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1. 发明申请

WO2019016375A1 HYDROTREATING CATALYST WITH A TITANIUM CONTAINING CARRIER AND SULFUR CONTAINING ORGANIC ADDITIVE 审中-公开
公开(公告)号：WO2019016375A1
公开(公告)日：2019-01-24
申请号：PCT/EP2018/069775
申请日：2018-07-20
申请人： ALBEMARLE EUROPE SPRL
发明人： ALCANIZ, Jana Juan , BERGWERFF, Jacob Arie , AU-YEUNG, Kar-Ming , VEERMAN, Wilhelmus Clemens Jo
IPC分类号： B01J21/06 , B01J37/20 , B01J23/74 , B01J23/882 , B01J23/883 , B01J23/888 , B01J27/19 , B01J37/02 , C10G45/04 , C10G45/06 , C10G45/08
摘要： Generally, it is disclosed a catalyst for use in a hydrotreating hydrocarbon feedstocks and the method of making such catalyst. It is generically provided that the catalyst comprises at least one Group VIB metal component, at least one Group VIII metal component, about (1) to (about (30) wt% C, and preferably about (1) to about (20) wt% C, and more preferably about (5) to about 15 wt% C of one or more sulfur containing organic additive and a titanium-containing carrier component, wherein the amount of the titanium component is in the range of about (3) to (about (60) wt%, expressed as an oxide (Ti0 2 ) and based on the total weight of the catalyst. The titanium-containing carrier is formed by co-extruding or precipitating a titanium source with a A1203 precursor to form a porous support material comprising A1 2 0 3 or by impregnating a titanium source onto a porous support material comprising A1 2 0 3 .

2. 发明申请

WO2016005391A1 ALKYLATION PROCESS USING A CATALYST COMPRISING CERIUM RICH RARE EARTH CONTAINING ZEOLITES AND A HYDROGENATION METAL 审中-公开
标题翻译：使用包含含稀土元素的含有沸石和氢化金属的催化剂的烷基化方法
公开(公告)号：WO2016005391A1
公开(公告)日：2016-01-14
申请号：PCT/EP2015/065481
申请日：2015-07-07
申请人： ALBEMARLE EUROPE SPRL
发明人： VAN BROEKHOVEN, Emanuel Hermanus , VAN LOEVEZIJN, Arnold , BAKKER, Richard Hendrik Marc
IPC分类号： C10G29/20 , B01J29/08 , C07C2/58 , B01J35/02 , B01J38/56 , B01J38/58 , B01J29/12 , B01J29/70 , B01J29/90
CPC分类号： B01J29/068 , B01J29/085 , B01J29/12 , B01J29/7057 , B01J29/7415 , C07C2/58 , C07C2529/068 , C10G29/205 , C10G2300/70 , C10G2400/02
摘要： An improved alkylation process utilizing a solid-acid catalyst comprising a cerium rich rare earth containing zeolite and a hydrogenation metal is disclosed.
摘要翻译：公开了利用包含富含铈的稀土类沸石和氢化金属的固体酸催化剂的改进的烷基化方法。

3. 发明申请

WO2014056846A1 SUPPORTED HYDROTREATING CATALYSTS HAVING ENHANCED ACTIVITY 审中-公开
标题翻译：支持加氢催化剂具有增强活性
公开(公告)号：WO2014056846A1
公开(公告)日：2014-04-17
申请号：PCT/EP2013/070826
申请日：2013-10-07
申请人： ALBEMARLE EUROPE SPRL
发明人： BASTIAAN, Maarten Vogelaar , BERGWERFF, Jacob Arie , VAN OENE, Johan , TROMP, Henk Jan
IPC分类号： B01J37/02 , B01J27/188 , B01J27/19 , C10G45/08 , C10G49/04 , B01J38/52 , B01J38/62 , B01J31/06 , B01J35/10 , B01J37/20
CPC分类号： B01J31/06 , B01J27/188 , B01J27/19 , B01J35/023 , B01J35/1019 , B01J37/0203 , B01J37/0217 , B01J37/0219 , B01J37/20 , B01J38/52 , B01J38/62 , B01J2231/64 , C10G45/00 , C10G45/08
摘要： This invention provides supported catalysts comprising a carrier, phosphorus, at least one Group VI metal, at least one Group VIII metal, and a polymer. In the catalyst, the molar ratio of phosphorus to Group VI metal is about 1:1.5 to less than about 1:12, the molar ratio of the Group VI metal to the Group VIII metal is about 1:1 to about 5:1, and the polymer has a carbon backbone and comprises functional groups having at least one heteroatom. Also provided are a process for preparing such supported catalysts, as well as methods for hydrotreating, hydrodenitrogenation, and/or hydro desulfurization, using supported catalysts.
摘要翻译：本发明提供了载体催化剂，其包含载体，磷，至少一种第Ⅵ族金属，至少一种Ⅷ族金属和聚合物。在催化剂中，磷与Ⅵ族金属的摩尔比为约1:1.5至小于约1:12，第Ⅵ族金属与Ⅷ族金属的摩尔比为约1:1至约5:1，并且聚合物具有碳骨架并且包含具有至少一个杂原子的官能团。还提供了制备这种负载催化剂的方法，以及使用负载催化剂的加氢处理，加氢脱氮和/或加氢脱硫的方法。

4. 发明申请

WO2014023758A3 SELECTIVE CATALYTIC DEOXYGENATION OF BIOMASS AND CATALYSTS THEREFOR 审中-公开
标题翻译：生物质和催化剂的选择性催化去氧化
公开(公告)号：WO2014023758A3
公开(公告)日：2014-04-17
申请号：PCT/EP2013066532
申请日：2013-08-07
申请人： ALBEMARLE EUROPE SPRL
发明人： VASIC MILENA , KOCH MELLE , PRONK MARTINUS HENRICUS , VAN DEN OETELAAR LEONARDUS CORNELIS ALBERTUS , VAN DUREN RUBEN
IPC分类号： C10G1/02 , B01J21/16 , B01J23/00 , B01J23/06 , B01J23/10 , B01J23/28 , B01J23/34 , B01J23/78 , B01J23/83 , B01J23/847 , C10B53/02 , C10B57/06 , C10C5/00 , C10G1/08
CPC分类号： B01J23/8474 , B01J21/16 , B01J23/007 , B01J23/10 , B01J23/28 , B01J23/34 , B01J23/78 , B01J23/83 , B01J27/236 , B01J37/0201 , B01J37/0207 , B01J37/0213 , B01J37/08 , B01J37/082 , C10B49/22 , C10B53/02 , C10B57/06 , C10C5/00 , C10G1/02 , C10G1/08 , C10G1/086 , Y02E50/14 , Y02P30/20
摘要： This invention provides new, effective pyrolysis catalysts adapted for use in pyrolysis of biomass, to the preparation of such catalysts, and to the use of such catalysts in the pyrolysis of biomass in the absence of added air, added molecular oxygen, and added molecular hydrogen, and liquids such as water. The catalysts are layered HTCs and related materials which are impregnated with specified pairs of metals, which impregnated layered HTCs and related materials have been calcined in air at elevated temperatures.
摘要翻译：本发明提供了适用于生物质热解的新的有效的热解催化剂，这种催化剂的制备，以及在没有添加的空气，加入的分子氧和加入的分子氢的情况下在生物质的热解中使用这种催化剂，和液体如水。催化剂是分层的HTC和相关材料，它们用特定的金属对浸渍，浸渍的层状HTC和相关材料已经在高温下在空气中煅烧。

5. 发明申请

WO2012059256A1 HYDRODEOXYGENATION OF PYROLYSIS OIL IN PRESENCE OF ADMIXED ALCOHOL 审中-公开
标题翻译：溶解性醇的热解反应
公开(公告)号：WO2012059256A1
公开(公告)日：2012-05-10
申请号：PCT/EP2011/064897
申请日：2011-08-30
申请人： ALBEMARLE EUROPE SPRL , VAN BROEKHOVEN, Emanuel Hermanus , KLOMP, Ralph , PRONK, Ruben Theodoor , GERRITSEN, Leendert Arie , PLANTENGA, Frans Lodewijk , STEENWINKEL, Edgar Evert
发明人： VAN BROEKHOVEN, Emanuel Hermanus , KLOMP, Ralph , PRONK, Ruben Theodoor , GERRITSEN, Leendert Arie , PLANTENGA, Frans Lodewijk , STEENWINKEL, Edgar Evert
IPC分类号： C10G45/00
CPC分类号： C07C1/22 , B01J23/85 , B01J23/883 , B01J37/20 , C10G3/46 , C10G3/50 , C10G2300/4006 , C10G2300/4081 , C10G2300/42 , Y02P30/20
摘要： The present invention relates to the hydrodeoxygenation of pyrolysis oils in the presence of an alcohol.
摘要翻译：本发明涉及在醇存在下热解油的加氢脱氧。

6. 发明申请

WO2010142448A3 SAPO MOLECULAR SIEVE CATALYSTS AND THEIR PREPARATION AND USES 审中-公开
标题翻译： SAPO分子筛催化剂及其制备和用途
公开(公告)号：WO2010142448A3
公开(公告)日：2011-03-24
申请号：PCT/EP2010003493
申请日：2010-06-10
申请人： ALBEMARLE EUROPE SPRL , MIES MARTIJN J M , HARTE MARK H , STEENWINKEL EDGAR EVERT , VAN BROEKHOVEN EMANUEL HERMANUS
发明人： MIES MARTIJN J M , HARTE MARK H , STEENWINKEL EDGAR EVERT , VAN BROEKHOVEN EMANUEL HERMANUS
IPC分类号： B01J29/85 , B01J37/10 , C01B39/54 , C10G45/64
CPC分类号： B01J29/85 , B01J29/005 , B01J37/10 , B01J2229/18 , C01B39/54 , C07C5/2775 , C07C2529/85 , C10G45/64 , C07C9/22
摘要： Novel silicoaluminophosphate molecular sieve compositions comprising SAPO-11 and SAPO-41 with at least about 5 wt% of in s/Yw-produced amorphous portion. Such compositions can be uncalcined or calcined and novel processes for their preparation are described. These compositions, when loaded or impregnated with a catalytically active species such as a Group VIII noble metal are novel, and are excellent hydroisomerization catalysts.
摘要翻译：新型硅铝磷酸盐分子筛组合物，其包含SAPO-11和SAPO-41，其具有至少约5重量％的s / Yw产生的无定形部分。这些组合物可以是未煅烧的或煅烧的，并且描述了它们制备的新方法。当用催化活性物质如VIII族贵金属负载或浸渍时，这些组合物是新颖的，并且是优异的加氢异构化催化剂。

7. 发明申请

WO2011023668A2 SOLUTIONS AND CATALYSTS COMPRISING GROUP VI METAL, GROUP VIII METAL, AND PHOSPHORUS 审中-公开
标题翻译：包含第VI组金属，第VIII族金属和磷的溶液和催化剂
公开(公告)号：WO2011023668A2
公开(公告)日：2011-03-03
申请号：PCT/EP2010/062282
申请日：2010-08-24
申请人： ALBEMARLE EUROPE SPRL , EIJSBOUTS-SPICKOVA, Sona , JANSEN, Marcel Adriaan
发明人： EIJSBOUTS-SPICKOVA, Sona , JANSEN, Marcel Adriaan
IPC分类号： B01J23/888
CPC分类号： B01J27/19 , B01J21/04 , B01J23/88 , B01J23/888 , B01J27/1853 , B01J37/0203 , B01J37/0213 , B01J37/0236 , B01J37/08 , C10G45/00 , C10G45/08 , C10G49/04
摘要： This invention provides a process for forming a solution composition, which process comprises forming a primary solution by bringing together, in an aqueous medium, i) at least one phosphorus compound, ii) at least one Group VI metal compound, iii) at least one Group VIII metal compound, and iv) an additive which is a) tetraethylene glycol, b) polyethylene glycol having an average molecular weight in the range of about 200 to about 400, c) a mixture of tetraethylene glycol and polyethylene glycol having an average molecular weight in the range of about 200 to about 400, or d) a mixture of (1) tetraethylene glycol and/or polyethylene glycol having an average molecular weight in the range of about 200 to about 400 and (2) one or more of monoethylene glycol, diethylene glycol, and triethylene glycol. The molar ratio of additive to the total moles of Group VI metal and Group VIII metal is above 0.30:1, and the atomic ratio of phosphorus to Group VI metal is at least about 0.33: 1. Optionally, the primary solution is heated at a temperature above about 40°C to form a heated solution. The heated solution is optionally cooled to form a cooled solution. Also provided are compositions formed by such processes, processes for forming catalyst compositions from these compositions, and catalyst compositions formed by these processes.
摘要翻译：本发明提供一种形成溶液组合物的方法，该方法包括通过在水性介质中聚合来形成初级溶液，i）至少一种磷化合物，ii）至少一种VI族金属化合物，iii）至少一种 VIII族金属化合物，和iv）a）四乙二醇，b）平均分子量在约200至约400范围内的聚乙二醇的添加剂，c）四甘醇和聚乙二醇的混合物，其平均分子量重量在约200至约400的范围内，或d）平均分子量在约200至约400范围内的（1）四甘醇和/或聚乙二醇的混合物，和（2）一种或多种单乙烯乙二醇，二甘醇和三甘醇。 VI族金属和VIII族金属的添加剂与总摩尔数的摩尔比高于0.30:1，磷与Ⅵ族金属的原子比为至少约0.33:1。任选地，将第一溶液加热至温度高于约40℃以形成加热溶液。加热的溶液任选地冷却以形成冷却的溶液。还提供了通过这些方法形成的组合物，由这些组合物形成催化剂组合物的方法，以及由这些方法形成的催化剂组合物。

8. 发明申请

WO2010079044A3 PROCESS FOR AROMATIC HYDROGENATION AND CETANE VALUE INCREASE OF MIDDLE-DISTILLATE FEEDSTOCKS 审中-公开
公开(公告)号：WO2010079044A3
公开(公告)日：2010-07-15
申请号：PCT/EP2009/067003
申请日：2009-12-11
申请人： TOTAL RAFFINAGE MARKETING , ALBEMARLE EUROPE SPRL , DATH, Jean-Pierre , VAN DONK, Sander , GRASSO, Giacomo , LODEWIJK PLANTENGA, Frans , NIEMAN, Jan
发明人： DATH, Jean-Pierre , VAN DONK, Sander , GRASSO, Giacomo , LODEWIJK PLANTENGA, Frans , NIEMAN, Jan
IPC分类号： C10G45/52 , C10G45/04 , C10G45/08 , C10G65/08 , B01J21/12 , B01J37/04
摘要： The instant invention pertains to a process for treating a feed, for example a Light Cycle Oil (LCO), having a high content of S and/ or N impurities and/ or a high content of aromatics, comprising the following steps, in particular in such an order a step of desulphurisation (HD S) and denitrification (HDN) of a feed, in particular LCO, is passed in presence of hydrogen over a catalyst, containing metals of the group VI B and VIII, leading to an effluent, optionally a step of stripping of the effluent, at least a subsequent step for dearomatization (HDA) in which at least a portion of the effluent, optionally stripped, is passed in presence of hydrogen over a catalyst comprising a combination of platinum and palladium supported on a carrier comprising silica-alumina dispersed in an alumina binder wherein the amount of alumina binder is 5-50 wt. % based on the total weight of the silica-alumina and alumina binder present in the carrier and wherein the silica-alumina comprises 5-50 wt. % of alumina based on the weight of the silica-alumina, and recovering the final load obtained, the use of a specific catalyst and a process for preparing diesel comprising the step of mixing the final effluent obtained by a process of the invention.

9. 发明申请

WO2014056846A9 SUPPORTED HYDROTREATING CATALYSTS HAVING ENHANCED ACTIVITY 审中-公开
公开(公告)号：WO2014056846A9
公开(公告)日：2014-04-17
申请号：PCT/EP2013/070826
申请日：2013-10-07
申请人： ALBEMARLE EUROPE SPRL
发明人： VOGELAAR, Bastiaan Maarten , BERGWERFF, Jacob Arie , VAN OENE, Johan , TROMP, Henk Jan
IPC分类号： B01J37/02 , B01J27/188 , B01J27/19 , C10G45/08 , C10G49/04 , B01J38/52 , B01J38/62 , B01J31/06 , B01J35/10 , B01J37/20
摘要： This invention provides supported catalysts comprising a carrier, phosphorus, at least one Group VI metal, at least one Group VIII metal, and a polymer. In the catalyst, the molar ratio of phosphorus to Group VI metal is about 1:1.5 to less than about 1:12, the molar ratio of the Group VI metal to the Group VIII metal is about 1:1 to about 5:1, and the polymer has a carbon backbone and comprises functional groups having at least one heteroatom. Also provided are a process for preparing such supported catalysts, as well as methods for hydrotreating, hydrodenitrogenation, and/or hydro desulfurization, using supported catalysts.

10. 发明申请

WO2011113827A1 METAL CARBONATE CONTAINING CATALYSTS AND THEIR USE IN SOLID BASIC CATALYST-CATALYZED REACTIONS 审中-公开
标题翻译：含有催化剂的金属碳酸盐及其在固体催化剂催化反应中的应用
公开(公告)号：WO2011113827A1
公开(公告)日：2011-09-22
申请号：PCT/EP2011/053884
申请日：2011-03-15
申请人： ALBEMARLE EUROPE SPRL , KOCH, Melle , THEWISSEN, Simone , VAN DER GRIEND, Hans , NUBERG, Edwin , FREE, Harmannus Willem Homan , VAN DER BEEK, David , STEENWINKEL, Edgar Evert
发明人： KOCH, Melle , THEWISSEN, Simone , VAN DER GRIEND, Hans , NUBERG, Edwin , FREE, Harmannus Willem Homan , VAN DER BEEK, David , STEENWINKEL, Edgar Evert
IPC分类号： B01J23/02 , C10L1/00 , C11C3/00
CPC分类号： B01J23/02 , C10L1/02 , C11C3/003
摘要： The present invention relates to catalysts comprising a metal component containing at least one metal component selected from Group IA metals of the Periodic Table, Group HA metals of the Periodic Table, and mixtures thereof, and at least one additional component, wherein said metal component comprises at least one oxide and at least one carbonate of the at least one metal, their preparation, and their use. The present invention also relates to methods of preparing such catalysts and the use thereof.
摘要翻译：本发明涉及包含含有至少一种选自元素周期表IA族金属，元素周期表HA族金属及其混合物中的至少一种金属组分的金属组分和至少一种另外的组分，其中所述金属组分包括至少一种氧化物和至少一种所述至少一种金属的碳酸盐，它们的制备及其用途。本发明还涉及制备这种催化剂的方法及其用途。

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