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1. 发明申请

WO1998012368A1 PLASMA-TREATED CARBON FIBRILS AND METHOD OF MAKING SAME 审中-公开
标题翻译：等离子体处理碳纤维及其制备方法
公开(公告)号：WO1998012368A1
公开(公告)日：1998-03-26
申请号：PCT/US1997015550
申请日：1997-09-04
申请人： HYPERION CATALYSIS INTERNATIONAL, INC.
发明人： HYPERION CATALYSIS INTERNATIONAL, INC. , FISCHER, Alan , HOCH, Robert
IPC分类号： D01F09/12
CPC分类号： D01F9/12 , D01F11/16
摘要： A method of treating carbon fibrils and carbon fibril structures such as assemblages, aggregates and hard porous structures with a plasma to effect an alteration of the surface or structure of the carbon fibril or fibrils. The method can be utilized to functionalize, prepare for functionalization or otherwise modify the fibril surface via a "dry" chemical process.
摘要翻译：用等离子体处理碳原子纤维和碳原纤维结构例如组合物，聚集体和硬质多孔结构的方法，以改变碳原纤维或原纤维的表面或结构。该方法可用于通过“干”化学方法官能化，准备官能化或以其它方式改性原纤维表面。

2. 发明申请

WO1987007559A1 NOVEL CARBON FIBRILS, METHOD FOR PRODUCING SAME, AND COMPOSITIONS CONTAINING SAME 审中-公开
标题翻译：新型碳纤维及其制造方法，以及含有它们的组合物
公开(公告)号：WO1987007559A1
公开(公告)日：1987-12-17
申请号：PCT/US1987001317
申请日：1987-06-05
申请人： HYPERION CATALYSIS INTERNATIONAL, INC.
发明人： HYPERION CATALYSIS INTERNATIONAL, INC. , TENNENT, Howard, G. , BARBER, James, J. , HOCH, Robert
IPC分类号： B32B09/00
CPC分类号： B82Y30/00 , B01J27/20 , B01J35/06 , B29K2307/00 , C04B14/386 , C04B35/62272 , C08K7/06 , D01F9/1272 , D01F9/1273 , D01F9/1275 , D01F9/1276 , D01F9/1277 , D01F9/1278 , D01F11/127 , F16D69/023 , H01B1/02 , H01B1/04 , H01B1/16 , H01B1/18 , H01B1/24
摘要： A discrete carbon fibril characterized by a substantially constant diameter between about 3.5 and about 70 nanometers, length greater than about 5 times the diameter and less than about 100 times the diameter, an outer region of multiple essentially continuous layers of ordered carbon atoms and a distinct inner core region. The invention further concerns a plurality of such fibrils. The fibrils of this invention may be produced by contacting for an appropriate period of time and at a suitable pressure a suitable metal-containing particle with a suitable gaseous, carbon-containing compound, at a temperature between about 850 DEG C and 1200 DEG C, or by treating discrete carbon fibrils, characterized by a length greater than about 100 times the diameter. Carbon fibrils may also be continuously produced by continuously contacting for an appropriate period of time at suitable conditions. Another aspect of the invention concerns a composition of matter comprising a carbon fiber or a carbon plate and a plurality of fibrils. Carbon fibrils and compositions of matter comprising carbon fibrils are useful in composites having a matrix of e.g., an organic polymer, an inorganic polymer or a metal. In specific embodiments, the fibrils or the compositions of matter may be used to reinforce a structural material, to enhance the electrical or thermal conductivity of a material, to increase the surface area of an electrode or capacitor plate, to provide a support for a catalyst, or to shield an object from electromagnetic radiation.
摘要翻译：离散的碳原纤维，其特征在于基本上恒定的直径在约3.5和约70纳米之间，长度大于直径的约5倍且小于直径的约100倍，多个基本连续的有序碳原子层的外部区域和不同的内核区域。本发明还涉及多个这样的原纤维。本发明的原纤维可以通过在合适的时间和合适的压力下，将合适的含金属颗粒与合适的含气体的碳化合物在约850℃和1200℃之间的温度下接触来制备，或通过处理离散的碳原纤维，其特征在于长度大于直径的约100倍。碳原纤维也可以通过在合适的条件下连续接触适当的时间来连续生产。本发明的另一方面涉及包含碳纤维或碳板和多个原纤维的物质组成。碳原纤维和包含碳原纤维的物质组合物可用于具有例如有机聚合物，无机聚合物或金属的基质的复合材料中。在具体实施方案中，原纤维或物质组合物可用于加强结构材料，以增强材料的导电性或导热性，以增加电极或电容器板的表面积，以提供催化剂的载体，或屏蔽物体免受电磁辐射。

3. 发明申请

WO2006130150A2 FUNCTIONALIZED SINGLE WALLED CARBON NANOTUBES 审中-公开
标题翻译：功能齐全的单壁碳纳米管
公开(公告)号：WO2006130150A2
公开(公告)日：2006-12-07
申请号：PCT/US2005/022413
申请日：2005-06-23
申请人： HYPERION CATALYSIS INTERNATIONAL, INC. , HOCH, Robert , FISCHER, Alan , TENNENT, Howard
发明人： HOCH, Robert , FISCHER, Alan , TENNENT, Howard
CPC分类号： B01J31/003 , B01J21/185 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/36 , D01F11/12 , D01F11/14 , H01M4/587 , H01M4/625 , H01M8/18 , Y02E60/528
摘要： Graphitic nanotubes, which includes tubular fullerenes (commonly called "buckytubes") and fibrils, which are functionalized by chemical substitution or by adsorption of functional moieties. More specifically the invention relates to single walled carbon nanotubes having diameters than 5 nanometers which are uniformly or non-uniformly substituted with chemical moieties or upon which certain cyclic compounds are adsorbed and to complex structures comprised of such functionalized nanotubes linked to one another. The invention also relates to methods for introducing functional groups onto the surface of such nanotubes. The invention further relates to uses for functionalized single walled carbon nanotubes.
摘要翻译：石墨纳米管，其包括管状富勒烯（通常称为“巴氏管”）和原纤维，其通过化学取代或功能部分的吸附官能化。更具体地，本发明涉及直径大于5纳米的单壁碳纳米管，其均匀或不均匀地被化学部分取代或者其上吸附某些环状化合物，以及由相互连接的这种官能化纳米管组成的复合结构。本发明还涉及在这种纳米管的表面上引入官能团的方法。本发明还涉及功能化单壁碳纳米管的用途。

4. 发明申请

WO1996018059A1 FUNCTIONALIZED FIBRILS 审中-公开
标题翻译：功能化纤维
公开(公告)号：WO1996018059A1
公开(公告)日：1996-06-13
申请号：PCT/US1995016159
申请日：1995-12-08
申请人： HYPERION CATALYSIS INTERNATIONAL, INC.
发明人： HYPERION CATALYSIS INTERNATIONAL, INC. , FISHER, Alan , HOCH, Robert , MOY, David , NIU, Chunming , OGATA, Naoya , TENNENT, Howard
IPC分类号： F16L11/00
CPC分类号： H01M4/60 , A61K33/44 , A61K48/00 , B82Y30/00 , B82Y40/00 , C01B32/152 , C01B32/174 , C01B2202/34 , C01B2202/36 , C07H21/02 , C07K17/06 , D01F9/12 , D01F11/14 , G01N33/5438 , G01N33/582 , G01N2030/8863 , G11C13/025 , Y10S530/811 , Y10S977/742 , Y10S977/746 , Y10S977/847 , Y10T428/249921 , Y10T428/25 , Y10T428/2927
摘要： Graphitic nanotubes, which includes tubular fullerenes (commonly called "buckytubes") and fibrils, which are functionalized by chemical substitution or by adsorption of functional moieties. More specifically the invention relates to graphitic nanotubes which are uniformly or non-uniformly substituted with chemical moieties or upon which certain cyclic compounds are adsorbed and to complex structures comprised of such functionalized fibrils linked to one another. The invention also relates to methods of introducing functional groups onto the surface of such fibrils.
摘要翻译：石墨纳米管，其包括管状富勒烯（通常称为“巴氏管”）和原纤维，其通过化学取代或功能部分的吸附官能化。更具体地，本发明涉及由化学部分均匀或不均匀取代或其上吸附某些环状化合物的石墨纳米管和由彼此连接的这种官能化原纤维组成的复合结构。本发明还涉及在这种原纤维的表面上引入官能团的方法。

5. 发明申请

WO2016145207A1 METHOD OF CO-PROCESSING NANOCARBONS IN CARBON BLACK, AND PRODUCTS THEREFROM 审中-公开
标题翻译：炭黑中的纳米碳共处理方法及其制备方法
公开(公告)号：WO2016145207A1
公开(公告)日：2016-09-15
申请号：PCT/US2016/021791
申请日：2016-03-10
申请人： HYPERION CATALYSIS INTERNATIONAL, INC.
发明人： MA, Jun , TENNENT, Howard , HOCH, Robert
IPC分类号： B02C19/00 , B82Y40/00 , C09C1/46 , C09C1/48
CPC分类号： C09C1/56 , B82Y40/00 , C01P2004/03 , C01P2004/45
摘要： Provided herein is a method of forming a composition by co-processing nanocarbon aggregates and carbon black aggregates, which includes providing nanocarbon aggregates, providing carbon black aggregates, and mixing the nanocarbon aggregates and the carbon black aggregates such that the nanocarbon aggregates disperse into looser aggregates of nanocarbons and carbon black, or individualized nanocarbons dispersed among the carbon black aggregates.
摘要翻译：本文提供了通过共处理纳米碳聚集体和炭黑聚集体形成组合物的方法，其包括提供纳米碳聚集体，提供炭黑聚集体，以及混合纳米碳聚集体和炭黑聚集体，使得纳米碳聚集体分散到松散聚集体的纳米碳和炭黑，或分散在碳黑聚集体之间的个体化纳米碳。

6. 发明申请

WO2006065431A2 METHOD FOR PREPARING CATALYST SUPPORTS AND SUPPORTED CATALYSTS FROM SINGLE WALLED CARBON NANOTUBES 审中-公开
标题翻译：从单壁碳纳米管制备催化剂载体和负载催化剂的方法
公开(公告)号：WO2006065431A2
公开(公告)日：2006-06-22
申请号：PCT/US2005/041604
申请日：2005-11-16
申请人： HYPERION CATALYSIS INTERNATIONAL, INC. , TENNENT, Howard , MA, Jun , MOY, David , FISCHER, Alan , HOCH, Robert
发明人： TENNENT, Howard , MA, Jun , MOY, David , FISCHER, Alan , HOCH, Robert
IPC分类号： B01J21/18 , B32B3/00 , B32B9/00 , B01J23/00
CPC分类号： B82Y30/00 , B01J21/185 , B01J23/40 , B01J35/1023 , B01J35/1061 , B01J35/109 , B01J37/0009 , B01J37/04 , Y02P20/582 , Y10T428/249962 , Y10T428/249967 , Y10T428/25 , Y10T428/2918 , Y10T428/2938 , Y10T428/30
摘要： A new method for preparing a supported catalyst is herein provided. A carbon nanotube structure such as a rigid porous structure is formed from single walled carbon nanotubes. A metal catalyst is then loaded or deposited onto the carbon nanotubes structure. The loaded carbon nanotube is preferably ground to power form.
摘要翻译：本文提供了制备负载型催化剂的新方法。诸如刚性多孔结构的碳纳米管结构由单壁碳纳米管形成。然后将金属催化剂装载或沉积到碳纳米管结构上。负载的碳纳米管优选被研磨成功率形式。

7. 发明申请

WO2006055679A2 METHOD FOR PREPARING SINGLE WALLED CARBON NANOTUBES 审中-公开
标题翻译：制备单壁碳纳米管的方法
公开(公告)号：WO2006055679A2
公开(公告)日：2006-05-26
申请号：PCT/US2005/041622
申请日：2005-11-16
申请人： HYPERION CATALYSIS INTERNATIONAL, INC. , ZHANG, Xinjie , MA, Jun , TENNENT, Howard , HOCH, Robert
发明人： ZHANG, Xinjie , MA, Jun , TENNENT, Howard , HOCH, Robert
IPC分类号： C01B31/02
CPC分类号： B82Y40/00 , B01J23/881 , B01J23/882 , B82Y30/00 , C01B32/162 , C01B2202/02 , C01B2202/26 , C01B2202/30 , C01B2202/34 , Y10S977/843
摘要： Methods of preparing single walled carbon nanotubes are provided. Carbon containing gas is contacted with a supported metal catalyst under reaction conditions to yield at least 90% single walled carbon nanotubes and at least 1 gram single walled carbon nanotubes/gram metal catalyst. The support material may be calcined at temperatures between 150 and 600°C, and may have at least one oxidized planar surface. Reaction conditions include less than 10 atmospheres pressure and less than 800°C.
摘要翻译：提供了制备单壁碳纳米管的方法。含碳气体在反应条件下与负载型金属催化剂接触以产生至少90％单壁碳纳米管和至少1克单壁碳纳米管/克金属催化剂。载体材料可以在150-600℃的温度下煅烧，并且可以具有至少一个氧化的平坦表面。反应条件包括小于10大气压和小于800℃。

8. 发明申请

WO2009094543A1 PROCESSES FOR THE RECOVERY OF CATALYTIC METAL AND CARBON NANOTUBES 审中-公开
标题翻译：催化金属和碳纳米管的回收方法
公开(公告)号：WO2009094543A1
公开(公告)日：2009-07-30
申请号：PCT/US2009/031840
申请日：2009-01-23
申请人： HYPERION CATALYSIS INTERNATIONAL, INC. , MA, Jun , HOCH, Robert
发明人： MA, Jun , HOCH, Robert
IPC分类号： B01J38/00 , B01J38/48
CPC分类号： B01J38/48 , B01J21/185 , B01J21/20 , B01J23/44 , B01J23/96 , B01J38/60 , B82Y30/00 , B82Y40/00 , C01B32/17 , Y02P20/584
摘要： A new method for recovering a catalytic metal and carbon nanotubes from a supported catalyst is provided. The carbon nanotube, including carbon nanotube structures, may serve as the support for the catalytic metal. The valence state of the catalytic metal, if not already in the positive state, is raised to a positive state by contacting the supported catalyst with a mild oxidizing agent under conditions which does not destroy the carbon nanotube. The supported catalyst is simultaneously or subsequently contacted with an acid solution to dissolve the catalytic metal without dissolving the carbon nanotube.
摘要翻译：提供了一种从负载催化剂中回收催化金属和碳纳米管的新方法。包括碳纳米管结构在内的碳纳米管可以用作催化金属的载体。在不破坏碳纳米管的条件下，通过使负载型催化剂与温和氧化剂接触，将催化金属的价态（如果不是正态）提高到正态。负载的催化剂同时或随后与酸溶液接触以溶解催化金属而不溶解碳纳米管。

9. 发明申请

WO2008051239A2 MIXED STRUCTURES OF SINGLE WALLED AND MULTI WALLED CARBON NANOTUBES 审中-公开
标题翻译：单壁多壁碳纳米管的混合结构
公开(公告)号：WO2008051239A2
公开(公告)日：2008-05-02
申请号：PCT/US2006/044846
申请日：2006-11-16
申请人： HYPERION CATALYSIS INTERNATIONAL, INC. , MA, Jun , FISHER, Alan , HOCH, Robert
发明人： MA, Jun , FISHER, Alan , HOCH, Robert
IPC分类号： C01B31/02
CPC分类号： B82B1/00 , B82Y30/00 , B82Y40/00 , C01B32/16 , C01B32/174
摘要： The invention relates to carbon nanotube structures containing both single walled and multi walled carbon nanotubes, and methods for preparing same. These carbon nanotube structures include but are not limited to macroscopic two and three dimensional structures of carbon nanotubes such as assemblages, mats, plugs, networks, rigid porous structures, extrudates, etc. The carbon nanotube structures of the present invention have a variety of uses, including but not limited to, porous media for filtration, adsorption, chromatography; electrodes and current collectors for supercapacitors, batteries and fuel cells; catalyst supports, (including electrocatalysis), etc.
摘要翻译：本发明涉及含有单壁和多壁碳纳米管的碳纳米管结构体及其制备方法。这些碳纳米管结构包括但不限于碳纳米管的宏观二维和三维结构，例如组合体，垫，塞，网络，刚性多孔结构，挤出物等。本发明的碳纳米管结构具有多种用途包括但不限于用于过滤，吸附，层析的多孔介质; 用于超级电容器，电池和燃料电池的电极和集电器; 催化剂载体，（包括电催化）等。

10. 发明申请

WO2006055670A3 METHODS FOR PREPARING CATALYSTS SUPPORTED ON CARBON NANOTUBE NETWORKS 审中-公开
公开(公告)号：WO2006055670A3
公开(公告)日：2006-05-26
申请号：PCT/US2005/041605
申请日：2005-11-16
申请人： HYPERION CATALYSIS INTERNATIONAL, INC. , MA, Jun , MOY, David , FISCHER, Alan , HOCH, Robert
发明人： MA, Jun , MOY, David , FISCHER, Alan , HOCH, Robert
IPC分类号： D01C5/00 , D01F9/12
摘要： A new method for preparing a supported catalyst is herein provided. The supported catalyst comprises a carbon nanotube network structure containing metal catalysts. The metal catalyst may be loaded onto functionalized carbon nanotubes before forming the carbon nanotube network structure. Alternatively, the metal catalyst may be loaded onto the carbon nanotube network structures themselves.

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