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1. 发明申请

WO2007082118A3 HYDROCARBON-SOLUBLE MOLYBDENUM CATALYST PRECURSORS AND METHODS OF MAKING SAME 审中-公开
标题翻译：烃可溶性钼催化剂前体及其制备方法
公开(公告)号：WO2007082118A3
公开(公告)日：2007-11-22
申请号：PCT/US2007060049
申请日：2007-01-03
申请人： HEADWATERS TECH INNOVATION LLC , WU ZHIHUA , ZHOU ZHENHUA , ZHOU BING
发明人： WU ZHIHUA , ZHOU ZHENHUA , ZHOU BING
IPC分类号： C10G47/26
CPC分类号： C10G47/06 , B01J27/051 , B01J31/04 , B01J31/2226 , B01J2531/64 , B82Y30/00 , C01B3/0021 , C10G47/26 , C10G2300/4037 , C10G2300/70 , Y02E60/325 , Y10S420/90 , Y10S977/70 , Y10S977/84
摘要： Hydrocarbon-soluble molybdenum catalyst precursors include a plurality of molybdenum cations that are each bonded with a plurality of organic anions to form an oil soluble molybdenum salt. A portion of the molybdenum atoms are in the 3+ oxidation state such that the plurality of molybdenum atoms has an average oxidation state of less than 4+, e.g., less than about 3.8+, especially less than about 3.5+. The catalyst precursors can form a hydroprocessing molybdenum sulfide catalyst in heavy oil feedstocks. The oil soluble molybdenum salts are manufactured in the presence of a reducing agent, such as hydrogen gas, to obtain the molybdenum in the desired oxidation state. Preferably the reaction is performed with hydrogen or an organic reducing agent and at a temperature such that the molybdenum atoms are reduced to eliminate substantially all molybdenum oxide species.
摘要翻译：可溶于烃的钼催化剂前体包括多个钼阳离子，其各自与多种有机阴离子键合以形成油溶性钼盐。一部分钼原子处于3+氧化态，使得多个钼原子具有小于4+，例如小于约3.8+，特别是小于约3.5+的平均氧化态。催化剂前体可在重油原料中形成加氢处理硫化钼催化剂。在还原剂例如氢气的存在下制造油溶性钼盐以获得处于期望氧化态的钼。优选地，反应用氢或有机还原剂进行，并且在使得钼原子被还原以基本上消除所有氧化钼物质的温度下进行。

2. 发明申请

WO2006078352A3 REFORMING NANOCATALYSTS AND METHOD OF MAKING AND USING SUCH CATALYSTS 审中-公开
标题翻译：重新制备纳米催化剂及其制备和使用这种催化剂的方法
公开(公告)号：WO2006078352A3
公开(公告)日：2007-10-25
申请号：PCT/US2005042841
申请日：2005-11-28
申请人： HEADWATERS TECH INNOVATION LLC , ZHOU BING , TREVINO HORACIO , WU ZHIHUA , ZHOU ZHENHUA , LIU CHANGKUN
发明人： ZHOU BING , TREVINO HORACIO , WU ZHIHUA , ZHOU ZHENHUA , LIU CHANGKUN
IPC分类号： C10G35/06
CPC分类号： C10G35/09 , B01J23/40 , B01J23/42 , B01J23/468 , B01J23/56 , B01J23/626 , B01J23/6567 , B01J23/8906 , B01J35/0013 , B01J35/006 , B01J37/0203 , B01J37/08 , B01J37/16 , B01J37/18 , B82Y30/00 , C10G35/085
摘要： Reforming nanocatalysts are formed using a dispersing agent to increase the activity, selectivity and longevity of the catalyst when used in a reforming process. The nanocatalyst particles are formed using a dispersing agent having at least one functional group selected from the group of a hydroxyl, a carboxyl, a carbonyl, an amide, an amine, a thiol, a sulfonic acid, sulfonyl halide, an acyl halide, an organometallic complex, and combinations of these. The dispersing agent is particularly useful for forming multicomponent catalysts comprising an alloy, combination, mixture, decoration, or interspersion of platinum and one or more of tin, rhenium or iridium. The formation of the nanoparticles may include a heat treating process performed in an inert or oxidative environment to maintain the catalyst atoms in a non-zero oxidation state to thereby maintain a stronger bond between the dispersing agent and the catalyst atoms. Multicomponent reforming catalysts having anchored nanocatalyst particles exhibit particularly good activity, selectivity and longevity when used in the reforming of naphtha and/or formation of BTX.
摘要翻译：使用分散剂形成纳米催化剂的重整，以提高催化剂在重整过程中的活性，选择性和使用寿命。纳米催化剂颗粒使用具有至少一个选自羟基，羧基，羰基，酰胺，胺，硫醇，磺酸，磺酰卤，酰基卤，有机金属络合物，以及它们的组合。分散剂特别可用于形成包含铂和锡，铼或铱中的一种或多种的合金，组合，混合物，装饰或间隙的多组分催化剂。纳米颗粒的形成可以包括在惰性或氧化环境中进行的热处理工艺，以保持催化剂原子处于非零氧化态，从而在分散剂和催化剂原子之间保持更强的键。具有锚定的纳米催化剂颗粒的多组分重整催化剂在用于石脑油重整和/或形成BTX时表现出特别好的活性，选择性和寿命。

3. 发明申请

WO2008127742A3 METHODS FOR MANUFACTURING SUPPORTED CATALYST FROM A POROUS SUPPORT AND A NANOCATALYST SOLUTION 审中-公开
标题翻译：用多孔支架和纳米催化剂溶液制造负载型催化剂的方法
公开(公告)号：WO2008127742A3
公开(公告)日：2008-12-04
申请号：PCT/US2008050016
申请日：2008-01-02
申请人： HEADWATERS TECH INNOVATION LLC , ZHOU ZHENHUA , WU ZHIHUA , ZHOU BING
发明人： ZHOU ZHENHUA , WU ZHIHUA , ZHOU BING
IPC分类号： B01J31/00
CPC分类号： C01B15/029 , B01J21/08 , B01J23/44 , B01J35/0013 , B01J35/023 , B01J37/0207 , B01J37/0211 , B01J37/0213 , B01J37/10 , B01J37/18
摘要： Supported catalysts are manufactured from a pretreated porous support material and a nanocatalyst solution of catalyst nanoparticles. The porous support material is pre-treated with a gaseous solvent (e.g., steam or alcohol) to protect the support material from cracking during impregnation of the nanocatalyst solution. The supported catalysts have more uniform size, lower attrition of metals during manufacturing and use, and improved distributions of metal loading compared to catalysts manufactured using known techniques. Hydrogen peroxide manufactured from such catalysts is less likely to be contaminated with catalyst metal.
摘要翻译：负载型催化剂由预处理的多孔载体材料和催化剂纳米颗粒的纳米催化剂溶液制造。用气态溶剂（例如蒸汽或醇）预处理多孔载体材料以保护载体材料在浸渍纳米催化剂溶液期间不开裂。与使用已知技术制造的催化剂相比，负载型催化剂具有更均匀的尺寸，在制造和使用期间较低的金属磨损以及改善的金属负载分布。由这种催化剂制造的过氧化氢不太可能被催化剂金属污染。

4. 发明申请

WO2008100753A3 SUPPOTED NANOCATALYST PARTICLES MANUFACTURED BY HEATING COMPLEXED CATALYST ATOMS 审中-公开
标题翻译：通过加热复合催化剂制备制备的纳米级纳米颗粒
公开(公告)号：WO2008100753A3
公开(公告)日：2008-10-23
申请号：PCT/US2008053171
申请日：2008-02-06
申请人： HEADWATERS TECH INNOVATION LLC , WU ZHIHUA , ZHOU ZHENHUA , RUETER MICHAEL , ZHOU BING
发明人： WU ZHIHUA , ZHOU ZHENHUA , RUETER MICHAEL , ZHOU BING
IPC分类号： B01J31/00 , A62D3/38
CPC分类号： C01B15/029 , B01J23/44 , B01J35/0013 , Y10S977/775
摘要： Methods for manufacturing supported catalysts and the use of these catalysts in, e.g., the direct synthesis of hydrogen peroxide. The nanocatalyst particles are manufactured from catalyst atoms complexed with organic agent molecules (e.g., polyacrylic acid). The complexed catalyst atoms are heated to cause formation of the nanocatalyst particles. The temperature used to cause formation of the particles is typically greater than 30°C, preferably greater than 50°C, and more preferably greater than 70°C.
摘要翻译：用于制造负载型催化剂的方法以及这些催化剂在例如直接合成过氧化氢中的用途。纳米催化剂颗粒由与有机试剂分子（例如聚丙烯酸）络合的催化剂原子制备。络合的催化剂原子被加热以引起纳米催化剂颗粒的形成。用于引起颗粒形成的温度通常大于30℃，优选大于50℃，更优选大于70℃。

5. 发明申请

WO2008048693A3 MAGNESIUM HYDROXIDE NANOPARTICLES, METHODS OF MAKING SAME AND COMPOSITIONS INCORPORATING SAME 审中-公开
标题翻译：氢氧化镁纳米粒子，其制备方法和合成它们的组合物
公开(公告)号：WO2008048693A3
公开(公告)日：2008-11-06
申请号：PCT/US2007060045
申请日：2007-01-03
申请人： HEADWATERS TECH INNOVATION LLC , ZHOU ZHENHUA , WU ZHIHUA , ZHOU BING
发明人： ZHOU ZHENHUA , WU ZHIHUA , ZHOU BING
IPC分类号： C09K21/00
CPC分类号： C09K21/02
摘要： Magnesium hydroxide nanoparticles are made from a magnesium compound that is reacted with an organic dispersing agent (e.g., a hydroxy acid) to form an intermediate magnesium compound. Magnesium hydroxide nanoparticles are formed from hydrolysis of the intermediate compound. The bonding between the organic dispersing agent and the magnesium during hydrolysis influences the size of the magnesium hydroxide nanoparticles formed therefrom. The magnesium hydroxide nanoparticles can be treated with an aliphatic compound (e.g., a monofunctional alcohol) to prevent aggregation of the nanoparticles during drying and/or to make the nanoparticles hydrophobic such that they can be evenly dispersed in a polymeric material. The magnesium hydroxide nanoparticles exhibit superior fire retarding properties in polymeric materials compared to known magnesium hydroxide particles.
摘要翻译：氢氧化镁纳米颗粒由与有机分散剂（例如羟基酸）反应形成中间体镁化合物的镁化合物制成。通过中间体化合物的水解形成氢氧化镁纳米颗粒。水解期间有机分散剂与镁之间的结合影响由其形成的氢氧化镁纳米粒子的尺寸。可以用脂族化合物（例如单官能醇）处理氢氧化镁纳米颗粒，以防止干燥期间纳米颗粒的聚集和/或使纳米颗粒疏水，使得它们可以均匀地分散在聚合物材料中。与已知的氢氧化镁颗粒相比，氢氧化镁纳米颗粒在聚合物材料中表现出优异的阻燃性能。

6. 发明申请

WO2007082117A3 HYDROCARBON-SOLUBLE, BIMETALLIC CATALYST PRECURSORS AND METHODS FOR MAKING SAME 审中-公开
标题翻译：碳氢化合物，双金属催化剂前体及其制备方法
公开(公告)号：WO2007082117A3
公开(公告)日：2008-01-17
申请号：PCT/US2007060047
申请日：2007-01-03
申请人： HEADWATERS TECH INNOVATION LLC , ZHOU BING , ZHOU ZHENHUA , WU ZHIHUA
发明人： ZHOU BING , ZHOU ZHENHUA , WU ZHIHUA
IPC分类号： B01J31/00
CPC分类号： C10G47/26 , B01J23/28 , B01J23/34 , B01J23/881 , B01J23/882 , B01J23/883 , B01J27/0515 , B01J27/1853 , B01J31/04 , B01J31/128 , B01J31/2226 , B01J35/12 , B01J2531/64 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C10G47/06 , C10G2300/1033 , C10G2300/107 , C10G2300/1077 , C10G2300/206
摘要： Bimetallic catalyst precursors are manufactured from a plurality of molybdenum atoms and a plurality of atoms of a secondary transition metal (e.g., one or more of cobalt, iron, or nickel). The molybdenum atoms and the secondary transition metal atoms are each bonded with a plurality of organic anions (e.g., 2-ethyl hexanoate) to form a mixture of an oil-soluble molybdenum salt and an oil-soluble secondary transition metal salt. The molybdenum and/or the secondary transition metals are preferably reacted with the organic agent in the presence of a strong reducing agent such as hydrogen. To obtain this mixture of metal salts, an organic agent is reacted with the molybdenum at a temperature between about 1000C and about 3500C. The secondary transition metal is reacted with the organic agent at a different temperature, preferably between 500C and 2000C. The metal salts are capable of forming a hydroprocessing metal sulfide catalyst in heavy oil feedstocks.
摘要翻译：双金属催化剂前体由多个钼原子和多个二次过渡金属原子（例如钴，铁或镍中的一种或多种）制成。钼原子和二次过渡金属原子各自与多个有机阴离子（例如2-乙基己酸酯）键合，形成油溶性钼盐和油溶二次过渡金属盐的混合物。钼和/或二次过渡金属优选在强还原剂如氢气存在下与有机试剂反应。为了获得这种金属盐的混合物，有机试剂在约1000℃至约350℃的温度下与钼反应。二次过渡金属与有机试剂在不同的温度下反应，优选在500℃-200℃之间。金属盐能够在重油原料中形成加氢处理金属硫化物催化剂。

7. 发明申请

WO2007137028A2 REFORMING NANOCATALYSTS AND METHODS OF MAKING AND USING SUCH CATALYSTS 审中-公开
标题翻译：改造纳米结构和制备和使用这种催化剂的方法
公开(公告)号：WO2007137028A2
公开(公告)日：2007-11-29
申请号：PCT/US2007068928
申请日：2007-05-15
申请人： HEADWATERS TECH INNOVATION LLC , TREVINO HORACIO , ZHOU ZHENHUA , WU ZHIHUA , ZHOU BING
发明人： TREVINO HORACIO , ZHOU ZHENHUA , WU ZHIHUA , ZHOU BING
IPC分类号： A23L3/34
CPC分类号： B01J23/40 , B01J21/04 , B01J23/468 , B01J23/56 , B01J23/626 , B01J23/6567 , B01J31/0201 , B01J31/0215 , B01J31/0217 , B01J31/0225 , B01J31/0229 , B01J31/0235 , B01J31/0237 , B01J31/0247 , B01J31/04 , B01J31/068 , B01J35/0013 , B01J35/002 , B01J35/006 , B01J37/0203 , B01J37/0211 , B01J37/08 , C10G35/09 , C10G35/095
摘要： Catalysts suitable for use in reforming hydrocarbons have a halogen promoter and a plurality of dispersed nanocatalyst particles supported on a solid support. The dispersed nanocatalyst particles are manufactured using a dispersing agent to control 5 the size and/or crystal face exposure of the particles. The controlled size and dispersion of the nanocatalyst particles allows the reforming catalyst to be loaded with significantly less halogen promoter while still maintaining or increasing the catalyst's reforming performance. The catalysts of the present invention have shown improved C5+ production with the significantly reduced levels of halogen promoter.
摘要翻译：适用于重整烃的催化剂具有卤素促进剂和负载在固体载体上的多个分散的纳米催化剂颗粒。使用分散剂制造分散的纳米催化剂颗粒以控制颗粒的尺寸和/或晶面暴露5。纳米催化剂颗粒的受控尺寸和分散体允许重整催化剂负载显着更少的卤素促进剂，同时仍保持或提高催化剂的重整性能。本发明的催化剂已经显示改进的C5 +产生与显着降低的卤素启动子水平。

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