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    • 2. 发明申请
    • AVERMECTIN B1 AND AVERMECTIN B1 MONOSACCHARIDE DERIVATIVES HAVING AN ALKOXYMETHYL SUBSTITUENT IN THE 4”- OR 4’-POSITION
    • 在4“或4”位置具有烷氧基甲基取代基的AVERMECTIN B1和AVERMECTIN B1单糖衍生物
    • WO2004056844A1
    • 2004-07-08
    • PCT/EP2003/014613
    • 2003-12-19
    • SYNGENTA PARTICIPATIONS AGMAIENFISCH, PeterMURPHY KESSABI, FionaCASSAYRE, JérômeQUARANTA, LauraPITTERNA, ThomasHUETER, Ottmar, FranzJUNG, Pierre
    • MAIENFISCH, PeterMURPHY KESSABI, FionaCASSAYRE, JérômeQUARANTA, LauraPITTERNA, ThomasHUETER, Ottmar, FranzJUNG, Pierre
    • C07H17/08
    • C07H17/08
    • What is described are a compound of the formula (I): wherein n is 0 or 1; A-B is -CH=CH- or -CH 2 -CH 2 -; R 1 is C 1 -C 12 -alkyl, C 3 -C 8 -cycloalkyl or C 2 -C 12 -alkenyl; R 2 is for example C 1 -C 12 -alkyl, C 2 -C 12 -alkenyl or C 2 -C 12 -alkinyl; which are optionally substituted with one to five substituents selected from the group consisting of OH, halogen, CN, -N 3 , -N0 2 , C 3 -C 8 -Cycloalkyl, norbornylenyl-, C 3 -C 8­ Cycloalkenyl; C 3 -C 8 - halocycloalkyl, C l -C 12 -alkoxy, C 1 -C 6 -alkoxy-C 1 -C 6 -alkoxy, C 3 -C 8 -cycloalkoxy, C 1 -C 12 -­haloalkoxy, C 1 -C 12 -alkylthio, C 3 -C 8 -cycloalkylthio, C 1 -C 12 -haloalkylthio, C l -C 12 alkylsulfinyl, C 3 -C 8 -cycloalkylsulfinyl, C 1 -C 12 -haloalkylsulfinyl, C 3 -C 8 - halocycloalkylsulfinyl, C l -C 12 -alkylsulfonyl, C 3 -C 8 -cycloalkylsulfonyl, C 1 -C 12 ­haloalkylsulfonyl, C 3 -C 8 -halocycloalkylsulfonyl, -NR 4 R 6 , -X-C(=Y)-R 4 , -X-C(=Y)-Z-R 4 , -P(=O)(OC l -C 6 -alkyl) 2 , aryl, heterocyclyl, aryloxy, arylthio and heterocyclyloxy; R 3 is for example H, C 1 -C 12 -alkyl or C 1 -C 12 -alkyl which is optionally substituted and, where applicable, to E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in salt form; a process for preparing and using these compounds and their tautomers; pesticides whose active compound is selected from these compounds and their tautomers; and a process for preparing these compounds and compositions, and the use of these compounds and compositions.
    • 描述的是式(I)的化合物:其中n是0或1; A-B是-CH = CH-或-CH 2 -CH 2 - ; R1是C1-C12-烷基,C3-C8-环烷基或C2-C12-烯基; R2是例如C1-C12-烷基,C2-C12-烯基或C2-C12-炔基; 其任选被一至五个选自OH,卤素,CN,-N 3,-NO 2,C 3 -C 8 - 环烷基,降冰片烯基 - ,C 3 -C 8环烯基的取代基取代; C 3 -C 8 - 卤代环烷基,C 1 -C 12 - 烷氧基,C 1 -C 6 - 烷氧基-C 1 -C 6 - 烷氧基,C 3 -C 8 - 环烷氧基,C 1 -C 12 - 卤代烷氧基,C 1 -C 12 - 烷硫基,C 3 -C 8环烷硫基, C 1 -C 12烷基亚磺酰基,C 3 -C 8环烷基亚磺酰基,C 1 -C 12卤代烷基亚磺酰基,C 3 -C 8卤代环烷基亚磺酰基,C 1 -C 12烷基磺酰基,C 3 -C 8环烷基磺酰基,C 1 -C 12卤代烷基磺酰基,C 3 -C 8卤代环烷基磺酰基, NR4R6,-XC(= Y)-R4,-XC(= Y)-Z-R4,-P(= O)(OCl-C6-烷基)2,芳基,杂环基,芳氧基,芳硫基和杂环氧基; R3是例如任选取代的H,C 1 -C 12 - 烷基或C 1 -C 12 - 烷基,并且在适用的情况下,E / Z异构体,E / Z异构体和/或互变异构体的混合物,在每种情况下为游离形式或 盐形式 一种制备和使用这些化合物及其互变异构体的方法; 活性化合物选自这些化合物及其互变异构体的农药; 以及制备这些化合物和组合物的方法,以及这些化合物和组合物的用途。
    • 3. 发明申请
    • AVERMECTINS AND AVERMECTIN MONOSACCHARIDES SUBSTITUTED IN THE 4’- AND 4’’-POSITION HAVING PESTICIDAL PROPERTIES
    • 在具有农药性质的4'-和4'位置取代的AVERMECTINS和AVERMECTIN单糖
    • WO2004069853A1
    • 2004-08-19
    • PCT/EP2004/000977
    • 2004-02-03
    • SYNGENTA PARTICIPATIONS AGMURPHY KESSABI, FionaCASSAYRE, JérômeQUARANTA, LauraPITTERNA, ThomasMAIENFISCH, Peter
    • MURPHY KESSABI, FionaCASSAYRE, JérômeQUARANTA, LauraPITTERNA, ThomasMAIENFISCH, Peter
    • C07H17/08
    • C07H17/08A01N43/90
    • What is described are a compound of the formula (I) wherein the bond of atoms C 22 and C 23 is a single or double bond; m is 0 or l; n is 0, 1 or 2; p is 0 or l; R 1 is C 1 -C 12 -alkyl, C 3 -C 8 -cycloalkyl or C 2 -C 12 -alkenyl; R 2 is for example H, C 1 -C 12 -alkyl, C 1 -C 12 -haloalkyl or C 1 -C 12 -hydroxyalkyl; or together with R 4 form with the carbon to which they are bound for example a three- to seven-membered ring; R 3 is for example H, C 1 -C 12 -alkyl, halogen, halo-C 1 -C 2 alkyl, CN, N0 2 or C 3 -C 8 cycloalkyl; R 4 has the same meanings as R 2 ; R 5 and R 6 independently of each other are for example H, C 1 -C 12 -alkyl, CN, N0 2 , OH, SH, halogen, halo-C 1 -­C 2 alkyl or C 3 -C 8 cycloalkyl; or, if appropriate, an E/Z isomer, E/Z isomer mixture and/or tautomer thereof, in each case in free form or in salt form a process for preparing and using these compounds and their tautomers; pesticides whose active compound is selected from these compounds and their tautomers; and a process for preparing these compounds and compositions, and the use of these compounds and compositions.
    • 描述的是式(I)的化合物,其中原子C 22和C 23的键是单键或双键; m为0或1; n为0,1或2; p为0或1; R1是C1-C12-烷基,C3-C8-环烷基或C2-C12-烯基; R2是例如H,C1-C12-烷基,C1-C12卤代烷基或C1-C12-羟基烷基; 或与R 4一起形成与它们所键合的碳例如三至七元环; R 3是例如H,C 1 -C 12 - 烷基,卤素,卤代-C 1 -C 2烷基,CN,NO 2或C 3 -C 8环烷基; R4与R2相同; R 5和R 6彼此独立地是例如H,C 1 -C 12 - 烷基,CN,NO 2,OH,SH,卤素,卤代-C 1 -C 2烷基或C 3 -C 8环烷基; 或者如果适用,E / Z异构体,E / Z异构体混合物和/或其互变异构体在每种情况下以游离形式或盐形成用于制备和使用这些化合物及其互变异构体的方法; 活性化合物选自这些化合物及其互变异构体的农药; 以及制备这些化合物和组合物的方法,以及这些化合物和组合物的用途。
    • 5. 发明申请
    • AVERMECTINS SUBSTITUTED IN THE 4” AND 4’-POSITIONS HAVING PESTICIDAL PROPERTIES
    • 在具有农药性质的4“和4”位置中取代
    • WO2004069852A1
    • 2004-08-19
    • PCT/EP2004/000972
    • 2004-02-03
    • SYNGENTA PARTICIPATIONS AGCASSAYRE, JérômeTOBLER, HansPITTERNA, ThomasMAIENFISCH, PeterMURPHY KESSABI, FionaQUARANTA, LauraHUETER, Ottmar, Franz
    • CASSAYRE, JérômeTOBLER, HansPITTERNA, ThomasMAIENFISCH, PeterMURPHY KESSABI, FionaQUARANTA, LauraHUETER, Ottmar, Franz
    • C07H17/08
    • C07H17/08
    • What is described are a compound of the formula (I) Wherein A-B is -CH=CH- or -CH 2 -CH 2 -; n is 0 or 1; R 1 , is C 1 -C 12 alkyl, C 3 -C 8 cycloalkyl or C 2 -C 12 alkenyl; R 2 and R 3 for instance are either, (i) independently from each other for instance -Q, -C(=Y)-Q, or -C(=Y)-O-Q; or (ii) together form with the nitrogen atom to which they are bound a three- to seven-membered ring, (iii) together are =C(R 4 )R 5 ; R 4 and R 5 are, independently from each other, for instance -Q, -C(=Y)-Q, or -C(=Y)-O-Q; Y is O or S; Q is for instance H or unsubstituted or mono- to pentasubstituted C 1 -C 12 alkyl; or, if appropriate, an E/Z isomer, E/Z isomer mixture and/or tautomer thereof; a process for preparing these compounds, their isomers and tautomers and the use of these compounds, their isomers and tautomers; pesticidal compositions whose active compound is selected from these compounds and their tautomers; intermediates for the preparation of the said compounds of the formula (I), methods for the preparation of the compounds of the formula (I), and a method for controlling pests using these compositions.
    • 描述的是式(I)的化合物,其中A-B是-CH = CH-或-CH 2 -CH 2 - ; n为0或1; R1是C1-C12烷基,C3-C8环烷基或C2-C12链烯基; R 2和R 3例如是(i)彼此独立地例如-Q,-C(= Y)-Q或-C(= Y)-O-Q; 或(ii)与其结合的氮原子一起形成三至七元环,(iii)一起为= C(R 4)R 5; R 4和R 5彼此独立地为例如-Q,-C(= Y)-Q或-C(= Y)-O-Q; Y为O或S; Q为例如H或未取代或单取代或未取代的C 1 -C 12烷基; 或者,如果合适的话,E / Z异构体,E / Z异构体混合物和/或其互变异构体; 制备这些化合物,其异构体和互变异构体的方法以及这些化合物,其异构体和互变异构体的用途; 活性化合物选自这些化合物及其互变异构体的杀虫组合物; 用于制备所述式(I)化合物的中间体,式(I)化合物的制备方法和使用这些组合物来控制害虫的方法。
    • 8. 发明申请
    • AVERMECTIN AND AVERMECTIN MONOSACCHARIDE DERIVATIVES SUBSTITUTED IN THE 4”- OR 4’-POSITION HAVING PESTICIDAL PROPERTIES
    • 在具有农药性质的4“或4”位置中取代的AVERMECTIN和AVERMECTIN单糖衍生物
    • WO2004067543A1
    • 2004-08-12
    • PCT/EP2004/000890
    • 2004-01-30
    • SYNGENTA PARTICIPATIONS AGPITTERNA, ThomasMURPHY KESSABI, FionaMAIENFISCH, PeterCASSAYRE, JéromeQUARANTA, LauraJUNG, Pierre
    • PITTERNA, ThomasMURPHY KESSABI, FionaMAIENFISCH, PeterCASSAYRE, JéromeQUARANTA, LauraJUNG, Pierre
    • C07H17/08
    • A01N43/90C07H17/08
    • What is described are a compound of the formula (I) Wherein U is -N(R 2 )OR 3 or -N + (O - )=C(R E )R Z ); n is 0 or 1; X-Y is -CH=CH- or -CH 2 -CH 2 -; R 1 is C 1 -C 12 alkyl, C 3 -C 8 cycloalkyl or C 2 -C 12 alkenyl; R 2 and R 3 are, for example; independently from each other, -Q, -C(=O)-Z-Q or -CN; R Z and R E are, independently from each other, -Q, -C(=O)-Z-Q or -CN; or R Z and R E together are a three- to seven membered alkylene or alkenylene bridge, which is unsubstituted or mono- to tri-substituted; Z is a bond, O or -NR 4 -; Q is H, C 1 -C 12 alkyl, C 2 -C 12 alkenyl, C 2 -C 12 alkynyl, C 3 -C 12 -cycloalkyl, C 5 -C 12 -cycloalkenyl, aryl, or heterocyclyl, which are unsubstituted or mono- to pentasubstituted; R 4 is for example H, C 1 -C 8 alkyl, hydroxy-C l -C 8 alkyl, C 3 -C 8 cycloalkyl or C 2 -C 8 alkenyl; or, if appropriate, an E/Z isomer, E/Z isomer mixture and/or tautomer thereof; a process for preparing these compounds, their isomers and tautomers and the use of these compounds, their isomers and tautomers; pesticidal compositions whose active compound is selected from these compounds and their tautomers; intermediates for the preparation of the said compounds of the formula (I), methods for the preparation of the compounds of the formula (I), and a method for controlling pests using these compositions.
    • 描述的是式(I)的化合物,其中U是-N(R 2)OR 3或-N +(O - )= C(RE)R Z); n为0或1; X-Y是-CH = CH-或-CH 2 -CH 2 - ; R1是C1-C12烷基,C3-C8环烷基或C2-C12链烯基; R2和R3例如是: 独立地为-Q,-C(= O)-Z-Q或-CN; RZ和RE彼此独立地为-Q,-C(= O)-Z-Q或-CN; 或RZ和RE一起是三至七元的亚烷基或亚烯基桥,其是未取代的或一至三取代的; Z是O或-NR4-键; Q是未被取代的或被一或五取代的H,C 1 -C 12烷基,C 2 -C 12烯基,C 2 -C 12炔基,C 3 -C 12环烷基,C 5 -C 12 - 环烯基,芳基或杂环基, R4是例如H,C1-C8烷基,羟基-C1-C8烷基,C3-C8环烷基或C2-C8链烯基; 或者,如果合适的话,E / Z异构体,E / Z异构体混合物和/或其互变异构体; 制备这些化合物,其异构体和互变异构体的方法以及这些化合物,其异构体和互变异构体的用途; 活性化合物选自这些化合物及其互变异构体的杀虫组合物; 用于制备所述式(I)化合物的中间体,式(I)化合物的制备方法和使用这些组合物来控制害虫的方法。