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    • 7. 发明申请
    • DIHYDROPYRROLE DERIVATIVES AS INSECTICIDAL COMPOUNDS
    • 作为杀虫剂化合物的二氢衍生物衍生物
    • WO2013026929A1
    • 2013-02-28
    • PCT/EP2012/066550
    • 2012-08-24
    • SYNGENTA PARTICIPATIONS AGCASSAYRE, Jérôme YvesRENOLD, PeterPITTERNA, ThomasEL QACEMI, Myriem
    • CASSAYRE, Jérôme YvesRENOLD, PeterPITTERNA, ThomasEL QACEMI, Myriem
    • C07D409/12A01N43/36
    • C07D409/12
    • The present invention provides compounds of formula (I), wherein G 1 is oxygen; R 1 is hydrogen; R 2 is group P L is a bond, methylene or ethylene; one of A 1 and A 2 is S, SO or S0 2 and the other is -C(R 4 )R 4 - R 3 is hydrogen or methyl; each R 4 is independently hydrogen or methyl; Y 1 is C-R 6 , CH or nitrogen; Y 2 and Y 3 are independently CH or nitrogen; wherein no more than two of Y 1 , Y 2 and Y 3 are nitrogen and wherein Y 2 and Y 3 are not both nitrogen; R 5 is hydrogen, halogen, cyano, nitro, NH 2 , -C 2 alkyl, C 3 -C 2 haloalkyl, C 3 -C 5 cycloalkyl, C 3 - C 5 halocycloalkyl, C 1 -C 2 alkoxy, C 1 -C 2 haloalkoxy; R 6 together with R 5 forms a -CH=CH-CH=CH- bridge; X 2 is C-X 6 or nitrogen; X1, X 3 and X 6 are independently hydrogen, halogen or trihalomethyl, wherein at least two of X 1 , X 3 and X 6 are not hydrogen; X 4 is trifluoromethyl, difluoromethyl or chlorodifluoromethyl. The invention also provides intermediates useful for the preparation of compounds of formula I, as well as methods of controlling insects, acarines, nematodes or molluscs using the compounds of formula I.
    • 本发明提供式(I)化合物,其中G1是氧; R1是氢; R2是基团P L是键,亚甲基或亚乙基; A1和A2之一是S,SO或SO 2,另一个是-C(R 4)R 4 -R 3是氢或甲基; 每个R 4独立地是氢或甲基; Y1是C-R6,CH或氮; Y2和Y3独立地是CH或氮; 其中Y1,Y2和Y3中不超过两个是氮,并且其中Y2和Y3不都是氮; R5是氢,卤素,氰基,硝基,NH2,-C2烷基,C3-C2卤代烷基,C3-C5环烷基,C3-C5卤代环烷基,C1-C2烷氧基,C1-C2卤代烷氧基; R6与R5一起形成-CH = CH-CH = CH-桥; X2是C-X6或氮; X1,X3和X6独立地为氢,卤素或三卤代甲基,其中X 1,X 3和X 6中的至少两个不是氢; X4是三氟甲基,二氟甲基或氯二氟甲基。 本发明还提供了可用于制备式I化合物的中间体,以及使用式I化合物控制昆虫,螨虫,线虫或软体动物的方法。