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1. 发明申请

WO1991016329A1 ORGANOSILICIFIED COMPOUNDS AND MATERIALS AND DEVICES CONTAINING SAME 审中-公开
标题翻译：有机化合物及其含有的物质和装置
公开(公告)号：WO1991016329A1
公开(公告)日：1991-10-31
申请号：PCT/FR1991000338
申请日：1991-04-24
申请人： RHONE-POULENC CHIMIE , MIGNANI, Gérard , SOULA, Gérard
发明人： RHONE-POULENC CHIMIE
IPC分类号： C07F07/08
CPC分类号： G02F1/3619 , C07F7/0803
摘要： A sub-group of the organosilicified compounds of French Patent Application No 880514 is described. This sub-group has general formula (I) wherein n is 1-20; R2 is an electron acceptor grouping; R3 is a C1-8alkyl radical, hydrogen, an aryl radical an R1 radical or R2; R4 represents a C1-8alkyl radical, hydrogen, an aryl radical, an R1 radical when R3 is not R2 or an R2 radical when R3 is not an R1 radical; and/or R1 is chosen from the group composed of alkyls, aryls and, if n = 1, silyls. Applications: non-linear optics.
摘要翻译：描述了法国专利申请880514的有机硅化合物的一个亚组。该亚组具有通式（I），其中n为1-20; R2是电子受体分组; R3是C1-8烷基，氢，芳基，R1基或R2; 当R 3不是R 1基团时，R 3不是R 2或R 2基团，R 4表示C 1-8烷基，氢，芳基，R 1基团; 和/或R 1选自由烷基，芳基和（如果n = 1）甲硅烷基组成的组。应用：非线性光学。

2. 发明申请

WO1991002018A1 SEQUENCED COPOLYMERS ORIENTABLE SO AS TO HAVE A NON-LINEAR OPTICAL ACTIVITY 审中-公开
标题翻译：具有非线性光学活性的顺序共聚物
公开(公告)号：WO1991002018A1
公开(公告)日：1991-02-21
申请号：PCT/FR1990000567
申请日：1990-07-26
申请人： RHONE-POULENC CHIMIE , MIGNANI, Gérard , MEYRUEIX, Rémi , PRUD'HOMME, Christian
发明人： RHONE-POULENC CHIMIE
IPC分类号： C08G77/42
CPC分类号： G02F1/3617 , C08G18/3836 , C08G18/3838 , C08G18/384 , C08G18/678 , C08G18/778 , C08G77/42 , C08G77/455
摘要： The present invention relates to sequenced polymers comprising hyperpolarisable groups. These sequenced polymers comprise elastomeric (organopolysiloxane) and thermoplastic (polyurethane) sequences. The hyperpolymerisable groups are present especially in the thermoplastic sequences. These polymers may be polarised under the effect of a polarisation field in the low-temperature ranges like ambient temperature and very quickly revert to their unpolarised state once the polymerisation field is removed.

3. 发明申请

WO1997008225A1 FUNCTIONALISED INORGANIC OXIDE HYDROXYLATED CARRIER AND METHOD FOR PREPARING SAME 审中-公开
标题翻译：功能无机氧化羟基化载体及其制备方法
公开(公告)号：WO1997008225A1
公开(公告)日：1997-03-06
申请号：PCT/FR1996001294
申请日：1996-08-19
申请人： RHONE-POULENC CHIMIE , FISCHER, Christian , MIGNANI, Gérard , PRIOU, Christian
发明人： RHONE-POULENC CHIMIE
IPC分类号： C08G83/00
CPC分类号： C08G77/02 , C01P2002/82 , C01P2006/12 , C08G83/001 , C09C1/00 , C09C1/3081 , C09C1/3684 , C09C1/407 , C09C3/08 , Y10T428/2991 , Y10T428/2995 , Y10T428/2998
摘要： A hydroxylated inorganic oxide carrier is functionalised by grafting one or more types of polyhydrogenosiloxane oils with 10 - 200 siloxane units, said grafting being provided by the covalent bonds formed by a dehydrogenocondensation reaction between Si-H groupings of the polyhydrogenosiloxane oil and free hydroxyls of the hydroxylated carrier, and by the hydrogen bonds between the hydroxyls of the hydroxylated carrier and oxygen atoms of the polyhydrogenosiloxane oil, which has free Si-H groupings.
摘要翻译：羟基化无机氧化物载体通过用10-200硅氧烷单元接枝一种或多种类型的聚硅氧烷油来官能化，所述接枝由通过聚硅氧烷油的Si-H基团与游离羟基的脱氢缩合反应形成的共价键提供，羟基化载体，以及羟基化载体的羟基与具有游离Si-H基团的多羟基硅氧烷油的氧原子之间的氢键。

4. 发明申请

WO1997033034A1 METHOD FOR SOFTENING A FABRIC MATERIAL, PREVENTING YELLOWING THEREOF AND CONFERRING HYDROPHILIC PROPERTIES THERETO BY MEANS OF A POLYORGANOSILOXANE COMPOSITION 审中-公开
标题翻译：用于织造织物材料的方法，防止其被黄色和通过聚硅氧烷类组合物的水凝胶性质
公开(公告)号：WO1997033034A1
公开(公告)日：1997-09-12
申请号：PCT/FR1997000378
申请日：1997-03-04
申请人： RHONE-POULENC CHIMIE , BRANLARD, Paul , GUENNOUNI, Nathalie , MIGNANI, Gérard
发明人： RHONE-POULENC CHIMIE
IPC分类号： D06M15/643
CPC分类号： C08G77/388 , C08G77/46 , D06M15/643 , D06M15/6436 , D06M15/647
摘要： A method for conditioning fabric materials by conferring a pleasant feel and good hydrophilic properties thereto as well as preventing yellowing thereof, wherein the fabric materials are contacted with a composition including at least one linear, cyclic or three-dimensional polyorganosiloxane. The polyorganosiloxane includes identical or different units of general formula (I), wherein (1) a is 0, 1, 2 or 3, b is 0, 1, 2 or 3, c is 0, 1, 2 or 3, and a+b+c , and (4) the V symbols are identical and/or different functional residues and represent a residue with one or more sterically hindered piperidinyl groups.
摘要翻译：通过赋予织物材料舒适的手感和良好的亲水性以及防止其变黄来调理织物材料的方法，其中织物材料与包含至少一种线性，环状或三维聚有机硅氧烷的组合物接触。聚有机硅氧烷包括相同或不同的通式（I）单元，其中（1）a为0,1,2或3，b为0,1,2或3，c为0,1,2或3，和 + b + c 3，（2）R符号是一价烃基，（3）X符号是相同的和/或不同的官能残基，代表式（CH 2）n - （OCH 2 CH 2） OCH 2 CHCH 3）β-OR 2，和（4）V符号是相同和/或不同的功能残基，并且表示具有一个或多个空间位阻哌啶基的残基。

5. 发明申请

WO1991013116A1 COMPOSITIONS ACTIVE IN NON LINEAR OPTICS, MATERIALS AND SYSTEMS CONTAINING THEM 审中-公开
标题翻译：非线性光学元件，材料和包含它们的系统中的组合物
公开(公告)号：WO1991013116A1
公开(公告)日：1991-09-05
申请号：PCT/FR1991000150
申请日：1991-02-25
申请人： RHONE-POULENC CHIMIE , CAMBERLIN, Yves , MEYRUEIX, Rémi , MIGNANI, Gérard
发明人： RHONE-POULENC CHIMIE
IPC分类号： C08K05/00
CPC分类号： G02F1/3615 , C08K5/0041 , C08K5/23 , C08K5/315 , C08L35/00
摘要： These compositions are of the type comprising a matrix formed from a polymer base and at least one hyperpolarisable compound, the main constituent of the matrix being a thermosetting polymer containing an imide group, preferably a maleimide group.

6. 发明申请

WO1997047677A1 METHOD FOR PREPARING SILICONE OILS BY HYDROSILYLATION WITH POLYORGANOHYDROGENOSILOXANES AND UNITS CONTAINING AT LEAST ONE HYDROCARBON RING INCLUDING AN OXYGEN ATOM, IN THE PRESENCE OF A HETEROGENEOUS CATALYTIC COMPOSITION 审中-公开
标题翻译：通过在多异氰酸酯基硅氧烷中的氢化制备硅油的方法以及包含氧原子的至少一个烃环的单体，在异构催化组合物存在下
公开(公告)号：WO1997047677A1
公开(公告)日：1997-12-18
申请号：PCT/FR1997001055
申请日：1997-06-12
申请人： RHONE-POULENC CHIMIE , BREUNIG, Stefan , MIGNANI, Gérard
发明人： RHONE-POULENC CHIMIE
IPC分类号： C08G77/38
CPC分类号： C07F7/21 , C08G77/38
摘要： A method for preparing low-colour, low-turbidity silicone oils by the hydrosilylation of polyorganohydrogenosiloxanes with different or identical synthons containing at least one hydrocarbon ring including an oxygen atom, said reaction being carried out in the presence of a heterogeneous catalytic composition including a metal selected from the group which consists of cobalt, rhodium, ruthenium, platinum and nickel, and deposited on an inert substrate.
摘要翻译：一种通过使用含有至少一个包含氧原子的烃环的不同或相同合成体的聚有机氢硅氧烷的氢化硅烷化制备低色低浊硅油的方法，所述反应是在非均相催化组合物的存在下进行的，包括金属选自由钴，铑，钌，铂和镍组成的组，并沉积在惰性衬底上。

7. 发明申请

WO1995028352A1 NON-STOICHIOMETRIC TUNGSTEN CARBIDE 审中-公开
标题翻译：非铁氧体硬质合金
公开(公告)号：WO1995028352A1
公开(公告)日：1995-10-26
申请号：PCT/FR1995000492
申请日：1995-04-13
申请人： RHONE-POULENC CHIMIE , CHARPENEL, Maurice , CHASSAGNEUX, Evelyne , JACQUOT, Roland , MIGNANI, Gérard , VIALON, Marcel
发明人： RHONE-POULENC CHIMIE
IPC分类号： C01B31/34
CPC分类号： B01J27/22 , C01B32/949 , C01P2006/10 , C01P2006/80
摘要： A compound useful for tungsten- and carbon-based hydrogenation reactions, having an atomic ratio between carbon and tungsten of 0.5-2, which ratio differs by at least 1 % from the stoichiometry of any given compound (of tungsten and carbon) in the same range. The method for preparing the compound comprises (a) a pre-processing step performed in an inert gas under tungsten oxide reaction conditions, preferably in nitrogen, by heating to a temperature of 150-1000 DEG C, preferably 400-600 DEG C, advantageously for at least one hour approximately; (b) a step of reducing/carbonising the compound from step (a) by contacting it with a hydrogen- and carbon-containing body at a preferred temperature of 600-1200 DEG C, advantageously 900-1100 DEG C; (c) an optional hydrogenation/decoking step in which the compound is contacted with hydrogen and optionally an inert gas at a temperature of 600-1200 DEG C, advantageously 700-1100 DEG C, and preferably 700-900 DEG C; and (d) an optional pyrophoricity reducing step in which the compound is contacted, at a temperature of 0-50 DEG C, and preferably at around 20 DEG C, with a gas that is inert for said compound and has an oxygen content advantageously lower than 5 %, and preferably no higher than 2 %, until said compound is no longer pyrophoric. The compound is useful in organic synthesis.
摘要翻译：用于钨和碳的氢化反应的化合物，碳原子与钨的原子比为0.5-2，该比率与任何给定化合物（钨和碳）的化学计量比相差至少1％范围。制备该化合物的方法包括（a）在氧化钨反应条件下，优选在氮气中，通过加热到150-1000℃，优选400-600℃的温度，在惰性气体中进行预处理步骤至少一个小时左右; （b）通过在优选的温度为600-1200℃（有利地为900-1100℃）下使其与含氢和碳的物体接触来从步骤（a）中还原/碳化化合物的步骤; （c）任选的氢化/脱焦步骤，其中化合物与氢气和任选的惰性气体在600-1200℃，有利地为700-1100℃，优选700-900℃的温度下接触; 和（d）任选的自燃还原步骤，其中所述化合物在0-50℃，优选约20℃的温度下与对所述化合物是惰性的并且具有有利地较低的氧含量的气体接触不超过5％，优选不高于2％，直到所述化合物不再自燃。该化合物可用于有机合成。

8. 发明申请

WO1998000463A1 USE OF PLATINUM COMPLEXES PARTICULARLY AS HOMOGENEOUS AND HEAT ACTIVABLE CATALYSTS FOR HYDROSILYLATION 审中-公开
标题翻译：作为均相和热活化催化剂的铂络合物特别用于氢化反应
公开(公告)号：WO1998000463A1
公开(公告)日：1998-01-08
申请号：PCT/FR1997001157
申请日：1997-06-27
申请人： RHONE-POULENC CHIMIE , MIGNANI, Gérard , OSBORN, John , STEFFANUT, Pascal
发明人： RHONE-POULENC CHIMIE
IPC分类号： C08L83/04
CPC分类号： B01J31/1608 , B01J31/2291 , B01J31/2295 , B01J2231/323 , B01J2531/828 , C07F15/0086 , C08G77/08 , C08G77/12 , C08G77/14 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/24 , C08G77/70 , C08K5/0091 , C08L83/04 , C08L83/00 , C08L2666/52
摘要： The invention concerns the sphere of cross-linking and functionalizing reaction catalysis of polymer chains e.g. combined with silicon. In particular the invention discloses the use of novel platinum based catalytic systems that are heat activatable, homogeneous, stable, long lasting and highly efficient as catalysts. The reagents involved are polyorganosiloxanes (POS) SiH and POS SiVi. The platinum complexes employed are, for example, as in (A).
摘要翻译：本发明涉及聚合物链的交联和官能化反应催化的领域，例如结合硅。特别地，本发明公开了使用可作为催化剂作为可热活化，均相，稳定，持久和高效的新型铂基催化体系。所涉及的试剂是聚有机硅氧烷（POS）SiH和POS SiVi。所用的铂络合物例如如（A）所示。

9. 发明申请

WO1996016127A1 NEW SILICON COMPOUNDS WITH STERICALLY HINDERED LINEAR AMINE FUNCTIONS, USEFUL FOR THE HEAT AND LIGHT STABILIZATION OF POLYMERS 审中-公开
标题翻译：新型硅化合物，具有异质线性胺功能，有利于聚合物的热稳定性和光稳定性
公开(公告)号：WO1996016127A1
公开(公告)日：1996-05-30
申请号：PCT/FR1995001502
申请日：1995-11-15
申请人： RHONE-POULENC CHIMIE , KARRER, Philippe , MAS, Jean-Manuel , MIGNANI, Gérard
发明人： RHONE-POULENC CHIMIE
IPC分类号： C08L83/08
CPC分类号： C07F7/21 , C07C215/08 , C07F7/0838 , C08G77/388
摘要： The present invention relates to linear, cyclic or branched polyorganosiloxanes having, per molecule, at least three siloxyl patterns, of which at least one is a function pattern having the formula (I), wherein R is a phenyl C1-C4 alkyl radical, X contains a secondary or tertiary linear amine function linked to the silicon by a bond -Si-A-C, with A being a simple valence link or an oxygen atom. Said linear amine function may be, when A = valency link, a radical having the formula -R -CR R -NR -R , wherein R may be an alkylen or alkenylen rest; R and R may represent alkyl rests; R may be H or alkyl; and R is a tertiary alkyl. The present invention also relates to the utilisation of said polyorganosiloxanes in polymers in order to improve particularly their photostabilization.
摘要翻译：本发明涉及线性，环状或支化的聚有机硅氧烷，其每分子具有至少三个酪醇酰基图案，其中至少一个是具有式（I）的功能图案，其中R 1是苯基C 1 -C 4烷基基团X包含通过键-Si-AC与硅连接的仲或叔直链胺官能团，其中A是简单的价键或氧原子。当A =价键时，所述线性胺官能团可以是具有式-R 8 -CR 9 R 10 -NR 11 -R 12的基团，其中R 8可以是亚烷基或烯基保持基; R 9和R 10可以代表烷基; R 11可以是H或烷基; 并且R 12是叔烷基。本发明还涉及所述聚有机硅氧烷在聚合物中的利用，以便特别地改进其光稳定化。

10. 发明申请

WO1991002019A1 SEQUENCED COPOLYMERS HAVING A NON-LINEAR OPTICAL ACTIVITY 审中-公开
标题翻译：具有非线性光学活性的顺序共聚物
公开(公告)号：WO1991002019A1
公开(公告)日：1991-02-21
申请号：PCT/FR1990000566
申请日：1990-07-26
申请人： RHONE-POULENC CHIMIE , MIGNANI, Gérard , PRUD'HOMME, Christian , MEYRUEIX, Rémi
发明人： RHONE-POULENC CHIMIE
IPC分类号： C08G77/458
CPC分类号： C08G18/678 , C08G18/3836 , C08G18/3838 , C08G18/384 , C08G18/778 , C08G77/42 , C08G77/455 , G02F1/3617
摘要： The present invention relates to sequenced polymers with organopolysiloxane and polyurethane sequences. Especially in the polyurethane sequences, these polymers have hyperpolymerisable groups. Thus these polymers, when subjected to a polarising field, acquire properties making them non-linearly optically active. The polysiloxane sequences, in particular, give the material a certain flexibility.

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