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    • 10. 发明申请
    • METHODS AND APPARATUSES FOR DEOXYGENATING PYROLYSIS OIL
    • 脱氧油的方法和装置
    • WO2016085562A2
    • 2016-06-02
    • PCT/US2015/051305
    • 2015-09-22
    • UOP LLC
    • BAIRD, Lance AwenderBRANDVOLD, Timothy A.FREY, Stanley Joseph
    • C07C1/22C07C5/367C07C2521/04C07C2521/06C07C2523/42C07C2523/44C10G3/42C10G3/47Y02P30/20
    • Methods and apparatuses are provided for deoxygenating pyrolysis oil. A method includes contacting a pyrolysis oil with a deoxygenation catalyst in a first reactor at deoxygenation conditions to produce a first reactor effluent. The first reactor effluent has a first oxygen concentration and a first hydrogen concentration, based on hydrocarbons in the first reactor effluent, and the first reactor effluent includes an aromatic compound. The first reactor effluent is contacted with a dehydrogenation catalyst in a second reactor at conditions that deoxygenate the first reactor effluent while preserving the aromatic compound to produce a second reactor effluent. The second reactor effluent has a second oxygen concentration lower than the first oxygen concentration and a second hydrogen concentration that is equal to or lower than the first hydrogen concentration, where the second oxygen concentration and the second hydrogen concentration are based on the hydrocarbons in the second reactor effluent.
    • 提供了用于脱氧裂解油的方法和装置。 一种方法包括在脱氧条件下在第一反应器中使热解油与脱氧催化剂接触以产生第一反应器流出物。 基于第一反应器流出物中的烃,第一反应器流出物具有第一氧浓度和第一氢气浓度,并且第一反应器流出物包括芳族化合物。 将第一反应器流出物与第二反应器中的脱氢催化剂接触,在脱氧第一反应器流出物的同时保留芳族化合物以产生第二反应器流出物。 第二反应器流出物具有低于第一氧浓度的第二氧浓度和等于或低于第一氢浓度的第二氢浓度,其中第二氧浓度和第二氢浓度基于第二氧浓度 反应器流出物。