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    • 4. 发明申请
    • IONIC LIQUIDS FOR HETEROGENISING METALLOCENE CATALYSTS
    • 用于异构金属催化剂的离子液体
    • WO2005085305A1
    • 2005-09-15
    • PCT/EP2005/050859
    • 2005-03-01
    • TOTAL PETROCHEMICALS RESEARCH FELUYCENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUELAVASTRE, OlivierBONNETTE, FabienRAZAVI, Abbas
    • LAVASTRE, OlivierBONNETTE, FabienRAZAVI, Abbas
    • C08F110/06
    • C08F110/06C08F4/65912C08F4/65916C08F4/65927
    • The present invention discloses a method for preparing an heterogeniseded catalyst component comprising the steps of: a) providing a halogenated precursor component of formula (I) -X-[-CH 2 ]-CH 3 b) reacting the halogenated precursor with an ionic liquid precursor in a solvent to prepare an ionic liquid; IL + X - c) optionally, reacting the intermediate IL + X - with a salt C + A - , wherein C + is a cation that can be selected from K + , Na + , NH4 + , and A - is an anion that can be selected from PF 6 - , SbF 6 - , BF 4 - , (CF 3 -SO 2 ) 2 N - CIO 4 -, CF 3 SO 3 - , NO 3 - or CF 3 CO 2 - . d) using the ionic liquid prepared in step b) to heterogenise a metallocene component of formula (II) R" (CpR m ) (Cp'R n ) MQ 2 wherein Cp and C'p are independen tly selected from substituted or unsubstituted cyclopentadienyl groups M is a metal selected from Group 4 of the Periodic Table, R" is a structural bridge imparting stereorigidity between Cp and Cp' and Q is a halogen or an alkyl having from 1 to 12 carbo n atoms; e) heterogenising the ionic liquid/metal system by addition of an apolar solvent inducing the precipitation reaction; f) retrieving a metallocene catalyst component heterogenised by an ionic liquid. It also discloses an active catalyst system hetero genised by an ionic liquid and its use in the polymerisation of olefins.
    • 本发明公开了一种制备异质化催化剂组分的方法,包括以下步骤:a)提供式(I)的卤代前体组分-X - [ - CH 2] -CH 3 b)使卤化前体与离子液体前体反应 制备离子液体的溶剂; C 1 -C 6烷基,C 1 -C 6烷基,C 1 -C 6烷基,C 1 -C 6烷基, +,Na +,NH 4 +和A - 是可以选自PF 6 - ,SbF 6 - ,BF 4 - ,(CF 3 -SO 2)2 N - CIO4-,CF3SO3 - ,NO3-或CF3CO2 - 。 d)使用步骤b)中制备的离子液体使式(Ⅱ)R“(CpR m)(Cp'R n)MQ2的茂金属组分异构化,其中Cp和C'p独立地选自被取代的 或未取代的环戊二烯基M是选自周期表第4族的金属,R“是赋予Cp和Cp'之间立体刚性的结构桥,Q是卤素或具有1至12个碳原子的烷基; e)通过添加引起沉淀反应的非极性溶剂使离子液体/金属体系异源化; f)检索由离子液体异源化的茂金属催化剂组分。 它还公开了由离子液体杂化的活性催化剂体系及其在烯烃聚合中的用途。