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    • 2. 发明申请
    • USE OF FUEL COMPOSITION
    • 燃料组合物的使用
    • WO2006108854A1
    • 2006-10-19
    • PCT/EP2006/061549
    • 2006-04-12
    • SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.CLAYTON, Christopher WilliamDAHLSTROM, Mary AnnLEE, George RobertPRICE, Richard JohnSMITH, Susan JaneTAIT, Nigel PeterWALLINGTON, Jessica F
    • CLAYTON, Christopher WilliamDAHLSTROM, Mary AnnLEE, George RobertPRICE, Richard JohnSMITH, Susan JaneTAIT, Nigel PeterWALLINGTON, Jessica F
    • C10L1/08C10G25/00C10G25/02C10L10/04
    • C10L1/08C10G25/00C10G25/02C10G2300/205C10G2400/04C10L10/04
    • Use of a fuel composition comprising a major amount of a fuel suitable for use in a compression-ignition engine, which fuel comprises one or more hydrocarbon components boiling within the diesel boiling range, at least one of which hydrocarbon components has been treated with a metal adsorbing or absorbing material in a different physical phase from the hydrocarbon component(s), preferably to reduce the level of at least one metal, more preferably the level of at least one heavier metal, most preferably the level of copper and/or iron and/or zinc, in said at least one hydrocarbon component, said treatment including physical separation of the hydrocarbon component from the metal adsorbing or absorbing phase, for the purpose of reducing subsequent formation of deposits, preferably combustion related deposits, during engine operation in a compression- ignition engine into which the fuel composition is introduced and/or of removing from the engine previously incurred deposits. Preferably the level of deposits in the engine after engine operation with said fuel composition in the engine is lower than the level of deposits in the engine after engine operation with an alternative fuel composition in the engine, said alternative fuel composition having essentially the same characteristics as said fuel composition but the hydrocarbon components of which have not been treated with said metal adsorbing or absorbing material.
    • 使用包含主要量的适用于压燃式发动机的燃料的燃料组合物,该燃料包括在柴油沸程范围内沸腾的一种或多种烃组分,其中至少一种烃组分已用金属处理 吸附或吸收与烃组分不同物理相的材料,优选降低至少一种金属的含量,更优选至少一种较重金属的含量,最优选铜和/或铁的含量,以及 /或锌,在所述至少一种烃组分中,所述处理包括烃组分与金属吸附或吸收相的物理分离,以便在发动机操作期间在压缩中减少随后的沉积物形成,优选燃烧相关沉积物 - 点燃发动机,其中引入燃料组合物和/或从发动机中除去先前发生的沉积物。 发动机运转后发动机运转时发动机中沉积物的沉积物水平低于在发动机运转后发动机运转时的发动机沉积物水平,所述替代燃料组合物具有与 所述燃料组合物,但其烃组分未用所述金属吸附材料或吸收材料处理。
    • 8. 发明申请
    • LIQUID FUEL COMPOSITIONS BASED ON CATALYTICALLY DEOXYGENATED AND CONDENSATED OXYGENATED CARBONHYDRATES
    • 基于催化去氧化和浓缩氧化碳水化合物的液体燃料组合物
    • WO2010028206A1
    • 2010-03-11
    • PCT/US2009/055976
    • 2009-09-04
    • SHELL OIL COMPANYSHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.BAULDREAY, Joanna MargaretBLOMMEL, Paul GeorgeCORTRIGHT, Randy DouglasPRICE, Richard John
    • BAULDREAY, Joanna MargaretBLOMMEL, Paul GeorgeCORTRIGHT, Randy DouglasPRICE, Richard John
    • C10G3/00C10L1/04
    • C10L1/04C10G3/45C10G3/46C10G3/47C10G3/49C10G2300/1011C10G2300/20C10G2300/202C10G2300/301C10G2300/302C10G2300/305C10G2300/307C10G2300/308C10G2300/805C10G2400/02C10G2400/04C10G2400/08C10L1/02Y02P30/20
    • The present invention provides a liquid fuel composition comprising a distillation fraction of a component having at least one C 4+ compound derived from a water-soluble oxygenated hydrocarbon prepared by a method comprising: providing water and a water-soluble oxygenated hydrocarbon comprising a C 1+ O 1+ hydrocarbon in an aqueous liquid phase and/or a vapor phase; providing H 2 ; catalytically reacting in the liquid and/or vapor phase the oxygenated hydrocarbon with the H 2 in the presence of a deoxygenation catalyst at a deoxygenation temperature and deoxygenation pressure to produce an oxygenate comprising a C 1+ O 1-3 hydrocarbon in a reaction stream; and catalytically reacting in the liquid and/or vapor phase the oxygenate in the presence of a condensation catalyst at a condensation temperature and condensation pressure to produce the C 4+ compound, wherein the C 4+ compound comprises a member selected from the group consisting of C 4+ alcohol, C 4+ ketone, C 4+ alkane, C 4+ alkene, C 5+ cycloalkane, C 5+ cycloalkene, aryl, fused aryl, and a mixture thereof; wherein the liquid fuel composition is selected from: a gasoline composition having an initial boiling point in the range of from 15 °C to 70 °C (IP123), a final boiling point of at most 230 °C (IP123), a RON in the range of from 85 to 110 (ASTM D2699) and a MON in the range of from 75 to 100 (ASTM D2700); a diesel fuel composition having an initial boiling point in the range of from 130 °C to 230 °C (IP123), a final boiling point of at most 410 °C (IP123) and a cetane number in the range of from 35 to 120 (ASTM D613); and a kerosene composition having an initial boiling point in the range of from 80 to 150 °C, a final boiling point in the range of from 200 to 320 °C and a viscosity at -20° C in the range of from 0.8 to 10 mm 2 /s (ASTM D445).
    • 本发明提供了一种液体燃料组合物,其包含具有至少一种衍生自水溶性氧化烃的C4 +化合物的组分的蒸馏馏分,该方法包括:提供水和包含C1 + O1 +烃的水溶性氧化烃 在水性液相和/或气相中; 提供H2; 在脱氧催化剂存在下,在脱氧温度和脱氧压下,在液相和/或气相中氧化烃与H 2催化反应,以在反应流中产生包含C1 + O1-3烃的含氧化合物; 并在冷凝温度和冷凝压力下,在缩合催化剂存在下,在液相和/或气相中催化反应生成C4 +化合物,其中C4 +化合物包括选自C4 +醇,C4 + 酮,C4 +烷烃,C4 +烯烃,C5 +环烷烃,C5 +环烯烃,芳基,稠合芳基及其混合物; 其中所述液体燃料组合物选自:起始沸点在15℃至70℃(IP123),最终沸点至多230℃(IP123)的沸点的汽油组合物, 范围为85至110(ASTM D2699)和MON为75至100(ASTM D2700)范围内的MON; 初始沸点在130℃至230℃范围内(IP123),最终沸点至多410℃(IP123)和十六烷值在35至120范围内的柴油燃料组合物 (ASTM D613); 初馏点为80-150℃,终沸点为200-320℃,-20℃下的粘度在0.8-10的范围内的煤油组合物 mm2 / s(ASTM D445)。
    • 9. 发明申请
    • GASOLINE COMPOSITIONS
    • 汽油组合物
    • WO2010000760A2
    • 2010-01-07
    • PCT/EP2009/058227
    • 2009-06-30
    • SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.CLARKE, LionelFELIX-MOORE, AlisonLOUIS, Jurgen Johannes JacobusPRICE, Richard JohnSMITH, Johanne
    • CLARKE, LionelFELIX-MOORE, AlisonLOUIS, Jurgen Johannes JacobusPRICE, Richard JohnSMITH, Johanne
    • C10L1/14C10L1/182C10L1/185C10L1/19C10L10/10
    • C10L1/14C10L1/1824C10L1/1852C10L1/1855C10L1/19C10L10/10
    • The present invention provides a gasoline composition comprising: (i) base gasoline; and (ii) a composition comprising component A and at least one component selected from categories (a) and (b) below: (a) component B, and (b) one component selected from components C, D and E, wherein: component A is an ester or mixture of esters having formula (I): R 1 C(O)-O-R 2 wherein R 1 is selected from a C 1-6 alkyl group and R 2 is selected from a C 1-4 alkyl group and wherein the total number of carbon atoms in R 1 and R 2 is in the range of from 5-9, with the proviso that component A has a boiling point or boiling point range within the temperature range of from 90 to 200 0 C; component B is ethanol; component C is a compound of formula (II) or formula (III). wherein the R 3 , R 4 , R 5 and R 6 groups are independently selected from hydrogen and C 1-6 hydrocarbyl groups, with the proviso that component C has a boiling point or boiling point range of at most 110 0 C; component D is butanol; and component E is an ether of the general formula (IV): R 7 -O-C(Me) 3 wherein R 7 is selected from methyl, ethyl or mixtures thereof, wherein the concentration of the components in the composition is calculated using the following equation (equation I ). wherein : n = 1 is component B, n = 2 is component A, n = 3 is any one of components C, D or E, V fn is the volume fraction of the component n = 1, 2 or 3 in the composition comprising component A and at least one component selected from components B, C, D and E, E70 n is the blending E70 value of the component represented by n, E1OO n is the blending E1OO value of the component represented by n, E70 base is in the range of from 10 to 55 %vol., and ElOO base is in the range of from 35 to 75 %vol..
    • 本发明提供一种汽油组合物,其包含:(i)汽油; 和(ii)包含组分A和选自以下类别(a)和(b)中的至少一种组分的组合物:(a)组分B和(b)选自组分C,D和E的一种组分,其中:组分 A是具有式(I)的酯或酯的混合物:R 1 C(O)-O-R 2,其中R 1选自C 1-6烷基,R 2选自C 1-4烷基, R1和R2中的碳原子在5-9的范围内,条件是组分A的沸点或沸点范围在90至200℃的温度范围内; 组分B是乙醇; 组分C是式(II)或式(III)的化合物。 其中R 3,R 4,R 5和R 6基团独立地选自氢和C 1-6烃基,条件是组分C的沸点或沸点范围至多为110℃; 组分D为丁醇; 并且组分E是通式(IV)的醚:R7-OC(Me)3,其中R7选自甲基,乙基或其混合物,其中组合物中组分的浓度使用下式计算(方程式 一世 )。 其中:n = 1是组分B,n = 2是组分A,n = 3是组分C,D或E中的任一个,V fn是包含组分的组合物中组分n = 1,2或3的体积分数 A和至少一种选自组分B,C,D和E的组分,E70 n是由n表示的组分的共混E70值,E100n是由n表示的组分的共混E100值,E70base在 10至55%体积,ElOObase为35至75体积%。