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    • 2. 发明申请
    • CHEMICAL COMPOUNDS
    • 化学化合物
    • WO2009092590A2
    • 2009-07-30
    • PCT/EP2009/000416
    • 2009-01-23
    • SYNGENTA PARTICIPATIONS AGPITTERNA, ThomasRENOLD, PeterHUETER, Ottmar, FranzMAIENFISCH, PeterZAMBACH, Werner
    • PITTERNA, ThomasRENOLD, PeterHUETER, Ottmar, FranzMAIENFISCH, PeterZAMBACH, Werner
    • C07D307/32C07D307/52C07D307/79
    • C07D307/79A01N41/10A01N43/08A01N43/10A01N43/12A01N43/28A01N43/36A01N43/40A01N43/653C07C311/20C07C311/29C07C323/49C07C2601/08C07D207/27C07D249/08C07D307/32C07D307/52C07D333/20C07D333/78C07D405/12
    • A compound of the formula (I) where, for example, W, X and Y are each CH; R 1 and R 6 , independently of each other, are for example, selected from the group consisting of H, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-alkoxy, C3-C8-cycloalkyl, R 7 C(=O), and a ring system; provided that at least one of R 1 and R 6 is a - C2-C6-alkenylthio-C1 -C6-alkyl, - C1 -C6-alkoxy-C(=O)NRx-C1-C6-alkyl, - partially or fully unsaturated ring system containing in at least one ring in the ring system at least one hetero atom selected from N, O and S, which ring system is bound (i.e. through the N bonded to R 1 and R 6 in formula I) either directly or via a a C1-C6-alkylene group to the remainder of the compound, - partially or fully unsaturated ring system containing a ring that is bound to the remainder of the compound (i.e. through the N bonded to R 1 and R 6 in formula I) via a C1-C6-alkylene group, which group contains at least one hetero atom and/or heteroatom group selected from N, O, S, SO, SO 2 , and C(=0), - a ring system having a 5- to 14-membered bicylic ring which may be unsubstituted or be substituted with 1, 2 or 3, independently of one another, radicals selected from halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy and C1-C6-haloalkoxy, or - (C3-C8-cyloalkyl)thio-C1 -C6-alkyl; R 2 is, for example, H, halogen, C1 -C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy or C1-C6-alkoxy-C1 -C6-alkoxy, and/or salts thereof; and their use as as pesticidal agents.
    • 式(I)的化合物,其中例如W,X和Y各自为CH; R 1和R 6彼此独立地例如选自H,C 1 -C 6 - 烷基,C 2 -C 6 - 烯基,C 2 -C 6 - 炔基,C 1 -C 6 - 烷氧基,C 3 -C 8 - 环烷基 ,R7C(= O)和环系统; 条件是R 1和R 6中的至少一个是C 1 -C 6 - 烯基硫基-C 1 -C 6 - 烷基,-C 1 -C 6 - 烷氧基-C(= O)NR x -C 1 -C 6烷基, - 部分或完全不饱和环 系统中至少一个环中含有至少一个选自N,O和S的杂原子,该环系统结合(即通过与式I中的R 1和R 6键合的N)直接或经由C1- C6-亚烷基与化合物的其余部分, - 部分或完全不饱和的环体系,其含有与化合物的其余部分结合的环(即,通过与式I中的R 1和R 6键合的N)经C1-C6- 亚烷基,该基团含有至少一个选自N,O,S,SO,SO 2和C(= O)的杂原子和/或杂原子, - 具有5至14元双环的环系, 可以是未取代的或被1,2或3个彼此独立地取代,选自卤素,C 1 -C 6 - 烷基,C 1 -C 6 - 卤代烷基,C 1 -C 6 - 烷氧基和C 1 -C 6 - 卤代烷氧基的基团,或 - ( C3-C8-环烷基)次 io-C 1 -C 6 - 烷基; R 2是例如H,卤素,C 1 -C 6 - 烷基,C 1 -C 6 - 卤代烷基,C 1 -C 6 - 烷氧基,C 1 -C 6 - 卤代烷氧基或C 1 -C 6 - 烷氧基-C 1 -C 6 - 烷氧基,和/ 物; 以及其作为杀虫剂的用途。
    • 6. 发明申请
    • AVERMECTINS SUBSTITUTED IN THE 4” AND 4’-POSITIONS HAVING PESTICIDAL PROPERTIES
    • 在具有农药性质的4“和4”位置中取代
    • WO2004069852A1
    • 2004-08-19
    • PCT/EP2004/000972
    • 2004-02-03
    • SYNGENTA PARTICIPATIONS AGCASSAYRE, JérômeTOBLER, HansPITTERNA, ThomasMAIENFISCH, PeterMURPHY KESSABI, FionaQUARANTA, LauraHUETER, Ottmar, Franz
    • CASSAYRE, JérômeTOBLER, HansPITTERNA, ThomasMAIENFISCH, PeterMURPHY KESSABI, FionaQUARANTA, LauraHUETER, Ottmar, Franz
    • C07H17/08
    • C07H17/08
    • What is described are a compound of the formula (I) Wherein A-B is -CH=CH- or -CH 2 -CH 2 -; n is 0 or 1; R 1 , is C 1 -C 12 alkyl, C 3 -C 8 cycloalkyl or C 2 -C 12 alkenyl; R 2 and R 3 for instance are either, (i) independently from each other for instance -Q, -C(=Y)-Q, or -C(=Y)-O-Q; or (ii) together form with the nitrogen atom to which they are bound a three- to seven-membered ring, (iii) together are =C(R 4 )R 5 ; R 4 and R 5 are, independently from each other, for instance -Q, -C(=Y)-Q, or -C(=Y)-O-Q; Y is O or S; Q is for instance H or unsubstituted or mono- to pentasubstituted C 1 -C 12 alkyl; or, if appropriate, an E/Z isomer, E/Z isomer mixture and/or tautomer thereof; a process for preparing these compounds, their isomers and tautomers and the use of these compounds, their isomers and tautomers; pesticidal compositions whose active compound is selected from these compounds and their tautomers; intermediates for the preparation of the said compounds of the formula (I), methods for the preparation of the compounds of the formula (I), and a method for controlling pests using these compositions.
    • 描述的是式(I)的化合物,其中A-B是-CH = CH-或-CH 2 -CH 2 - ; n为0或1; R1是C1-C12烷基,C3-C8环烷基或C2-C12链烯基; R 2和R 3例如是(i)彼此独立地例如-Q,-C(= Y)-Q或-C(= Y)-O-Q; 或(ii)与其结合的氮原子一起形成三至七元环,(iii)一起为= C(R 4)R 5; R 4和R 5彼此独立地为例如-Q,-C(= Y)-Q或-C(= Y)-O-Q; Y为O或S; Q为例如H或未取代或单取代或未取代的C 1 -C 12烷基; 或者,如果合适的话,E / Z异构体,E / Z异构体混合物和/或其互变异构体; 制备这些化合物,其异构体和互变异构体的方法以及这些化合物,其异构体和互变异构体的用途; 活性化合物选自这些化合物及其互变异构体的杀虫组合物; 用于制备所述式(I)化合物的中间体,式(I)化合物的制备方法和使用这些组合物来控制害虫的方法。
    • 7. 发明申请
    • AVERMECTIN B1 AND AVERMECTIN B1 MONOSACCHARIDE DERIVATIVES HAVING AN ALKOXYMETHYL SUBSTITUENT IN THE 4”- OR 4’-POSITION
    • 在4“或4”位置具有烷氧基甲基取代基的AVERMECTIN B1和AVERMECTIN B1单糖衍生物
    • WO2004056844A1
    • 2004-07-08
    • PCT/EP2003/014613
    • 2003-12-19
    • SYNGENTA PARTICIPATIONS AGMAIENFISCH, PeterMURPHY KESSABI, FionaCASSAYRE, JérômeQUARANTA, LauraPITTERNA, ThomasHUETER, Ottmar, FranzJUNG, Pierre
    • MAIENFISCH, PeterMURPHY KESSABI, FionaCASSAYRE, JérômeQUARANTA, LauraPITTERNA, ThomasHUETER, Ottmar, FranzJUNG, Pierre
    • C07H17/08
    • C07H17/08
    • What is described are a compound of the formula (I): wherein n is 0 or 1; A-B is -CH=CH- or -CH 2 -CH 2 -; R 1 is C 1 -C 12 -alkyl, C 3 -C 8 -cycloalkyl or C 2 -C 12 -alkenyl; R 2 is for example C 1 -C 12 -alkyl, C 2 -C 12 -alkenyl or C 2 -C 12 -alkinyl; which are optionally substituted with one to five substituents selected from the group consisting of OH, halogen, CN, -N 3 , -N0 2 , C 3 -C 8 -Cycloalkyl, norbornylenyl-, C 3 -C 8­ Cycloalkenyl; C 3 -C 8 - halocycloalkyl, C l -C 12 -alkoxy, C 1 -C 6 -alkoxy-C 1 -C 6 -alkoxy, C 3 -C 8 -cycloalkoxy, C 1 -C 12 -­haloalkoxy, C 1 -C 12 -alkylthio, C 3 -C 8 -cycloalkylthio, C 1 -C 12 -haloalkylthio, C l -C 12 alkylsulfinyl, C 3 -C 8 -cycloalkylsulfinyl, C 1 -C 12 -haloalkylsulfinyl, C 3 -C 8 - halocycloalkylsulfinyl, C l -C 12 -alkylsulfonyl, C 3 -C 8 -cycloalkylsulfonyl, C 1 -C 12 ­haloalkylsulfonyl, C 3 -C 8 -halocycloalkylsulfonyl, -NR 4 R 6 , -X-C(=Y)-R 4 , -X-C(=Y)-Z-R 4 , -P(=O)(OC l -C 6 -alkyl) 2 , aryl, heterocyclyl, aryloxy, arylthio and heterocyclyloxy; R 3 is for example H, C 1 -C 12 -alkyl or C 1 -C 12 -alkyl which is optionally substituted and, where applicable, to E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in salt form; a process for preparing and using these compounds and their tautomers; pesticides whose active compound is selected from these compounds and their tautomers; and a process for preparing these compounds and compositions, and the use of these compounds and compositions.
    • 描述的是式(I)的化合物:其中n是0或1; A-B是-CH = CH-或-CH 2 -CH 2 - ; R1是C1-C12-烷基,C3-C8-环烷基或C2-C12-烯基; R2是例如C1-C12-烷基,C2-C12-烯基或C2-C12-炔基; 其任选被一至五个选自OH,卤素,CN,-N 3,-NO 2,C 3 -C 8 - 环烷基,降冰片烯基 - ,C 3 -C 8环烯基的取代基取代; C 3 -C 8 - 卤代环烷基,C 1 -C 12 - 烷氧基,C 1 -C 6 - 烷氧基-C 1 -C 6 - 烷氧基,C 3 -C 8 - 环烷氧基,C 1 -C 12 - 卤代烷氧基,C 1 -C 12 - 烷硫基,C 3 -C 8环烷硫基, C 1 -C 12烷基亚磺酰基,C 3 -C 8环烷基亚磺酰基,C 1 -C 12卤代烷基亚磺酰基,C 3 -C 8卤代环烷基亚磺酰基,C 1 -C 12烷基磺酰基,C 3 -C 8环烷基磺酰基,C 1 -C 12卤代烷基磺酰基,C 3 -C 8卤代环烷基磺酰基, NR4R6,-XC(= Y)-R4,-XC(= Y)-Z-R4,-P(= O)(OCl-C6-烷基)2,芳基,杂环基,芳氧基,芳硫基和杂环氧基; R3是例如任选取代的H,C 1 -C 12 - 烷基或C 1 -C 12 - 烷基,并且在适用的情况下,E / Z异构体,E / Z异构体和/或互变异构体的混合物,在每种情况下为游离形式或 盐形式 一种制备和使用这些化合物及其互变异构体的方法; 活性化合物选自这些化合物及其互变异构体的农药; 以及制备这些化合物和组合物的方法,以及这些化合物和组合物的用途。