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1. 发明申请

WO2010126767A2 SINGLE WALL CARBON NANOTUBE BASED AIR CATHODES 审中-公开
标题翻译：单壁碳纳米管空气阴极
公开(公告)号：WO2010126767A2
公开(公告)日：2010-11-04
申请号：PCT/US2010031995
申请日：2010-04-22
申请人： UNIV FLORIDA RES FOND INC , RINZLER ANDREW GABRIEL , DAS RAJIB KUMAR , REYNOLDS JOHN R , WALCZAK RYAN M
发明人： RINZLER ANDREW GABRIEL , DAS RAJIB KUMAR , REYNOLDS JOHN R , WALCZAK RYAN M
IPC分类号： H01M12/06 , B82B3/00 , H01M8/02
CPC分类号： H01M4/8673 , H01M4/8605 , H01M4/8657 , H01M4/8668 , H01M8/1007 , H01M8/1011 , H01M12/06 , H01M2008/1095 , Y02E60/523 , Y10T29/49124
摘要： An embodiment of the invention is an air cathode having a porous membrane with at least one hydrophobic surface that contacts a conductive catalytic film that comprises single walled carbon nanotubes (SWNTs) where the nanotubes are in intimate electrical contact. The conductive film can include fullerenes, metals, metal alloys, metal oxides, or electroactive polymers in addition to the SWNTs. In other embodiments of the invention the air cathode is a component of a metal-air battery or a fuel cell.
摘要翻译：本发明的一个实施方案是具有多孔膜的空气阴极，该多孔膜具有至少一个疏水表面，该疏水性表面与包含纳米管紧密电接触的单壁碳纳米管（SWNT）的导电催化膜相接触。除了SWNT之外，导电膜可以包括富勒烯，金属，金属合金，金属氧化物或电活性聚合物。在本发明的其它实施例中，空气阴极是金属 - 空气电池或燃料电池的组件。

2. 发明申请

WO2010126767A8 SINGLE WALL CARBON NANOTUBE BASED AIR CATHODES 审中-公开
标题翻译：单壁碳纳米管空气阴极
公开(公告)号：WO2010126767A8
公开(公告)日：2011-01-06
申请号：PCT/US2010031995
申请日：2010-04-22
申请人： UNIV FLORIDA , RINZLER ANDREW GABRIEL , DAS RAJIB KUMAR , REYNOLDS JOHN R , WALCZAK RYAN M
发明人： RINZLER ANDREW GABRIEL , DAS RAJIB KUMAR , REYNOLDS JOHN R , WALCZAK RYAN M
IPC分类号： H01M12/06 , B82B3/00 , H01M8/02
CPC分类号： H01M4/8673 , H01M4/8605 , H01M4/8657 , H01M4/8668 , H01M8/1007 , H01M8/1011 , H01M12/06 , H01M2008/1095 , Y02E60/523 , Y10T29/49124
摘要： An embodiment of the invention is an air cathode having a porous membrane with at least one hydrophobic surface that contacts a conductive catalytic film that comprises single walled carbon nanotubes (SWNTs) where the nanotubes are in intimate electrical contact. The conductive film can include fullerenes, metals, metal alloys, metal oxides, or electroactive polymers in addition to the SWNTs. In other embodiments of the invention the air cathode is a component of a metal-air battery or a fuel cell.
摘要翻译：本发明的一个实施方案是具有多孔膜的空气阴极，该多孔膜具有至少一个疏水表面，该疏水性表面与包含纳米管紧密电接触的单壁碳纳米管（SWNT）的导电催化膜相接触。除了SWNT之外，导电膜可以包括富勒烯，金属，金属合金，金属氧化物或电活性聚合物。在本发明的其它实施例中，空气阴极是金属 - 空气电池或燃料电池的组件。

3. 发明申请

WO2009023337A2 SUPRAMOLECULAR POLYMERS ASSOCIATIVE TO CARBON NANOTUBES 审中-公开
标题翻译：与碳纳米管相关的分子聚合物
公开(公告)号：WO2009023337A2
公开(公告)日：2009-02-19
申请号：PCT/US2008064146
申请日：2008-05-19
申请人： UNIV FLORIDA , REYNOLDS JOHN R , WALCZAK RYAN M , VAN DER AA EVELINE MARIA , RINZLER ANDREW GABRIEL
发明人： REYNOLDS JOHN R , WALCZAK RYAN M , VAN DER AA EVELINE MARIA , RINZLER ANDREW GABRIEL
CPC分类号： C08G18/73 , B29C73/163 , B29C73/22 , B82Y30/00 , C08G18/2865 , C08J5/005
摘要： A supramolecular polymer and its composite with carbon nanotubes, CNTs, are described. The supramolecular polymer is an ensemble of precursors that independently contain "sticky feet" for non-covalent binding to carbon nanotube surfaces and associative groups. There is at least one of the associative groups covalently bound to each of the precursor and there is at least one covalently connecting moiety connecting associative groups within a precursor or connecting an associative group to a linker to a "sticky foot" in a precursor. When the associative groups are in a dissociative state, the supramolecular polymer precursors and CNTs can be combined to form a dispersion. Upon promotion, the dissociated associative groups in the dispersion can associate to yield a CNT/supramolecular polymer composite.
摘要翻译：描述了超分子聚合物及其与碳纳米管，CNT的复合物。超分子聚合物是独立包含用于非共价结合碳纳米管表面和缔合基团的“粘性脚”的前体的组合。至少有一个共价基团与每个前体共价结合，并且存在至少一个共价连接部分，其连接前体内的缔合基团或将缔合基团连接到前体中的“粘性脚”。当缔合基团处于解离状态时，可以将超分子聚合物前体和CNT组合形成分散体。促进时，分散体中的离解的缔合基团可以缔合以产生CNT /超分子聚合物复合物。

4. 发明申请

WO2008118704A3 VARIABLE COLOR DIOXYHETEROCYCLE COPOLYMERS 审中-公开
标题翻译：可变颜料二氧化硅共聚物
公开(公告)号：WO2008118704A3
公开(公告)日：2008-12-11
申请号：PCT/US2008057420
申请日：2008-03-19
申请人： UNIV FLORIDA , REYNOLDS JOHN R , JUNG JUNE-HO , WALCZAK RYAN M
发明人： REYNOLDS JOHN R , JUNG JUNE-HO , WALCZAK RYAN M
IPC分类号： C08G61/12 , H01L51/00
CPC分类号： C08G61/124 , C08G61/125 , C08G61/126 , H01L51/0037 , H01L51/0043
摘要： Soluble copolymers of heterocyclic monomers that have electrochromic properties are prepared chemically, where the properties are dependent on the proportions and block sizes of the monomer sequences in the copolymer. By the judicious choice of the comonomers and their proportions, the color and/or band gap of the resulting copolymer can be predetermined and achieved, with little, if any, change in a polymerization process other than the monomer feed ratio. Additional control can be achieved of the block size distribution and resulting copolymer properties by the copolymerization of an oligomer, with a core of one monomer and termini of another, with a monomer of the same or similar heterocyclic structure as the termini of the oligomer. In another embodiment an asymmetric dimer of two heterocyclic monomers can be copolymerized with the same or similar heterocyclic structure as either or both heterocyclic monomers of the dimer to achieve electrochromic copolymers of a predetermined band gap and/or color.
摘要翻译：具有电致变色性质的杂环单体的可溶性共聚物是化学制备的，其中性质取决于共聚物中单体序列的比例和嵌段大小。通过明智地选择共聚单体和它们的比例，所得共聚物的颜色和/或带隙可以预先确定，并且除了单体进料比之外，聚合过程中几乎没有任何变化。可以通过低聚物与一个单体的核心和另一个单体的末端与与低聚物的末端具有相同或相似的杂环结构的单体共聚来实现块尺寸分布和所得的共聚物性质的附加控制。在另一个实施方案中，两种杂环单体的不对称二聚体可以与二聚体的任一种或两种杂环单体相同或相似的杂环结构共聚，以实现预定带隙和/或颜色的电致变色共聚物。

5. 发明申请

WO2012138632A3 NANOTUBE DISPERSANTS AND DISPERSANT FREE NANOTUBE FILMS THEREFROM 审中-公开
标题翻译：纳米管分散剂和无分散纳米管膜
公开(公告)号：WO2012138632A3
公开(公告)日：2012-12-20
申请号：PCT/US2012031950
申请日：2012-04-03
申请人： UNIV FLORIDA , WALCZAK RYAN M , REYNOLDS JOHN R , RINZLER ANDREW G , SPRING ANDREW M , VASILYEVA SVETLANA V , WADHWA POOJA
发明人： WALCZAK RYAN M , REYNOLDS JOHN R , RINZLER ANDREW G , SPRING ANDREW M , VASILYEVA SVETLANA V , WADHWA POOJA
IPC分类号： C08L1/02 , C08J5/18 , C08K3/04 , C08K7/24 , C08L101/16
CPC分类号： H05K1/092 , B05D1/04 , B05D1/18 , B05D1/28 , B05D3/007 , B82Y30/00 , B82Y40/00 , C01B32/168 , C01B32/174 , C01B32/194 , C08J3/02 , C08J2300/10 , C08K3/041 , C08K7/24 , C09D5/027 , C09D7/1291 , C09D7/70 , C09D11/30 , C09D11/52 , C09D101/02 , C09D147/00 , H05K2201/0323 , C08L1/284 , C08L101/02
摘要： A degradable polymeric nanotube (NT) dispersant comprises a multiplicity of NT associative groups that are connected to a polymer backbone by a linking group where there are cleavable groups within the polymer backbone and/or the linking groups such that on a directed change of conditions, bond breaking of the cleavable groups results in residues from the degradable polymeric NT dispersant in a manner where the associative groups are uncoupled from other associative groups, rendering the associative groups monomelic in nature. The degradable polymeric nanotube (NT) dispersant can be combined with carbon NTs to form a NT dispersion that can be deposited to form a NT film, or other structure, by air brushing, electrostatic spraying, ultrasonic spraying, ink-jet printing, roll-to-roll coating, or dip coating. The deposition can render a NT film that is of a uniform thickness or is patterned with various thicknesses. Upon deposition of the film, the degradable polymeric nanotube (NT) dispersant can be cleaved and the cleavage residues removed from the film to yield a film where contact between NTs is unencumbered by dispersants, resulting in highly conductive NT films.
摘要翻译：可降解的聚合物纳米管（NT）分散剂包含多个NT缔合基团，所述NT缔合基团通过其中在聚合物主链和/或连接基团中存在可裂解基团的连接基团连接至聚合物主链，使得在条件的定向改变时，可裂解基团的键断裂导致来自可降解聚合物NT分散剂的残基，其中缔合基团与其他缔合基团解偶联，使缔合基团在本质上是单体性的。可降解的聚合物纳米管（NT）分散剂可以与碳NTs组合以形成NT分散体，其可以通过空气刷涂，静电喷涂，超声喷涂，喷墨印刷，辊涂等方法沉积以形成NT膜或其它结构。辊对涂布或浸涂。沉积可以使NT膜具有均匀的厚度或者以各种厚度图案化。在膜沉积之后，可降解的聚合物纳米管（NT）分散剂可被切割并且从膜上去除切割残余物以产生膜，其中NT之间的接触不受分散剂阻碍，导致高导电性NT膜。

6. 发明申请

WO2008046010A3 ELECTROACTIVE POLYMERS CONTAINING PENDANT PI-INTERACTING/BINDING SUBSTITUENTS, THEIR CARBON NANOTUBE COMPOSITES, AND PROCESSES TO FORM THE SAME 审中-公开
标题翻译：含有PI相互作用/结合取代基的电动聚合物，其碳纳米管复合材料及其形成方法
公开(公告)号：WO2008046010A3
公开(公告)日：2008-06-26
申请号：PCT/US2007081121
申请日：2007-10-11
申请人： UNIV FLORIDA , REYNOLDS JOHN R , WALCZAK RYAN M , RINZLER ANDREW G
发明人： REYNOLDS JOHN R , WALCZAK RYAN M , RINZLER ANDREW G
IPC分类号： C08K7/06 , C08K7/24 , C09D5/24 , H01B1/12 , H01B1/24 , H01L51/00
CPC分类号： C09D5/24 , G02F2001/1515 , H01B1/24 , H01L51/0039 , H01L51/0043 , H01L51/0054
摘要： A composition of matter comprises a polymer with a fully conjugated backbone or a conjugated block with a plurality of binding groups connected to the backbone by a linking moiety. The binding groups permit a non-covalent binding to a graphitic surface such as a carbon nanotube. A composition of matter where an electroactive polymer with binding groups connected to a conjugated backbone through a linking moiety is bound to carbon nanotubes. Such compositions can be used for a variety of applications using electroactive materials.
摘要翻译：物质组合物包含具有完全共轭骨架的聚合物或具有多个通过连接部分连接至主链的结合基团的共轭嵌段。结合基团允许与石墨表面（例如碳纳米管）非共价结合。其中具有通过连接部分与共轭骨架连接的结合基团的电活性聚合物与碳纳米管结合的物质组合物。这种组合物可用于使用电活性材料的各种应用。

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