorption of functional moieties. More specifically the invention relates to single walled carbon nanotubes having diameters than 5 nanometers which are uniformly or non-uniformly substituted with chemical moieties or upon which certain cyclic compounds are adsorbed and to complex structures comprised of such functionalized nanotubes linked to one another. The invention also relates to methods for introducing functional groups onto the surface of such nanotubes. The invention further relates to uses for functionalized single walled carbon nanotubes.
摘要翻译：石墨纳米管，其包括管状富勒烯（通常称为“巴氏管”）和原纤维，其通过化学取代或功能部分的吸附官能化。更具体地，本发明涉及直径大于5纳米的单壁碳纳米管，其均匀或不均匀地被化学部分取代或者其上吸附某些环状化合物，以及由相互连接的这种官能化纳米管组成的复合结构。本发明还涉及在这种纳米管的表面上引入官能团的方法。本发明还涉及功能化单壁碳纳米管的用途。

3. 发明申请

WO2003038837A1 POLYMER CONTAINING FUNCTIONALIZED CARBON NANOTUBES 审中-公开
标题翻译：含有官能化碳纳米管的聚合物
公开(公告)号：WO2003038837A1
公开(公告)日：2003-05-08
申请号：PCT/US2002/034435
申请日：2002-10-29
申请人： HYPERION CATALYSIS INTERNATIONAL, INC.
发明人： NIU, Chunming , NGAW, Lein
IPC分类号： H01B1/00
CPC分类号： B82Y30/00 , B82Y10/00 , B82Y40/00 , C01B32/174 , C08K7/24 , H01B1/24 , Y10S977/745 , Y10S977/752 , Y10S977/753 , Y10T428/2982 , Y10T428/2998
摘要： A polymer composite composed of a polymerised mixture of functionalized I carbon nanotubes and monomer which chemically reacts with the functionalized nanotubes. The carbon nanotubes are functionalized by reacting with oxidising or other chemical media through chemical reactions or physical adsorption. The reacted surface carbons of the nanotubes are further functionalized with chemical moieties that react with the surface carbons and selected monomers. The functionalized nanotubes are first dispersed in an appropriate medium such as water, alcohol or a liquefied monomer and then the mixture is polymerised. The polymerisation results in polymer chains of increasing weight bound to the surface carbons of the nanotubes. The composite may consist of some polymer chains imbedded in the composite without attachment to the nanotubes. The resulting composite yields superior chemical, physical and electrical properties over polymer composites that are only physically mixed and without binding to the surface carbons of the nanotubes.
摘要翻译：由官能化的碳纳米管的聚合混合物和与官能化纳米管发生化学反应的单体组成的聚合物复合物。碳纳米管通过化学反应或物理吸附与氧化或其它化学介质反应而被官能化。纳米管的反应表面碳被进一步官能化化学部分与表面碳和选定的单体反应。功能化纳米管首先分散在合适的介质如水，醇或液化单体中，然后将该混合物聚合。聚合导致结合到纳米管的表面碳的增加的重量的聚合物链。复合材料可以由嵌入复合材料中的一些聚合物链组成而不连接到纳米管。所得到的复合材料比仅在物理上混合并且不与纳米管的表面碳结合的聚合物复合材料上产生优异的化学，物理和电学性质。

4. 发明申请

WO2002095098A1 MODIFICATION OF CARBON NANOTUBES BY OXIDATION WITH PEROXYGEN COMPOUNDS 审中-公开
标题翻译：用过氧化合物氧化改性碳纳米管
公开(公告)号：WO2002095098A1
公开(公告)日：2002-11-28
申请号：PCT/US2002/015828
申请日：2002-05-17
申请人： HYPERION CATALYSIS INTERNATIONAL, INC.
发明人： NIU, Chunming , MOY, David , MA, Jun , CHISHTI, Asif
IPC分类号： D01F9/12
CPC分类号： D01F11/122 , B82Y30/00 , H01G11/36 , Y02E60/13 , Y10S977/847
摘要： A method of chemically modifying carbon nanotubes having a diameter less than one micron comprising: contacting the nanotubes with a peroxygen compound selected from the group consisting of organic peroxyacids, inorganic peroxoacids and organic hydroperoxides, or a salt thereof, under oxidation conditions and thereby producing modified carbon nanotubes. Oxidation of the nanotubes increases the degree of dispersion of aggregates of nanotubes and aids in the disassembling of such aggregates. The dispersed nanotubes are used to prepare rigid structures and can be used in electrodes and capacitors.
摘要翻译：化学改性直径小于1微米的碳纳米管的方法包括：在氧化条件下使纳米管与选自有机过氧酸，无机过氧酸和有机氢过氧化物或其盐的过氧化合物接触，从而产生改性的碳纳米管。纳米管的氧化增加了纳米管聚集体的分散程度，有助于这种聚集体的分解。分散的纳米管用于制备刚性结构，可用于电极和电容器中。

5. 发明申请

WO1997045257A1 METHOD FOR DISENTANGLING HOLLOW CARBON MICROFIBERS, ELECTRICALLY CONDUCTIVE TRANSPARENT CARBON MICROFIBERS AGGREGATION FILM AND COATING COMPOSITION FOR FORMING SUCH FILM 审中-公开
标题翻译：用于分解中空微晶纤维的方法，用于形成这种薄膜的电导电透明碳微胶囊聚集膜和涂层组合物
公开(公告)号：WO1997045257A1
公开(公告)日：1997-12-04
申请号：PCT/US1997009064
申请日：1997-05-28
申请人： HYPERION CATALYSIS INTERNATIONAL, INC. , MITSUBISHI MATERIALS CORPORATION
发明人： HYPERION CATALYSIS INTERNATIONAL, INC. , MITSUBISHI MATERIALS CORPORATION , SHIBUTA, Daisuke
IPC分类号： B32B09/00
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/168 , C01B2202/22 , C01B2202/34 , C01B2202/36 , C09D5/24 , D01F9/127 , H01B1/04 , Y10T428/29 , Y10T428/2918 , Y10T428/2933
摘要： This invention relates to a method for disentangling hollow carbon microfibers and to the dispersion of hollow carbon microfibers, having an outer diameter of 3.5-70 nm and an aspect ratio of at least 5, to form transparent electrically conductive carbon film. Hollow carbon microfibers, treated with a strong acid such as sulfuric acid or oleum and an oxidizing agent such as nitric acid, are disentangled and dispersed homogeneously in a polar solvent. The obtained slurry in which microfibers are suspended can be coated on a substrate. The coating film is dried and a transparent electrically conductive film is formed. Because hollow carbon microfibers have self-cohesiveness characteristics and a film comprising the microfibers can be formed without a binder, a carbon microfiber aggregation film with excellent transparency can be obtained having a total transmittance of at least 80 % and haze value of at most 0.1 %. Further, this invention relates to an electrically conductive transparent film comprising a binder to improve the strength of the film.
摘要翻译：本发明涉及一种解开空心碳微纤维和中空碳微纤维分散体的方法，其外径为3.5-70nm，纵横比至少为5，形成透明导电碳膜。用强酸如硫酸或发烟硫酸处理的中空碳微纤维和硝酸等氧化剂，分散并均匀分散在极性溶剂中。将得到的悬浮有微纤维的浆料涂布在基材上。干燥涂膜，形成透明导电膜。由于空心碳微纤维具有自粘结特性，并且可以在没有粘合剂的情况下形成包含微纤维的膜，因此可以获得具有至少80％的总透射率和至多0.1％的雾度值的具有优异透明性的碳微纤维聚集膜，。此外，本发明涉及包含粘合剂以提高膜强度的导电透明膜。

6. 发明申请

WO1996018059A1 FUNCTIONALIZED FIBRILS 审中-公开
标题翻译：功能化纤维
公开(公告)号：WO1996018059A1
公开(公告)日：1996-06-13
申请号：PCT/US1995016159
申请日：1995-12-08
申请人： HYPERION CATALYSIS INTERNATIONAL, INC.
发明人： HYPERION CATALYSIS INTERNATIONAL, INC. , FISHER, Alan , HOCH, Robert , MOY, David , NIU, Chunming , OGATA, Naoya , TENNENT, Howard
IPC分类号： F16L11/00
CPC分类号： H01M4/60 , A61K33/44 , A61K48/00 , B82Y30/00 , B82Y40/00 , C01B32/152 , C01B32/174 , C01B2202/34 , C01B2202/36 , C07H21/02 , C07K17/06 , D01F9/12 , D01F11/14 , G01N33/5438 , G01N33/582 , G01N2030/8863 , G11C13/025 , Y10S530/811 , Y10S977/742 , Y10S977/746 , Y10S977/847 , Y10T428/249921 , Y10T428/25 , Y10T428/2927
摘要： Graphitic nanotubes, which includes tubular fullerenes (commonly called "buckytubes") and fibrils, which are functionalized by chemical substitution or by adsorption of functional moieties. More specifically the invention relates to graphitic nanotubes which are uniformly or non-uniformly substituted with chemical moieties or upon which certain cyclic compounds are adsorbed and to complex structures comprised of such functionalized fibrils linked to one another. The invention also relates to methods of introducing functional groups onto the surface of such fibrils.
摘要翻译：石墨纳米管，其包括管状富勒烯（通常称为“巴氏管”）和原纤维，其通过化学取代或功能部分的吸附官能化。更具体地，本发明涉及由化学部分均匀或不均匀取代或其上吸附某些环状化合物的石墨纳米管和由彼此连接的这种官能化原纤维组成的复合结构。本发明还涉及在这种原纤维的表面上引入官能团的方法。

7. 发明申请

WO1986003455A1 CARBON FIBRILS, METHOD FOR PRODUCING SAME, AND COMPOSITIONS CONTAINING SAME 审中-公开
标题翻译：碳纤维，其制造方法以及含有它们的组合物
公开(公告)号：WO1986003455A1
公开(公告)日：1986-06-19
申请号：PCT/US1985002390
申请日：1985-12-04
申请人： HYPERION CATALYSIS INTERNATIONAL, INC.
发明人： HYPERION CATALYSIS INTERNATIONAL, INC. , TENNETT, Howard, G.
IPC分类号： B32B09/00
CPC分类号： B01J35/06 , B29K2307/00 , B82Y30/00 , C04B14/386 , C04B35/62272 , C04B35/80 , C04B35/83 , C08K7/06 , D01F9/1272 , D01F9/1273 , D01F9/1275 , D01F9/1276 , D01F9/1277 , D01F9/1278 , D01F11/127 , F16D69/023 , H01B1/02 , H01B1/04 , H01B1/18 , Y10T428/2918 , Y10T428/2935 , Y10T428/2975 , Y10T428/30
摘要： An essentially cylindrical discrete carbon fibril characterized by a substantially constant diameter between about 3.5 and about 70 nanometers, e.g. between about 7 and 25 nanometers, length greater than about 10 times the diameter, an outer region of multiple essentially continuous layers of ordered carbon atoms and a distinct inner core region, each of the layers and core disposed substantially concentrically about the cylindrical axis of the fibril. Preferably the entire fibril is substantially free of thermal carbon overcoat. The invention further concerns a plurality of such fibrils. The fibril or plurality of fibrils of this invention may be produced by contacting for an appropriate period of time and at suitable pressure a suitable metal-containing particle with a suitable gaseous, carbon-containing compound, at a temperature between about 850 C and 1200 C, the ratio on a dry weight basis of carbon-containing compound to metal containing particle being at least about 100:1.
摘要翻译：基本上圆柱形的离散碳原子纤维，其特征在于在约3.5和约70纳米之间的基本上恒定的直径，例如在约7和25纳米之间，长度大于直径的约10 2倍，多个基本上连续的有序碳原子层的外部区域和不同的内芯区域，每个层和芯基本上同心地围绕圆柱体原纤维的轴线。优选地，整个原纤维基本上不含热碳外涂层。本发明还涉及多个这样的原纤维。本发明的原纤维或多个原纤维可以通过在合适的时间和合适的压力下将合适的含金属颗粒与合适的含气体的含碳化合物在约850℃ 和1200℃，含碳化合物与含金属颗粒的干重之比为至少约100:1。

8. 发明申请

WO2014150885A1 DEPOSITING NANOSCALE MATERIALS WITHIN COATED NETWORKED NANOFIBERS 审中-公开
标题翻译：在涂覆的网络纳米纤维中沉积纳米材料
公开(公告)号：WO2014150885A1
公开(公告)日：2014-09-25
申请号：PCT/US2014/024458
申请日：2014-03-12
申请人： HYPERION CATALYSIS INTERNATIONAL, INC.
发明人： FREYDINA, Evgeniya
IPC分类号： C01B31/04 , C04B35/00 , C01D3/00
CPC分类号： H01M4/663 , C04B35/52 , C04B35/62844 , C04B35/62847 , C04B35/62852 , C04B35/62881 , C04B35/62886 , C04B2235/3206 , C04B2235/3217 , C04B2235/3262 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3284 , C04B2235/3291 , C04B2235/3296 , C04B2235/44 , C04B2235/442 , C04B2235/443 , C04B2235/445 , C04B2235/448 , C04B2235/449 , C04B2235/5264 , C04B2235/5268 , C04B2235/5288 , H01M4/02 , H01M4/0402 , H01M4/0416 , H01M4/48 , H01M4/625
摘要： Provided herein is a method of manufacturing a nanoscale coated network, which includes providing nanofibers, capable of forming a network in the presence of a liquid vehicle and providing a nanoscale solid substance in the presence of the liquid vehicle. The method may also include forming a network of the nanofibers and the nanoscale solid substance and redistributing at least a portion of the nanoscale solid substance within the network to produce a network of nanofibers coated with the nanoscale solid substance. Also provided herein is a nanoscale coated network with an active material coating that is redistributed to cover and electrochemically isolate the network from materials outside the network.
摘要翻译：本文提供了制造纳米级涂层网络的方法，其包括提供能够在液体载体存在下形成网络并在液体载体存在下提供纳米尺度固体物质的纳米纤维。该方法还可以包括形成纳米纤维和纳米尺度固体物质的网络并且重新分布网络内的至少一部分纳米级固体物质以产生涂覆有纳米级固体物质的纳米纤维网络。本文还提供了具有活性材料涂层的纳米级涂层网络，其被重新分布以覆盖并电化学地将网络与网络外部的材料隔离。

9. 发明申请

WO2007092021A2 SINGLE-WALLED CARBON NANOTUBE CATALYST 审中-公开
标题翻译：单壁碳纳米管催化剂
公开(公告)号：WO2007092021A2
公开(公告)日：2007-08-16
申请号：PCT/US2006/004766
申请日：2006-02-07
申请人： HYPERION CATALYSIS INTERNATIONAL, INC. , MA, Jun , MOY, David
发明人： MA, Jun , MOY, David
CPC分类号： D01F9/127 , B01J21/005 , B01J23/002 , B01J23/005 , B01J23/78 , B01J37/0236 , B01J37/031 , B01J37/08 , B01J37/18 , B01J2523/00 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , B01J2523/22 , B01J2523/842 , B01J2523/845 , B01J2523/41 , B01J2523/31
摘要： An activated catalyst capable of selectively growing single-walled carbon nanotubes when reacted with carbonaceous gas is provided. The activated catalyst is formed by reducing a catalyst that comprises a complex oxide. The complex oxide may be of formula A x B y O z , wherein x/y ≤ 2 and z/y ≤ 4, A being a Group VIII element and B being an element such that an oxide of element B is not reducible in the presence of hydrogen at a temperature less than or equal to about 900°C. Methods of making, uses for and carbon fibril-containing product made with these activated catalysts are also provided.
摘要翻译：提供了当与含碳气体反应时能够选择性生长单壁碳纳米管的活化催化剂。活化的催化剂通过还原包含复合氧化物的催化剂而形成。复合氧化物可以具有下式：其中x /y≤2且z /y≤4，A为第VIII族元素和B是使元素B的氧化物在氢气存在下在小于或等于约900℃的温度下不可还原的元素。还提供了用这些活化的催化剂制造和使用含碳原纤维产品的方法。

10. 发明申请

WO2006135439A2 IMPROVED OZONOLYSIS OF CARBON NANOTUBES 审中-公开
标题翻译：改进的碳纳米管的臭氧分解
公开(公告)号：WO2006135439A2
公开(公告)日：2006-12-21
申请号：PCT/US2005/038116
申请日：2005-10-21
申请人： HYPERION CATALYSIS INTERNATIONAL, INC. , MA, Jun , CHISHTI, Asif , NGAW, Lein , FISCHER, Allen , BRADEN, Robert
发明人： MA, Jun , CHISHTI, Asif , NGAW, Lein , FISCHER, Allen , BRADEN, Robert
IPC分类号： C01B31/00 , C07C27/06
CPC分类号： H01G9/058 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/06 , C01B2202/36 , H01G11/34 , H01G11/36 , Y02E60/13
摘要： Methods of treating single walled and multiwalled carbon nanotubes with ozone are provided. The carbon nanotubes are treated by contacting the carbon nanotubes with ozone at a temperature range between 0°C and 100°C to yield functionalized nanotubes which are greater in weight than the untreated carbon nonotubes. The carbon nonotubes treated according to methods of the invention can be used to prepare complex structures such as three dimensional networks or rigid porous structures which can be utilized to form electordes for fabrication of improved electrochemical capacitors. Useful catalyst supports are prepared by contacting carbon nanotube structures such as carbon nanotube aggregates, three dimensional network or rigid porous structures with ozone in the temperature range between 0°C and 100°C.
摘要翻译：提供了用臭氧处理单壁和多壁碳纳米管的方法。通过使碳纳米管与臭氧在0℃和100℃之间的温度范围内接触来处理碳纳米管，得到的功能化纳米管的重量大于未处理的碳管。根据本发明方法处理的碳非管可用于制备复合结构，例如可用于形成用于制造改进的电化学电容器的电极的三维网络或刚性多孔结构。通过使碳纳米管结构如碳纳米管聚集体，三维网络或刚性多孔结构与臭氧在0℃至100℃之间的温度范围内接触来制备有用的催化剂载体。

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