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1. 发明申请

WO1994029227A1 PROCESS FOR PURIFYING SULPHIDE-CONTAINING WASTE WATER 审中-公开
标题翻译：用于净化含硫化物废水的方法
公开(公告)号：WO1994029227A1
公开(公告)日：1994-12-22
申请号：PCT/NL1994000132
申请日：1994-06-09
申请人： PAQUES B.V. , BUISMAN, Cees, Jan, Nico
发明人： PAQUES B.V.
IPC分类号： C02F03/34
CPC分类号： C01B17/05 , C02F3/345
摘要： A process is described for purifying waste water containing sulphide, comprising oxidising the sulphide to elemental sulphur in a reactor with sulphide-oxidising bacteria in the presence of oxygen, and separating from the waste water at least a part of the sulphur formed during the oxidation, while recycling a part of the elemental sulphur separated from the reactor effluent into the reactor in such a way that a concentration of elemental sulphur of at least 1 g/l is maintained in the reactor. The sulphur, in the form of aggregates, is used as a carrier material for the sulphide-oxidising bacteria.
摘要翻译：描述了一种用于净化含硫化物的废水的方法，包括在氧气存在下将硫化物氧化成具有硫化物 - 氧化细菌的反应器中的元素硫，并且从废水中分离氧化期间形成的至少一部分硫，同时将从反应器流出物分离的部分硫元素再循环到反应器中，使得在反应器中保持至少1g / l的元素硫浓度。以聚集体形式的硫用作硫化物 - 氧化细菌的载体材料。

2. 发明申请

WO1992017410A1 METHOD FOR REMOVING SULPHUR COMPOUNDS FROM WATER 审中-公开
标题翻译：从水中去除硫化合物的方法
公开(公告)号：WO1992017410A1
公开(公告)日：1992-10-15
申请号：PCT/NL1992000064
申请日：1992-04-03
申请人： PAQUES B.V. , BUISMAN, Cees, Jan, Nico
发明人： PAQUES B.V.
IPC分类号： C02F03/28
CPC分类号： C01B17/0259 , B01D53/84 , C01B17/0253 , C02F3/28 , C02F3/345 , Y02A50/2358 , Y02E50/343
摘要： The invention provides a method for removing sulphur compounds from water by anaerobic reduction of the sulphur compounds to sulphide, followed by partial oxidation of the sulphide to elementary sulphur. The anaerobic reduction is carried out at elevated temperature, either continuously at a temperature of 45-70 DEG C, or periodically at a temperature of 55-100 DEG C. If the reduction is carried out periodically, a single rise in temperature for a few hours to several days over a period of 3-6 months can suffice. The method is particularly applicable to the removal of sulphate, sulphite and thiosulphate.
摘要翻译：本发明提供一种通过将硫化合物氧化还原成硫化物，随后将硫化物部分氧化成单质硫，从水中除去硫化合物的方法。厌氧还原在高温下连续进行，温度为45-70℃，或周期性在55-100℃的温度下进行。如果周期性地进行还原，则单次升温几段在3-6个月内的几个小时到几天就足够了。该方法特别适用于去除硫酸盐，亚硫酸盐和硫代硫酸盐。

3. 发明申请

WO1992010270A1 PROCESS FOR THE REMOVAL OF SULPHUR COMPOUNDS FROM GASES 审中-公开
标题翻译：从气体中去除硫化合物的方法
公开(公告)号：WO1992010270A1
公开(公告)日：1992-06-25
申请号：PCT/NL1991000250
申请日：1991-12-04
申请人： PAQUES B.V. , BUISMAN, Cees, Jan, Nico
发明人： PAQUES B.V.
IPC分类号： B01D53/14
CPC分类号： C12M47/18 , B01D53/48 , B01D53/507 , B01D53/52 , B01D53/84 , C01B17/05 , C02F3/345 , C12M21/04 , Y02A50/2358 , Y02C10/06 , Y02E50/343 , Y10S423/17
摘要： A process for the removal of sulphur compounds from a gaseous effluent, comprising the steps of: a) contacting the gaseous effluent with an aqueous solution wherein sulphur compounds are dissolved: b) adjusting the concentration of buffering compounds such as carbonate and/or bicarbonate and/or phosphate in the aqueous solution to a value between 20 and 2000 meq/l; c) subjecting the aqueous solution containing sulphide to sulphide-oxidising bacteria in the presence of oxygen in a reactor wherein sulphide is oxidised to elemental sulphur; d) separating elemental sulphur from the aqueous solution; and e) recycling the aqueous solution to step a). This process is suitable for removing H2S from biogas, ventilation air etc. It can be used for removing SO2 from combustion gases by introducing the additional step, after step a) and before step c), of subjecting the aqueous solution containing the sulphur compounds to a reduction of the sulphur compounds to sulphide. H2S and SO2 removal is further enhanced by a residual sulphur content in the washing liquid of 1-50 g/l.
摘要翻译：一种从气态流出物中除去硫化合物的方法，包括以下步骤：a）使气体流出物与其中硫化合物溶解的水溶液接触：b）调节缓冲化合物如碳酸盐和/或碳酸氢盐的浓度， /或磷酸盐在水溶液中的值为20至2000meq / l; c）使含硫化物的水溶液在氧气存在下在硫酸盐氧化成元素硫的反应器中进行硫化物氧化细菌; d）从水溶液中分离元素硫; 和e）将水溶液再循环到步骤a）。该方法适用于从沼气，通风空气等中除去H2S。可以在步骤a）和步骤c）之后引入附加步骤，将含硫化合物的水溶液将硫化合物还原成硫化物。 H2S和SO2的去除通过洗涤液中残留的硫含量进一步提高了1-50g / l。

4. 发明申请

WO1997043033A1 PROCESS FOR THE PURIFICATION OF GASES CONTAINING HYDROGEN SULPHIDE 审中-公开
标题翻译：用于净化含硫化氢的气体的方法
公开(公告)号：WO1997043033A1
公开(公告)日：1997-11-20
申请号：PCT/NL1997000265
申请日：1997-05-12
申请人： PAQUES B.V. , BUISMAN, Cees, Jan, Nico , SOROKIN, Dimitri, Yuri , KUENEN, Johannes, Gijsbrecht , JANSSEN, Jozef, Hendrik , ROBERTSON, Lesley, Anne
发明人： PAQUES B.V.
IPC分类号： B01D53/84
CPC分类号： B01D53/1425 , B01D53/1418 , B01D53/1468 , B01D53/52 , C02F3/345 , C02F2103/18 , C12P3/00
摘要： The invention relates to a process for scrubbing a gas containing hydrogen sulphide and/or carbonyl sulphide, in which the spent scrubbing liquid is treated with autotrophic sulphide-oxidising bacteria capable of oxidising at high pH, and elemental sulphur is obtained, the elemental sulphur is separated and the treated scrubbing liquid is recycled to the gas scrubbing step. Before recycling, the scrubbing liquid may further be treated with heterotrophic thiosulphate-oxidising bacteria which produce polythionate which is useful for further enhancing the sulphide-scrubbing capacity of the scrubbing liquid.
摘要翻译：本发明涉及一种用于洗涤含硫化氢和/或硫化硫的气体的方法，其中废洗涤液体用能够在高pH下氧化的自养硫化物 - 氧化细菌处理，得到元素硫，元素硫为将处理后的洗涤液再循环至气体洗涤步骤。在再循环之前，洗涤液可以进一步用产生多硫酸盐的异养硫代硫酸盐氧化细菌处理，其可用于进一步提高洗涤液的硫化物洗涤能力。

5. 发明申请

WO1996030110A1 PROCESS FOR THE TREATMENT OF GASES 审中-公开
标题翻译：气体处理工艺
公开(公告)号：WO1996030110A1
公开(公告)日：1996-10-03
申请号：PCT/NL1996000126
申请日：1996-03-25
申请人： PAQUES B.V. , BUISMAN, Cees, Jan, Nico
发明人： PAQUES B.V.
IPC分类号： B01D53/84
CPC分类号： C02F3/30 , B01D53/52 , B01D53/84 , C01B17/05 , C02F3/302 , C02F3/345 , Y02A50/2358
摘要： An installation and a method are described for the treatment of a gas containing hydrogen sulphide, the gas (1) being washed in a first gas scrubber (5) with an alkaline wash liquid and the spent wash liquid (4) being treated in an aerobic reactor (6) with oxygen in the presence of sulphide-oxidising bacteria and the effluent (9) from the aerobic reactor (6) being re-used as wash liquid (3) and the elementary sulphur formed during the treatment with oxygen being removed from the effluent (19), the effluent (13) from which sulphur has been removed being treated in an anaerobic reactor (17) with sulphate-reducing bacteria and returned to the aerobic reactor (6). The installation and the method can also be used for simultaneous removal of SO2, COS, CS2, NH3 and HCN.
摘要翻译：描述了用于处理含有硫化氢的气体的装置和方法，气体（1）在第一气体洗涤器（5）中用碱性洗涤液体洗涤，废洗涤液体（4）在需氧中处理反应器（6）在硫化物 - 氧化细菌存在下用氧气和来自好氧反应器（6）的流出物（9）被再次用作洗涤液体（3），并且在氧气处理期间形成的元素硫被从在厌氧反应器（17）中用硫酸盐还原细菌处理已经除去硫的流出物（19），流出物（13），并返回到好氧反应器（6）。安装和方法也可用于同时除去SO2，COS，CS2，NH3和HCN。

6. 发明申请

WO1993024416A1 PROCESS FOR REMOVING SULPHUR COMPOUNDS FROM WATER 审中-公开
标题翻译：从水中除去硫化合物的方法
公开(公告)号：WO1993024416A1
公开(公告)日：1993-12-09
申请号：PCT/NL1993000107
申请日：1993-05-26
申请人： PAQUES B.V. , BUISMAN, Cees, Jan, Nico
发明人： PAQUES B.V.
IPC分类号： C02F03/28
CPC分类号： C02F3/30 , B01D53/84 , B01D2257/30 , C02F3/28 , C02F3/345 , Y02A50/2358 , Y02E50/343 , Y02W10/12
摘要： The invention provides a method for removing sulphur compounds from water which contains low levels of organic matter, by anaerobic reduction of the sulphur compounds to sulphide, followed by partial oxidation of the sulphide to elementary sulphur. The cost-increasing consumption of electron donor (nutrient) during the anaerobic reduction is lowered by one or more of the following measures: a1) keeping the sulphate concentration in the anaerobic effluent at at least 500 mg/l; a2) keeping the sulphite concentration in the anaerobic effluent at at least 100 mg/l; b) keeping the salt concentration, expressed in sodium ion equivalents, in the anaerobic medium at at least 3 g/l; c) keeping the sulphide concentration in the anaerobic influent at at least 100 mg/l; d) introducing an inhibitor into the anaerobic treatment medium, which inhibitor is more toxic to the methane-producing bacteria than to incompletely oxidising sulphate-reducing bacteria or sulphate-reducing bacteria oxidising compounds having one carbon atom.
摘要翻译：本发明提供一种通过将硫化合物厌氧还原成硫化物，然后将硫化物部分氧化成单质硫，从含水量低的有机物质中除去硫化合物的方法。在厌氧还原期间，电子供体（营养）的成本增加消耗被降低了以下一种或多种措施：a1）将厌氧流出物中的硫酸盐浓度保持在至少500mg / l; a2）将厌氧流出物中的亚硫酸盐浓度保持在至少100 mg / l; b）将在厌氧培养基中以钠离子当量表示的盐浓度保持在至少3g / l; c）将厌氧流入物中的硫化物浓度保持在至少100 mg / l; d）向厌氧处理介质中引入抑制剂，该抑制剂对产生甲烷的细菌更具毒性，不如不完全氧化具有一个碳原子的硫酸盐还原菌或硫酸盐还原菌氧化化合物。

7. 发明申请

WO1991016269A1 PROCESS FOR THE TREATMENT OF WATER CONTAINING SULPHUR COMPOUNDS 审中-公开
标题翻译：含硫硫化合物的处理方法
公开(公告)号：WO1991016269A1
公开(公告)日：1991-10-31
申请号：PCT/NL1991000059
申请日：1991-04-11
申请人： PAQUES B.V. , BUISMAN, Cees, Jan, Nico
发明人： PAQUES B.V.
IPC分类号： C02F03/30
CPC分类号： C02F3/06 , C01B17/06 , C02F3/28 , C02F3/345 , Y02W10/15 , Y10S210/903 , Y10S210/912
摘要： A process is provided for the treatment of water containing sulphide wherein the sulphide is oxidized in an aerobic reactor having a minimum sulphide sludge load. The minimum sulphide load is at least 10 mg of sulphide per mg of the nitrogen present in the sludge per hour, the sludge load being calculated on the basis of the sulphide oxidizing part of the biomass. The minimum sulphide load may also be defined as 25 mg of sulphide per liter of reactor material per hour. The sulphide can be largely oxidized to elemental sulphur which is then separated and reused. Waste water also containing organic matter in addition to varying levels of sulphide is purified without interference of filamentous bacteria using a two step aerobic process. The process for sulphide removal can be used for the treatment of waste water having high levels of sulphur compounds such as sulphate, sulphite and thiosulphate by first reducing these sulphur compounds in an aerobic step. Heavy metals are removed from water by adding sulphide to the water and precipitating the metals as sulphides; the sulphide can be added by reducing sulphur compounds already present.
摘要翻译：提供了一种处理含硫硫化物的方法，其中硫化物在具有最小硫化物污泥负荷的需氧反应器中被氧化。最小硫化物负荷是每小时每个污泥中存在的氮至少10毫克的硫化物，污泥负荷是基于生物质的硫化物氧化部分计算的。最小硫化物负载也可以定义为每小时每升反应器材料25mg硫化物。硫化物可以很大程度上被氧化成元素硫，然后将其分离并重复使用。除了不同程度的硫化物之外，还含有有机物质的废水在不受丝状细菌干扰的情况下使用两步有氧过程进行纯化。通过首先在有氧步骤中还原这些硫化合物，可以将去除硫化物的方法用于处理具有高含量硫化合物如硫酸盐，亚硫酸盐和硫代硫酸盐的废水。通过向水中加入硫化物并将金属沉淀为硫化物，从水中除去重金属; 可以通过还原已经存在的硫化合物来加入硫化物。

8. 发明申请

WO1993015024A1 REACTOR FOR THE BIOLOGICAL TREATMENT OF WASTE WATER 审中-公开
标题翻译：废水生物处理反应器
公开(公告)号：WO1993015024A1
公开(公告)日：1993-08-05
申请号：PCT/NL1993000018
申请日：1993-01-19
申请人： PAQUES B.V. , VELLINGA, Sjoerd, Hubertus, Jozef
发明人： PAQUES B.V.
IPC分类号： C02F03/06
CPC分类号： C02F3/2806 , C02F3/02 , C02F3/06 , Y02W10/15
摘要： A reactor for the biological treatment of waste water comprises a reactor vessel (1) intended to receive support material. Biomass is able to adhere to this material. The reactor vessel has an inlet (2) for the water to be treated and an outlet (3) for treated water. A number of module tanks (4) adjoining one another, over which said support material can be distributed, are placed in the reactor vessel. These module tanks can individually be inserted in and removed from the reactor.
摘要翻译：用于生物处理废水的反应器包括用于接收支撑材料的反应器容器（1）。生物质能够坚持这种材料。反应器容器具有用于待处理水的入口（2）和用于处理水的出口（3）。将多个相互邻接的模块箱（4）放置在反应器容器中，所述支撑材料可以分配在该模块箱上。这些模块罐可以分别插入反应器和从反应器中取出。

9. 发明申请

WO1996032177A1 SETTLING DEVICE FOR A FLUID CONTAINING LIQUID, GAS AND PARTICULATE MATERIAL, AS WELL AS A CLEANING DEVICE PROVIDED HEREWITH AND A METHOD FOR CLEANING WASTE WATER 审中-公开
标题翻译：含有液体，气体和颗粒材料的流体装置，作为提供给您的清洁装置和清洁废水的方法
公开(公告)号：WO1996032177A1
公开(公告)日：1996-10-17
申请号：PCT/NL1996000156
申请日：1996-04-10
申请人： PAQUES B.V. , VELLINGA, Sjoerd, Hubertus, Jozef
发明人： PAQUES B.V.
IPC分类号： B01D21/00
CPC分类号： C02F3/2886 , B01D19/0042 , B01D21/0039 , B01D21/0045 , B01D21/0069 , B01D21/2433 , B01D21/2444 , B01D21/2494 , C02F3/02 , Y02W10/15
摘要： The present invention relates to a settling device (2) for a fluid containing liquid, gas and particulate material. The device (2) comprises liquid-discharge means (15) fitted close to the water level of the fluid and supply means for supplying the fluid at the bottom of the settling chamber. In the settling chamber one or more caps (12) are disposed with their longitudinal axis at an angle to the water level, such that fluid supplied at the bottom of the settling chamber flows obliquely up, forced along the bottom of the at least one cap. Whilst gas bubbles contained therein collect in the ridge (17) of the at least one cap. The gas collected in the ridge of the at least one cap is trapped by means of gas-discharge means (18) beneath the water level of the fluid. Preferably, use is made of a row containing a multiplicity of caps (12) which are disposed in oblique, overlapping and parallel arrangement. The caps (12) can be fitted at an angle of 60 DEG relative to the water level and preferably have a mutual interval of about 6 cm. The invention further relates to a purifier provided with a settling device of this kind and to a method for the anaerobic purification of waste water using a settling device or purifier according to the invention.
摘要翻译：本发明涉及一种用于含有液体，气体和颗粒材料的流体的沉降装置（2）。装置（2）包括靠近流体水位安装的排液装置（15）和用于在沉降室底部供应流体的供应装置。在沉降室中，一个或多个盖子（12）以其纵向轴线与水平面成一角度设置，使得在沉降室底部供应的流体向上倾斜地流动，沿着至少一个盖子的底部被迫。其中包含的气泡聚集在至少一个盖的隆起（17）中。收集在至少一个盖的脊中的气体通过在流体的水位下方的气体排出装置（18）而被捕获。优选地，使用包含以倾斜，重叠和平行布置的多个盖（12）的行。盖（12）可以相对于水位成60度的角度安装，优选地具有约6cm的相互间隔。本发明还涉及一种具有这种沉降装置的净化器以及使用根据本发明的沉降装置或净化器的废水的厌氧净化方法。

10. 发明申请

WO1998019971A1 APPARATUS FOR THE BIOLOGICAL PURIFICATION OF WASTE WATER 审中-公开
标题翻译：废水生物净化装置
公开(公告)号：WO1998019971A1
公开(公告)日：1998-05-14
申请号：PCT/NL1997000592
申请日：1997-10-29
申请人： PAQUES B.V. , HABETS, Leonard, Hubertus, Alphonsus , ENGELAAR, Antonius, Johannes, Hendrikus, Hyacinthus , VELLINGA, Sjoerd, Hubertus, Jozef
发明人： PAQUES B.V.
IPC分类号： C02F03/30
CPC分类号： C02F3/2846 , C02F1/24 , C02F3/12 , C02F3/20 , C02F3/30 , C02F3/301 , Y02E50/343 , Y02W10/15
摘要： For the biological purification of waste water, use is made of a column containing a UASB reactor (1) at the bottom and an aerobic reactor (2) at the top. The two reactors (1; 2) are separated from one another by a partition (12) in which openings are provided to allow the anaerobic effluent through into the aerobic reactor. The partition (12) is situated at some distance above the gas collection means (8) in order to form a buffer space (13) for anaerobic sludge which has flowed through. Preferably, a floatation apparatus (3) is mounted on the aerobic reactor in order to separate biomass from the purified water.
摘要翻译：对于废水的生物净化，使用在底部含有UASB反应器（1）的塔和位于顶部的需氧反应器（2）。两个反应器（1; 2）通过隔板（12）彼此分开，在隔板（12）中提供开口以使厌氧流出物进入需氧反应器。分隔件（12）位于气体收集装置（8）上方一定距离处，以便形成已经流过的厌氧污泥的缓冲空间（13）。优选地，漂浮装置（3）安装在需氧反应器上以便将生物质与净化水分离。

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