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1. 发明申请

WO2011120968A3 GAZOLINE UPGRADING PROCESS. 审中-公开
标题翻译： GAZOLINE升级过程
公开(公告)号：WO2011120968A3
公开(公告)日：2012-06-07
申请号：PCT/EP2011054824
申请日：2011-03-29
申请人： TOTAL RAFFINAGE MARKETING , MINOUX DELPHINE , VAN DONK SANDER , NESTERENKO NIKOLAI , BULUT METIN
发明人： MINOUX DELPHINE , VAN DONK SANDER , NESTERENKO NIKOLAI , BULUT METIN
IPC分类号： C10G50/00 , B01J29/04 , B01J29/06 , B01J29/40 , B01J29/83 , B01J29/85 , B01J35/10 , C07C7/08 , C07C7/12
CPC分类号： C10G50/00 , B01J29/06 , B01J29/40 , B01J29/83 , B01J35/1061 , B01J2229/16 , B01J2229/22 , B01J2229/38 , B01J2229/40 , C10G2300/104 , C10G2300/1088 , C10G2300/1096 , C10G2300/301 , C10G2300/4018 , C10G2400/04 , C10G2400/30
摘要： The present invention relates to a process allowing the tuning of the gasoline/diesel balance by converting an initial feedstock containing olefins from 4 to 20 carbon atoms using a crystalline catalyst with reduced diffusional limitations. The process comprises: -processing a feedstock stream containing olefins from 4 to 20 carbon atoms with or without the presence of an aromatic containing stream, -contacting said stream(s) with a catalyst at conditions effective to oligomerize a least a portion of the olefins and eventually alkylate at least a portion of the aromatics, wherein the catalyst is a crystalline compound with micro/mesoporous structure chosen among crystalline aluminosilicates, crystalline aluminophosphates, crystalline silico-aluminophosphates, crystalline zeolites, or the catalyst is a composite material comprising at least 20%wt of at least one of the above mentioned crystalline compounds, and wherein the mesoporous volume of the crystalline compound is at least 0.22ml/g.
摘要翻译：本发明涉及通过使用具有降低的扩散限制的结晶催化剂转化含有4至20个碳原子的烯烃的初始原料来调节汽油/柴油平衡的方法。该方法包括：在有或没有含芳族化合物流的情况下处理含有4-20个碳原子的烯烃的原料物流， - 在有效使低至少一部分烯烃的条件下将催化剂与催化剂接触并最终将至少一部分芳族化合物烷基化，其中催化剂是具有选自结晶铝硅酸盐，结晶铝磷酸盐，结晶硅铝磷酸盐，结晶沸石的微/介孔结构的结晶化合物，或者该催化剂是包含至少20 至少一种上述结晶化合物的wt％，并且其中结晶化合物的介孔体积为至少0.22ml / g。

2. 发明申请

WO2012084276A3 PROCESS FOR PREPARING AN INDUSTRIAL HYDROCONVERSION CATALYST, CATALYST THUS OBTAINED AND USE THEREOF IN A HYDROCONVERSION PROCESS 审中-公开
标题翻译：制备工业级氢化催化剂的方法，其获得的催化剂及其在氢转化方法中的应用
公开(公告)号：WO2012084276A3
公开(公告)日：2012-10-04
申请号：PCT/EP2011059659
申请日：2011-06-10
申请人： TOTAL RAFFINAGE MARKETING , VAN DONK SANDER , DANILINA NADIYA , MINOUX DELPHINE , BULUT METIN
发明人： VAN DONK SANDER , DANILINA NADIYA , MINOUX DELPHINE , BULUT METIN
IPC分类号： C10G45/04 , B01J29/08 , B01J29/12 , B01J29/14 , B01J29/16 , C01B39/02 , C10G47/16
CPC分类号： B01J29/166 , B01J29/146 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/109 , B01J37/0009 , B01J37/0201 , B01J37/0203 , B01J2229/16 , B01J2229/42 , C01B39/026 , C01B39/20 , C01B39/24 , C10G45/04 , C10G47/16 , C10G49/08
摘要： The invention relates to a process for preparing a hydreconversion catalyst based on modified zeolite Y, comprising the steps of: A- preparation of a modified zeolite Y, whose intracrystalline structure presents at least one network of micropores, at least one network of small mesopores with a mean diameter of 2 to 5 nm and at least one network of large mesopores with a mean diameter of 10 to 50 nm, these various networks being interconnected; B- mixing the zeolite with a binder, shaping the mixture and then calcining; C- introducing at least one catalytic metal chosen from metals of group VIII and/or of group VIB, followed by calcination. The invention also relates to a catalyst obtained via this process and also to the use thereof.
摘要翻译：本发明涉及一种制备基于改性沸石Y的水解转化催化剂的方法，包括以下步骤：A-制备改性沸石Y，其结晶结构呈现至少一个微孔网络，至少一个小介孔网络与平均直径为2至5nm的平均直径为10至50nm的至少一个大的介孔网络，这些各种网络互连; B-将沸石与粘合剂混合，将混合物成形，然后煅烧; C-引入至少一种选自VIII族和/或VIB族金属的催化剂金属，然后煅烧。本发明还涉及通过该方法获得的催化剂以及其用途。

3. 发明申请

WO2009016155A3 USE OF PHOSPHORUS MODIFIED MOLECULAR SIEVES IN CONVERSION OF ORGANICS TO OLEFINS 审中-公开
标题翻译：磷酸改性分子筛在有机物转化成烯烃中的应用
公开(公告)号：WO2009016155A3
公开(公告)日：2010-09-16
申请号：PCT/EP2008059885
申请日：2008-07-28
申请人： TOTAL PETROCHEMICALS RES FELUY , NESTERENKO NIKOLAI , VERMEIREN WALTER , MINOUX DELPHINE , VAN DONK SANDER
发明人： NESTERENKO NIKOLAI , VERMEIREN WALTER , MINOUX DELPHINE , VAN DONK SANDER
IPC分类号： C07C1/20 , C01B39/02 , C07C1/32 , C07C4/06 , C10G11/16
CPC分类号： C07C1/20 , B01J29/40 , B01J37/28 , B01J2229/18 , B01J2229/37 , C07C1/322 , C07C4/06 , C07C2529/85 , C10G2400/20 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a process to make light olefins, in a combined XTO-OCP process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with a catalyst made of a P-modified zeolite (A) at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; separating said light olefins from said heavy hydrocarbon fraction; contacting said heavy hydrocarbon fraction in the OCP reactor with a catalyst made of a P-modified zeolite (A) at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins; wherein said P-modified zeolite (A) is made by a process comprising in that order: selecting a zeolite (advantageously with Si/AI ratio between 4 and 500) among H+ or NH4 +-form of MFI, MEL, FER, MOR, clinoptilolite; introducing P at conditions effective to introduce advantageously at least 0.05 wt% of P; separation of the solid from the liquid if any; an optional washing step or an optional drying step or an optional drying step followed by a washing step; a calcination step.
摘要翻译：本发明涉及一种在组合的XTO-OCP方法中由含氧，含卤素或含硫有机原料制备轻质烯烃的方法，包括：将含氧的含卤素或含硫的在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃馏分的XTO反应器流出物的条件下，在XTO反应器中的有机原料具有由P改性沸石（A）制成的催化剂; 将所述轻质烯烃与所述重质烃馏分分离; 在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下，使所述OCP反应器中的所述重质烃馏分与由P-改性沸石（A）制成的催化剂接触; 其中所述P型改性沸石（A）通过以下方法制备：在MFI，MEL，FER，MOR，HNO 3的H +或NH 4 +形式中选择沸石（有利地具有4至500的Si / Al比）斜发沸石; 在有效引入至少0.05重量％的P的条件下引入P; 从液体中分离出固体物质; 任选的洗涤步骤或任选的干燥步骤或任选的干燥步骤，随后进行洗涤步骤; 煅烧步骤。

4. 发明申请

WO2009016153A3 PHOSPHORUS MODIFIED MOLECULAR SIEVES, THEIR USE IN CONVERSION OF ORGANICS TO OLEFINS 审中-公开
标题翻译：磷酸改性分子筛，它们在有机物转化成烯烃中的用途
公开(公告)号：WO2009016153A3
公开(公告)日：2010-04-29
申请号：PCT/EP2008059883
申请日：2008-07-28
申请人： TOTAL PETROCHEMICALS RES FELUY , NESTERENKO NIKOLAI , VERMEIREN WALTER , MINOUX DELPHINE , VAN DONK SANDER
发明人： NESTERENKO NIKOLAI , VERMEIREN WALTER , MINOUX DELPHINE , VAN DONK SANDER
IPC分类号： B01J29/85 , C01B39/02 , C07C1/20 , C07C2/08 , C07C11/02
CPC分类号： C07C1/322 , B01J29/40 , B01J29/85 , B01J2229/36 , B01J2229/37 , C01B39/026 , C07C1/20 , C07C1/22 , C07C1/26 , C07C2/06 , C07C4/06 , C07C7/04 , C07C2529/85 , C10G3/00 , C10G2300/202 , C10G2300/4081 , C10G2400/20 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/02 , C07C11/06
摘要： The present invention is a phosphorous modified zeolite (A) made by a process comprising in that order: selecting a zeolite with low Si/AI ratio (advantageously lower than 30) among H+ or NH4 +-form of MFI, MEL, FER, MOR, clinoptilolite, said zeolite having been made preferably without direct addition of organic template; steaming at a temperature ranging from 400 to 870°C for 0.01-200h; leaching with an aqueous acid solution containing the source of P at conditions effective to remove a substantial part of Al from the zeolite and to introduce at least 0.3 wt% of P; separation of the solid from the liquid; an optional washing step or an optional drying step or an optional drying step followed by a washing step; a calcination step. The present invention also relates to a process (hereunder referred as 'XTO process') for making an olefin product from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock wherein said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock is contacted with the above catalyst (in the XTO reactor) under conditions effective to convert at least a portion of the oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to olefin products (the XTO reactor effluent). The present invention also relates to a process (hereunder referred as 'combined XTO and OCP process') to make light olefins from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the above catalyst at conditions effective to convert at least a portion of the feedstock to form an XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; separating said light olefins from said heavy hydrocarbon fraction; contacting said heavy hydrocarbon fraction in the OCP reactor at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins.
摘要翻译：本发明是通过以下方法制备的磷改性沸石（A）：在MFI，MEL，FER，MOR的H +或NH4 +形式中选择具有低Si / Al比（有利地低于30）的沸石，斜发沸石，所述沸石优选不直接添加有机模板; 在400〜870℃的温度范围内蒸煮0.01〜200h; 在有效从沸石中除去大部分Al并引入至少0.3wt％P的条件下，用含有P源的酸性水溶液浸出; 从液体中分离固体; 任选的洗涤步骤或任选的干燥步骤或任选的干燥步骤，随后进行洗涤步骤; 煅烧步骤。本发明还涉及从含氧，含卤素或含硫有机原料制备烯烃产物的方法（以下称为“XTO法”），其中所述含氧卤化物或含硫的在有效将至少一部分含氧，含卤素或含硫有机原料转化为烯烃产物（XTO反应器流出物）的条件下，有机原料与上述催化剂（在XTO反应器中）接触。本发明还涉及从含氧的含卤化物或含硫有机原料制备轻质烯烃的方法（以下称为“组合的XTO和OCP方法”），包括：使含有氧的含卤素的或含硫有机原料在具有上述催化剂的XTO反应器中，在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃馏分的XTO反应器流出物的条件下; 将所述轻质烯烃与所述重质烃馏分分离; 在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下使OCP反应器中的所述重质烃馏分接触。

5. 发明申请

WO2009092781A2 PROCESS FOR OBTAINING MODIFIED MOLECULAR SIEVES 审中-公开
标题翻译：获得修饰分子筛的方法
公开(公告)号：WO2009092781A2
公开(公告)日：2009-07-30
申请号：PCT/EP2009050758
申请日：2009-01-23
申请人： TOTAL PETROCHEMICALS RES FELUY , NESTERENKO NIKOLAI , VERMEIREN WALTER , VAN DONK SANDER , MINOUX DELPHINE
发明人： NESTERENKO NIKOLAI , VERMEIREN WALTER , VAN DONK SANDER , MINOUX DELPHINE
IPC分类号： B01J27/16 , B01J29/06 , B01J29/40 , C07C1/20 , C07C4/06
CPC分类号： C07C1/20 , B01J27/16 , B01J29/06 , B01J29/061 , B01J29/40 , B01J29/405 , B01J37/0201 , B01J37/0207 , B01J37/024 , B01J37/28 , B01J2229/16 , B01J2229/186 , B01J2229/36 , B01J2229/37 , C07C4/06 , C07C2523/02 , C07C2527/14 , C07C2529/06 , C07C2529/40 , C07C2529/82 , C07C2529/85 , C08F110/02 , C10G2400/20 , Y02P30/42 , C07C11/02
摘要： The invention covers a process for obtaining an alkaline earth or rare earth metal-P-modified molecular sieve (M-P-modified molecular sieve) comprising the following steps: a), selecting at least one molecular sieve selected from one of: - a P-modified molecular sieve which contains at least 0.3 wt% of P obtained by dealuminating a molecular sieve in a steaming step, followed by a leaching step using an acid solution containing a source of P - a molecular sieve which is modified with P during step b) by dealuminating the molecular sieve in a steaming step, followed by a leaching step using an acid solution containing a source of P thereby introducing at least 0.3 wt % of P b). contacting said molecular sieve with an alkaline earth or rare earth metal-containing compound (M-containing compound) to introduce at least 0.05 wt% of the alkaline earth or rare earth metal to the molecular sieve. The invention also covers a catalyst composite comprising: a), at least 10 wt % of a M-P-modified molecular sieve comprising at least 0.05 % by weight of an alkaline earth or rare earth metal (M) and at least 0.3 wt% of P, b). optionally metal phosphate, c). optionally matrix material, and d). optionally binder. The catalyst of the invention can also be used in a process for making an olefin product from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock wherein said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock is contacted in the XTO reactor with the catalyst composite according to the invention under conditions effective to convert the oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to olefin products (the XTO reactor effluent). The catalyst composite of the invention can also be used in addition or alternatively in an OCP process.
摘要翻译：本发明包括获得碱土或稀土金属-P-改性分子筛（MP-改性分子筛）的方法，其包括以下步骤：a）选择至少一种选自以下物质之一的分子筛：-P- 其包含至少0.3重量％的通过在汽蒸步骤中将分子筛脱铝而获得的P，然后使用含有P的分子筛的酸溶液进行浸提步骤，所述分子筛在步骤b）期间用P改性，通过在汽蒸步骤中使分子筛脱铝，接着使用含有P源的酸溶液进行浸出步骤，由此引入至少0.3重量％的P b）。使所述分子筛与含碱土金属或稀土金属的化合物（含M化合物）接触以将至少0.05重量％的碱土金属或稀土金属引入分子筛中。本发明还包括催化剂复合物，其包含：a）至少10wt％的包含至少0.05重量％的碱土金属或稀土金属（M）和至少0.3重量％的P ，b）。任选地金属磷酸盐，c）。任选的基质材料，和d）。可选的粘合剂本发明的催化剂也可用于由含氧，含卤化物或含硫有机原料制备烯烃产物的方法，其中所述含氧，含卤化物或含硫有机原料与具有根据本发明的催化剂复合物的XTO反应器在有效将含氧，含卤化物或含硫有机原料转化成烯烃产物（XTO反应器流出物）的条件下进行。本发明的催化剂复合材料还可以另外或可选地用于OCP工艺中。

6. 发明申请

WO2010079044A2 PROCESS FOR AROMATIC HYDROGENATION AND CETANE VALUE INCREASE OF MIDDLE-DISTILLATE FEEDSTOCKS 审中-公开
标题翻译：芳烃加氢方法和中等离子交换剂的增值价格
公开(公告)号：WO2010079044A2
公开(公告)日：2010-07-15
申请号：PCT/EP2009067003
申请日：2009-12-11
申请人： TOTAL RAFFINAGE MARKETING , ALBEMARLE EUROPE SPRL , DATH JEAN-PIERRE , VAN DONK SANDER , GRASSO GIACOMO , LODEWIJK PLANTENGA FRANS , NIEMAN JAN
发明人： DATH JEAN-PIERRE , VAN DONK SANDER , GRASSO GIACOMO , LODEWIJK PLANTENGA FRANS , NIEMAN JAN
IPC分类号： C10G45/52 , B01J21/12 , B01J37/04 , C10G45/04 , C10G45/08 , C10G65/08
CPC分类号： C10G45/52 , B01J23/44 , B01J23/63 , B01J23/652 , B01J23/89 , B01J35/0066 , B01J35/1019 , B01J35/1042 , C10G45/04 , C10G45/08 , C10G65/08
摘要： The instant invention pertains to a process for treating a feed, for example a Light Cycle Oil (LCO), having a high content of S and/ or N impurities and/ or a high content of aromatics, comprising the following steps, in particular in such an order a step of desulphurisation (HD S) and denitrification (HDN) of a feed, in particular LCO, is passed in presence of hydrogen over a catalyst, containing metals of the group VI B and VIII, leading to an effluent, optionally a step of stripping of the effluent, at least a subsequent step for dearomatization (HDA) in which at least a portion of the effluent, optionally stripped, is passed in presence of hydrogen over a catalyst comprising a combination of platinum and palladium supported on a carrier comprising silica-alumina dispersed in an alumina binder wherein the amount of alumina binder is 5-50 wt. % based on the total weight of the silica-alumina and alumina binder present in the carrier and wherein the silica-alumina comprises 5-50 wt. % of alumina based on the weight of the silica-alumina, and recovering the final load obtained, the use of a specific catalyst and a process for preparing diesel comprising the step of mixing the final effluent obtained by a process of the invention.
摘要翻译：本发明涉及用于处理具有高含量S和/或N杂质和/或高含量芳族化合物的进料例如轻循环油（LCO）的方法，其包括以下步骤，特别是在进料，特别是LCO的脱硫（HDS）和脱氮（HDN）的步骤在氢存在下通过含有VIB和VIII族的金属的催化剂通过，导致流出物，任选地至少后续的脱芳环化步骤（HDA），其中将至少一部分流出物任选地汽提，在氢存在下通过催化剂，所述催化剂包含铂和钯的组合，所述催化剂负载在载体，其包含分散在氧化铝粘合剂中的二氧化硅 - 氧化铝，其中氧化铝粘合剂的量为5-50wt。基于存在于载体中的二氧化硅 - 氧化铝和氧化铝粘合剂的总重量，其中二氧化硅 - 氧化铝包含5-50wt。基于二氧化硅 - 氧化铝的重量的氧化铝的百分比，并且回收所获得的最终载荷，使用特定催化剂和制备柴油的方法，包括混合通过本发明的方法获得的最终流出物的步骤。

7. 发明申请

WO2009156436A3 PROCESS TO MAKE OLEFINS FROM ORGANICS 审中-公开
标题翻译：从有机物制备烯烃的方法
公开(公告)号：WO2009156436A3
公开(公告)日：2010-02-18
申请号：PCT/EP2009057890
申请日：2009-06-24
申请人： TOTAL PETROCHEMICALS RES FELUY , NESTERENKO NIKOLAI , VERMEIREN WALTER , GRASSO GIACOMO , VAN DONK SANDER , GARCIA WOLFGANG
发明人： NESTERENKO NIKOLAI , VERMEIREN WALTER , GRASSO GIACOMO , VAN DONK SANDER , GARCIA WOLFGANG
IPC分类号： C07C1/20 , B01J27/16 , B01J29/40 , B01J37/28 , C10G11/05
CPC分类号： C07C1/20 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J38/12 , B01J2229/16 , B01J2229/18 , B01J2229/36 , B01J2229/37 , C07C1/26 , C07C1/322 , C07C4/06 , C07C2529/40 , Y02P20/584 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, optionally at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide- containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction and the second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction and oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to light olefins.
摘要翻译：本发明涉及一种在组合的XTO-OC方法中由含氧，含卤素或含硫有机原料制备轻质烯烃的方法，包括：a）提供所述氧气的第一部分和第二部分 a）提供包含在其微孔结构中含有至少10元环孔或更大孔沸石分子筛的催化剂，b）提供XTO反应区，OC反应区和催化剂再生区，所述催化剂在三个区域中循环，使得至少一部分再生催化剂通入OC反应区，任选地将OC反应区中的至少一部分催化剂通入XTO反应区域，并且XTO反应区中的至少一部分催化剂被传送到再生区; c）在有效地转化至少一部分原料以形成包含轻质烯烃的XTO反应器流出物的条件下，将XTO反应器中的含氧卤化物或含硫有机原料的第一部分与催化剂接触，重质烃馏分; d）从所述重质烃馏分中分离出所述轻质烯烃; e）在OC反应器中将所述重质烃部分和第二部分所述含氧卤化物或含硫有机原料与所述催化剂接触，所述条件有效地将至少一部分所述重质烃部分和氧 - 含卤素或含硫有机原料转化成轻质烯烃。

8. 发明申请

WO2009092780A3 PROCESS FOR OBTAINING CATALYST COMPOSITES COMPRISING MEAPO AND THEIR USE IN CONVERSION OF ORGANICS TO OLEFINS 审中-公开
标题翻译：获得含有MEAPO的催化剂组合物及其在有机物转化成烯烃中的用途的方法
公开(公告)号：WO2009092780A3
公开(公告)日：2009-09-17
申请号：PCT/EP2009050756
申请日：2009-01-23
申请人： TOTAL PETROCHEMICALS RES FELUY , NESTERENKO NIKOLAI , VERMEIREN WALTER , VAN DONK SANDER
发明人： NESTERENKO NIKOLAI , VERMEIREN WALTER , VAN DONK SANDER
IPC分类号： B01J29/06 , B01J29/85 , C07C1/20
CPC分类号： C07C1/32 , B01J29/005 , B01J29/40 , B01J29/85 , B01J2229/186 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C1/26 , Y02P30/42 , C07C11/02
摘要： The present invention is a catalyst composite comprising: - at least 0.5% by- weight of at least one metal salt, which is stable under XTO conditions and - at least 10% by weight of molecular sieves which comprise - 70% to 100% by weight of said molecular sieves of at least one small pore aluminosilicate or metalloaluminophosphate (MeAPO) molecular sieve and 0 to 30% by weight of said molecular sieves of at least one medium or large pore molecular sieve selected from one or more of crystalline silicoaluminates, silicoaluminophosphates or mesoporous silicoaluminates (co-catalyst) (A). MeAPO molecular sieves having CHA (SAPO-34) or AEI (SAPO-18) structure or mixture thereof are the most preferable. The present invention also relates to a process (hereunder referred as "XTO process") for making an olefin product from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock with the above catalyst. The present invention also relates to a "combined XTO and OCP process".
摘要翻译：本发明是一种催化剂复合材料，其包括：至少0.5重量％的至少一种金属盐，其在XTO条件下是稳定的，和至少10重量％的分子筛，其包含 - 70％至100％至少一种小孔硅铝酸盐或金属铝磷酸盐（MeAPO）分子筛的所述分子筛的重量和0至30重量％的所述分子筛至少一种选自一种或多种结晶硅铝酸盐，硅铝磷酸盐的中孔或大孔分子筛或介孔硅铝酸盐（助催化剂）（A）。具有CHA（SAPO-34）或AEI（SAPO-18）结构的MeAPO分子筛或其混合物是最优选的。本发明还涉及用含有上述催化剂的含氧卤化物或含硫有机原料制造烯烃产物的方法（以下称为“XTO法”）。本发明还涉及“组合的XTO和OCP方法”。

9. 发明申请

WO2009156433A3 PROCESS TO MAKE OLEFINS FROM OXYGENATES 审中-公开
标题翻译：从氧化剂制备油脂的方法
公开(公告)号：WO2009156433A3
公开(公告)日：2010-02-18
申请号：PCT/EP2009057887
申请日：2009-06-24
申请人： TOTAL PETROCHEMICALS RES FELUY , NESTERENKO NIKOLAI , VERMEIREN WALTER , GRASSO GIACOMO , VAN DONK SANDER , GARCIA WOLFGANG
发明人： NESTERENKO NIKOLAI , VERMEIREN WALTER , GRASSO GIACOMO , VAN DONK SANDER , GARCIA WOLFGANG
IPC分类号： C07C1/20 , B01J29/40 , B01J37/28
CPC分类号： C07C1/22 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J37/10 , B01J38/12 , B01J2229/16 , B01J2229/186 , B01J2229/36 , C07C1/20 , C07C1/26 , C07C1/322 , C07C4/06 , C07C2529/40 , C10G3/44 , C10G3/49 , C10G3/62 , C10G9/00 , C10G55/04 , C10G2400/20 , Y02P20/584 , Y02P30/20 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : a) providing a catalyst comprising zeolitic molecular sieves containing 10 member and larger channels in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting said oxygen-containing, halogenide-containing or sulphur- containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins.
摘要翻译：本发明涉及一种在组合的XTO-OC方法中由含氧的含卤素或含硫有机原料制备轻质烯烃的方法，包括：a）提供包含含有10个成员的沸石分子筛和在其微孔结构中较大的通道，b）提供XTO反应区，OC反应区和催化剂再生区，所述催化剂在三个区中循环，使得至少一部分再生催化剂通过OC反应区，将OC反应区中的至少一部分催化剂通入XTO反应区，并将XTO反应区中的至少一部分催化剂通入再生区; c）在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃部分的XTO反应器流出物的条件下，将XTO反应器中的含氧，含卤素或含硫有机原料与催化剂接触 ; d）从所述重质烃馏分中分离出所述轻质烯烃; e）使OC反应器中的所述重质烃馏分与催化剂在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下接触。

10. 发明申请

WO2009156435A3 PROCESS TO MAKE OLEFINS AND AROMATICS FROM ORGANICS 审中-公开
标题翻译：从有机物制备油脂和芳香油的工艺
公开(公告)号：WO2009156435A3
公开(公告)日：2010-02-18
申请号：PCT/EP2009057889
申请日：2009-06-24
申请人： TOTAL PETROCHEMICALS RES FELUY , NESTERENKO NIKOLAI , VERMEIREN WALTER , GRASSO GIACOMO , VAN DONK SANDER , GARCIA WOLFGANG
发明人： NESTERENKO NIKOLAI , VERMEIREN WALTER , GRASSO GIACOMO , VAN DONK SANDER , GARCIA WOLFGANG
IPC分类号： C07C1/20 , B01J29/40 , B01J37/28
CPC分类号： C07C1/20 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J38/12 , B01J2229/16 , B01J2229/18 , B01J2229/36 , B01J2229/37 , C07C1/26 , C07C1/322 , C07C2/864 , C07C4/06 , C07C2529/40 , Y02P20/584 , Y02P30/42 , C07C15/02 , C07C11/02
摘要： The present invention relates to a process to make light olefins and aromatics, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide- containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction and the second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction and oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to light olefins and aromatics.
摘要翻译：本发明涉及一种在组合的XTO-OC方法中由含氧，含卤素或含硫有机原料制备轻质烯烃和芳族化合物的方法，包括：a0）提供第一部分和第二部分所述含氧，含卤素或含硫有机原料，a）提供包含在其微孔结构中含有至少10元环孔孔或更大的沸石分子筛的催化剂，b）提供XTO反应区，OC反应区域和催化剂再生区，所述催化剂在三个区域中循环，使得至少一部分再生催化剂通过OC反应区，OC反应区中的至少一部分催化剂通过XTO 反应区和XTO反应区中的至少一部分催化剂通入再生区; c）在有效地转化至少一部分原料以形成包含轻质烯烃的XTO反应器流出物的条件下，将XTO反应器中的含氧卤化物或含硫有机原料的第一部分与催化剂接触，重质烃馏分; d）从所述重质烃馏分中分离出所述轻质烯烃; e）在OC反应器中将所述重质烃部分和第二部分所述含氧卤化物或含硫有机原料与所述催化剂接触，所述条件有效地将至少一部分所述重质烃部分和氧 - 含有卤化物或含硫有机原料至轻质烯烃和芳族化合物。

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