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    • 1. 发明申请
    • PROCESS FOR PRODUCING TONER FOR DEVELOPING ELECTROSTATICALLY CHARGED IMAGES
    • 用于生产用于开发静电荷图像的调色剂的方法
    • WO1997001131A1
    • 1997-01-09
    • PCT/JP1996001714
    • 1996-06-20
    • NIPPON ZEON CO., LTD.HASEGAWA, JunSAKAI, JunWATANABE, MakotoYAMADA, FumioOGAWA, Tokudai
    • NIPPON ZEON CO., LTD.
    • G03G09/093
    • G03G9/0806G03G9/09314G03G9/09335G03G9/09357G03G9/09378G03G9/09392
    • A process for producing a toner for developing electrostatically charged images which comprises suspension-polymerizing a monomer composition at least comprising a polymerizable monomer and a colorant in an aqueous dispersion medium containing a dispersant to form colored polymer particles, characterized by comprising the following two steps: (1) the first step of forming colored polymer particles as the core component by suspension-polymerizing a monomer composition for the core component comprising at least one core-forming monomer giving a polymer having a glass transition temperature of 80 DEG C or below and a colorant in an aqueous dispersion medium until the conversion of the monomer into polymer reaches 80 % or above, and (2) the second step of forming a polymer layer as the shell on the surface of each colored polymer particle as the core component by adding at least one shell-forming monomer giving a polymer having a glass transition temperature higher than that of the polymer forming the core or a shell-forming monomer composition containing such a monomer and a water-soluble radical polymerization initiator to the reaction system containing the colored polymer particles as the core component and subjecting the obtained mixture to polymerization, and thereby producing encapsulated colored polymer particles having a core-shell structure comprising 40 to 99 wt% of the core component and 1 to 60 wt% of the shell component. The toner thus produced has a low fixing temperature, a good transparency of the images formed on an OHP film, and an excellent shelf stability.
    • 一种生产用于显影静电荷图像的调色剂的方法,其包括在含有分散剂的水性分散介质中使至少包含可聚合单体和着色剂的单体组合物悬浮聚合以形成着色聚合物颗粒,其特征在于包括以下两个步骤: (1)通过悬浮聚合用于芯组分的单体组合物形成着色聚合物颗粒作为核心组分的第一步骤,该单体组合物包含至少一种产生玻璃化转变温度为80℃或更低的聚合物的成核单体和 在水分散介质中着色剂直到单体转化为聚合物达到80%以上,(2)第二步,通过加入到作为核成分的每个着色聚合物颗粒的表面上形成作为壳的聚合物层 至少一种成型单体得到玻璃化转变温度高于聚合物的聚合物 在含有着色聚合物粒子作为核心成分的反应体系中形成含有这样的单体和水溶性自由基聚合引发剂的成核单体组合物,使得到的混合物进行聚合,由此制造包封的着色聚合物粒子 其具有包含核组分的40至99重量%和壳组分的1至60重量%的核 - 壳结构。 由此制得的调色剂具有低的定影温度,在OHP膜上形成的图像的良好的透明度,以及优异的储存稳定性。
    • 3. 发明申请
    • PROCESS FOR PRODUCING POLYMERIC TONER
    • 制备聚合物的方法
    • WO1998025186A1
    • 1998-06-11
    • PCT/JP1997004476
    • 1997-12-05
    • NIPPON ZEON CO., LTD.OTA, NobuyasuHASEGAWA, Jun
    • NIPPON ZEON CO., LTD.
    • G03G09/093
    • G03G9/09392
    • A process for producing a polymeric toner having a core/shell structure, which comprises: passing a core-forming polymerizable monomer composition comprising at least a core-forming polymerizable monomer and a colorant through a space between a rotor rotating at a high speed and a stator surrounding the rotor and having small openings or comb teeth in an aqueous dispersion medium containing a dispersion stabilizer to thereby form droplets of the composition; polymerizing the droplets to obtain core particles; and then polymerizing in the presence of the core particles a shell-forming polymerizable monomer capable of forming a polymer having a higher glass transition temperature than the polymer constituting the core particles to thereby form shells which are polymer layers with which the core particles are covered; a polymeric toner obtained by the process; a method of image forming using the toner; and an image-forming apparatus containing the toner.
    • 一种制备具有核/壳结构的聚合物调色剂的方法,其包括:通过高速旋转的转子和转速高的转子之间的空间使包含至少芯形成可聚合单体和着色剂的芯形成可聚合单体组合物通过 定子围绕转子并且在含有分散稳定剂的水性分散介质中具有小的开口或梳齿,从而形成组合物的液滴; 聚合液滴以获得核心颗粒; 然后在核心颗粒存在下聚合成能形成玻璃化转变温度高于构成核心颗粒的聚合物的聚合物的成壳聚合性单体,从而形成作为核颗粒被覆盖的聚合物层的壳体; 通过该方法获得的聚合物调色剂; 使用调色剂的成像方法; 以及含有调色剂的图像形成装置。
    • 7. 发明申请
    • IMAGE FORMING APPARATUS AND IMAGE FORMING METHOD
    • 图像形成装置和图像形成方法
    • WO1998006012A1
    • 1998-02-12
    • PCT/JP1997002734
    • 1997-08-06
    • NIPPON ZEON CO., LTD.MAKUTA, YoshihiroIMAI, Toyoko
    • NIPPON ZEON CO., LTD.
    • G03G15/08
    • G03G21/0064G03G5/043G03G9/0827
    • A toner image is formed on an electrophotograph photosensitive body by a developing means in which toner powder is stored. The toner image is transferred onto a transfer material and the image is outputted. The toner powder which remains on the electrophotograph photosensitive body after the transfer is recovered by the developing means which also functions as a cleaning means. The material of the surface of the electrophotograph photosensitive body is positive-chargeable organic photosensitive material which contains a phthalocyanine compound as a charge generating agent, a diphenoquinone compound as an electron transporting agent and a nitrogen-containing polyaromatic cyclic compound as a positive hole transporting agent. The toner powder has a sphericity which is calculated by dividing the area (Sc) of a circle whose diameter is the absolutely maximum length of the particles by the actual projection area (Sr) of the particles, within a range of 1.0-1.3 and is colored polymer particles produced by a suspension polymerization method.
    • 通过存储调色剂粉末的显影装置在电子照相感光体上形成调色剂图像。 将调色剂图像转印到转印材料上,并输出图像。 在转印之后保留在电子照相感光体上的调色剂粉末由也用作清洁装置的显影装置回收。 电子照相感光体的表面的材料是含有作为电荷发生剂的酞菁化合物,作为电子传输剂的二苯醌化合物和作为空穴传输剂的含氮多芳族环状化合物的正电荷性有机感光材料 。 调色剂粉末具有球形度,其通过将直径为粒子的绝对最大长度的圆的面积(Sc)除以粒子的实际投影面积(Sr)在1.0-1.3的范围内,并且为 通过悬浮聚合法制备的着色聚合物颗粒。