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1. 发明申请

WO2006078352A2 REFORMING NANOCATALYSTS AND METHOD OF MAKING AND USING SUCH CATALYSTS 审中-公开
标题翻译：重新制备纳米催化剂及其制备和使用这种催化剂的方法
公开(公告)号：WO2006078352A2
公开(公告)日：2006-07-27
申请号：PCT/US2005/042841
申请日：2005-11-28
申请人： HEADWATERS NANOKINETIX, INC. , ZHOU, Bing , TREVINO, Horacio , WU, Zhihua , ZHOU, Zhenhua , LIU, Changkun
发明人： ZHOU, Bing , TREVINO, Horacio , WU, Zhihua , ZHOU, Zhenhua , LIU, Changkun
IPC分类号： C10G35/09 , B01J31/00
CPC分类号： C10G35/09 , B01J23/40 , B01J23/42 , B01J23/468 , B01J23/56 , B01J23/626 , B01J23/6567 , B01J23/8906 , B01J35/0013 , B01J35/006 , B01J37/0203 , B01J37/08 , B01J37/16 , B01J37/18 , B82Y30/00 , C10G35/085
摘要： Reforming nanocatalysts are formed using a dispersing agent to increase the activity, selectivity and longevity of the catalyst when used in a reforming process. The nanocatalyst particles are formed using a dispersing agent having at least one functional group selected from the group of a hydroxyl, a carboxyl, a carbonyl, an amide, an amine, a thiol, a sulfonic acid, sulfonyl halide, an acyl halide, an organometallic complex, and combinations of these. The dispersing agent is particularly useful for forming multicomponent catalysts comprising an alloy, combination, mixture, decoration, or interspersion of platinum and one or more of tin, rhenium or iridium. The formation of the nanoparticles may include a heat treating process performed in an inert or oxidative environment to maintain the catalyst atoms in a non-zero oxidation state to thereby maintain a stronger bond between the dispersing agent and the catalyst atoms. Multicomponent reforming catalysts having anchored nanocatalyst particles exhibit particularly good activity, selectivity and longevity when used in the reforming of naphtha and/or formation of BTX.
摘要翻译：使用分散剂形成纳米催化剂的重整，以提高催化剂在重整过程中的活性，选择性和使用寿命。纳米催化剂颗粒使用具有至少一个选自羟基，羧基，羰基，酰胺，胺，硫醇，磺酸，磺酰卤，酰基卤，有机金属络合物，以及它们的组合。分散剂特别可用于形成包含铂和锡，铼或铱中的一种或多种的合金，组合，混合物，装饰或间隙的多组分催化剂。纳米颗粒的形成可以包括在惰性或氧化环境中进行的热处理工艺，以保持催化剂原子处于非零氧化态，从而在分散剂和催化剂原子之间保持更强的键。具有锚定的纳米催化剂颗粒的多组分重整催化剂在用于石脑油重整和/或形成BTX时表现出特别好的活性，选择性和寿命。

2. 发明申请

WO2007137028A3 REFORMING NANOCATALYSTS AND METHODS OF MAKING AND USING SUCH CATALYSTS 审中-公开
公开(公告)号：WO2007137028A3
公开(公告)日：2007-11-29
申请号：PCT/US2007/068928
申请日：2007-05-15
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , TREVINO, Horacio , ZHOU, Zhenhua , WU, Zhihua , ZHOU, Bing
发明人： TREVINO, Horacio , ZHOU, Zhenhua , WU, Zhihua , ZHOU, Bing
IPC分类号： C10G35/09
摘要： Catalysts suitable for use in reforming hydrocarbons have a halogen promoter and a plurality of dispersed nanocatalyst particles supported on a solid support. The dispersed nanocatalyst particles are manufactured using a dispersing agent to control 5 the size and/or crystal face exposure of the particles. The controlled size and dispersion of the nanocatalyst particles allows the reforming catalyst to be loaded with significantly less halogen promoter while still maintaining or increasing the catalyst's reforming performance. The catalysts of the present invention have shown improved C5+ production with the significantly reduced levels of halogen promoter.

3. 发明申请

WO2007082118A2 HYDROCARBON-SOLUBLE MOLYBDENUM CATALYST PRECURSORS AND METHODS OF MAKING SAME 审中-公开
标题翻译：碳氢化合物钼酸盐催化剂前体及其制备方法
公开(公告)号：WO2007082118A2
公开(公告)日：2007-07-19
申请号：PCT/US2007/060049
申请日：2007-01-03
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , WU, Zhihua , ZHOU, Zhenhua , ZHOU, Bing
发明人： WU, Zhihua , ZHOU, Zhenhua , ZHOU, Bing
IPC分类号： B01J31/00 , H01B3/22 , C10G47/00
CPC分类号： C10G47/06 , B01J27/051 , B01J31/04 , B01J31/2226 , B01J2531/64 , B82Y30/00 , C01B3/0021 , C10G47/26 , C10G2300/4037 , C10G2300/70 , Y02E60/325 , Y10S420/90 , Y10S977/70 , Y10S977/84
摘要： Hydrocarbon-soluble molybdenum catalyst precursors include a plurality of molybdenum cations that are each bonded with a plurality of organic anions to form an oil soluble molybdenum salt. A portion of the molybdenum atoms are in the 3+ oxidation state such that the plurality of molybdenum atoms has an average oxidation state of less than 4+, e.g., less than about 3.8+, especially less than about 3.5+. The catalyst precursors can form a hydroprocessing molybdenum sulfide catalyst in heavy oil feedstocks. The oil soluble molybdenum salts are manufactured in the presence of a reducing agent, such as hydrogen gas, to obtain the molybdenum in the desired oxidation state. Preferably the reaction is performed with hydrogen or an organic reducing agent and at a temperature such that the molybdenum atoms are reduced to eliminate substantially all molybdenum oxide species.
摘要翻译：烃可溶性钼催化剂前体包括多个钼阳离子，其各自与多个有机阴离子键合以形成油溶性钼盐。一部分钼原子处于3+氧化态，使得多个钼原子具有小于4+，例如小于约3.8+，特别是小于约3.5+的平均氧化态。催化剂前体可以在重油原料中形成加氢处理钼硫化物催化剂。油溶性钼盐在还原剂如氢气存在下制备，得到所需氧化态的钼。优选地，反应用氢或有机还原剂进行，并且在使得钼原子被还原以消除基本上所有氧化钼物质的温度下进行。

4. 发明申请

WO2008008979A1 FISCHER-TROPSCH CATALYSTS INCORPORATING PROMOTER FOR INCREASING YIELDS OF C5+ HYDROCARBONS AND METHODS FOR MAKING AND USING SAME 审中-公开
标题翻译：用于增加C5 +碳氢化合物的增压剂催化剂及其制备和使用方法的FISCHER-TROPSCH催化剂
公开(公告)号：WO2008008979A1
公开(公告)日：2008-01-17
申请号：PCT/US2007/073500
申请日：2007-07-13
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , LU, Yijun , WU, Zhihua , ZHOU, Zhenhua , ZHOU, Bing
发明人： LU, Yijun , WU, Zhihua , ZHOU, Zhenhua , ZHOU, Bing
IPC分类号： C07C27/00 , B01J23/32 , B01J23/40 , B01J23/72
CPC分类号： B01J25/00 , B01J23/745 , B01J23/78 , B01J23/8892 , B01J35/023 , B01J37/0201 , C10G2/33 , C10G2/331 , C10G2/332
摘要： An improved skeletal iron catalyst is provided for use in Fischer-Tropsch synthesis reactions for converting CO and H 2 to hydrocarbon products. The skeletal iron catalyst is manufactured using iron and a removable non-ferrous component such as aluminum. The iron and removable non-ferrous component are mixed together to form a precursor catalyst and then a portion of the removable non-ferrous component is removed to leave a skeletal iron catalyst. One or more first promoter metals and optionally one or more second promoter metals are incorporated into the skeletal iron catalyst either by blending the promoter into the precursor catalyst during the formation thereof or by depositing the promoter on the skeletal iron. The first promoter metals comprises a metal selected from the group consisting of titanium, zirconium, vanadium, cobalt, molybdenum, tungsten, and platinum-group metals. The first promoter metal is selected to improve the yield of C 5+ hydrocarbons when the skeletal iron catalyst is used in a Fischer-Tropsch reaction.
摘要翻译：提供改进的骨架铁催化剂用于费 - 托合成反应，用于将CO和H 2 CO 2转化为烃产物。骨架铁催化剂使用铁和可移除的有色金属组分如铝制造。将铁和可除去的有色金属组分混合在一起形成前体催化剂，然后除去一部分可除去的有色金属组分以留下骨架铁催化剂。一种或多种第一促进剂金属和任选的一种或多种第二助催化剂金属通过将助催化剂在其形成过程中掺入前体催化剂中或者通过将促进剂沉积在骨架铁上而引入骨架铁催化剂中。第一助催化剂金属包括选自钛，锆，钒，钴，钼，钨和铂族金属的金属。当骨架铁催化剂用于费 - 托反应时，选择第一助催化剂金属以提高C 5+烃的产率。

5. 发明申请

WO2007082117A2 HYDROCARBON-SOLUBLE, BIMETALLIC CATALYST PRECURSORS AND METHODS FOR MAKING SAME 审中-公开
标题翻译：碳氢化合物，双金属催化剂前体及其制备方法
公开(公告)号：WO2007082117A2
公开(公告)日：2007-07-19
申请号：PCT/US2007/060047
申请日：2007-01-03
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , ZHOU, Bing , ZHOU, Zhenhua , WU, Zhihua
发明人： ZHOU, Bing , ZHOU, Zhenhua , WU, Zhihua
IPC分类号： C10L1/04 , B01J31/00
CPC分类号： C10G47/26 , B01J23/28 , B01J23/34 , B01J23/881 , B01J23/882 , B01J23/883 , B01J27/0515 , B01J27/1853 , B01J31/04 , B01J31/128 , B01J31/2226 , B01J35/12 , B01J2531/64 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C10G47/06 , C10G2300/1033 , C10G2300/107 , C10G2300/1077 , C10G2300/206
摘要： Bimetallic catalyst precursors are manufactured from a plurality of molybdenum atoms and a plurality of atoms of a secondary transition metal (e.g., one or more of cobalt, iron, or nickel). The molybdenum atoms and the secondary transition metal atoms are each bonded with a plurality of organic anions (e.g., 2-ethyl hexanoate) to form a mixture of an oil-soluble molybdenum salt and an oil-soluble secondary transition metal salt. The molybdenum and/or the secondary transition metals are preferably reacted with the organic agent in the presence of a strong reducing agent such as hydrogen. To obtain this mixture of metal salts, an organic agent is reacted with the molybdenum at a temperature between about 1000C and about 3500C. The secondary transition metal is reacted with the organic agent at a different temperature, preferably between 500C and 2000C. The metal salts are capable of forming a hydroprocessing metal sulfide catalyst in heavy oil feedstocks.
摘要翻译：双金属催化剂前体由多个钼原子和多个二次过渡金属原子（例如钴，铁或镍中的一种或多种）制成。钼原子和二次过渡金属原子各自与多个有机阴离子（例如2-乙基己酸酯）键合，形成油溶性钼盐和油溶二次过渡金属盐的混合物。钼和/或二次过渡金属优选在强还原剂如氢气存在下与有机试剂反应。为了获得这种金属盐的混合物，有机试剂在约1000℃至约350℃的温度下与钼反应。二次过渡金属与有机试剂在不同的温度下反应，优选在500℃-200℃之间。金属盐能够在重油原料中形成加氢处理金属硫化物催化剂。

6. 发明申请

WO2008042670A1 METHODS FOR MANUFACTURING BI-METALLIC CATALYSTS HAVING A CONTROLLED CRYSTAL FACE EXPOSURE 审中-公开
标题翻译：用于制造具有受控晶体面暴露的双金属催化剂的方法
公开(公告)号：WO2008042670A1
公开(公告)日：2008-04-10
申请号：PCT/US2007/079555
申请日：2007-09-26
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , ZHOU, Zhenhua , WU, Zhihua , ZHANG, Cheng , ZHOU, Bing
发明人： ZHOU, Zhenhua , WU, Zhihua , ZHANG, Cheng , ZHOU, Bing
IPC分类号： B01J23/02
CPC分类号： C01B15/029 , B01J23/44 , B01J35/0013 , B01J37/0203 , B01J37/0211 , B01J37/18
摘要： Improved bi-metallic nanocatalysts are manufactured using a control agent to produce nanoparticles having a controlled crystal face exposure. The bi-metallic nanocatalyst particles are manufactured in a two-step process. In a first step, nanocatalyst particles are manufactured using the control agent and the primary metal atoms. The primary metal atoms and the control agent are reacted to form complexed metal atoms. The complexed metal atoms are then allowed or caused to form nanoparticles. The nanoparticles formed in the first step using the control agent have a desired crystal face exposure. In a second step, the secondary metal atoms are deposited on the surface of the primary metal nanoparticles. The secondary catalyst atoms maintain the same crystal face exposure as the primary metal nanoparticles.
摘要翻译：使用控制剂制备改进的双金属纳米催化剂以产生具有受控晶面曝光的纳米颗粒。双金属纳米催化剂颗粒以两步法制备。在第一步中，使用控制剂和主要金属原子制造纳米催化剂颗粒。使主要金属原子和控制剂反应形成络合的金属原子。然后允许或引起络合的金属原子形成纳米颗粒。使用控制剂在第一步中形成的纳米颗粒具有所需的晶面曝光。在第二步中，二次金属原子沉积在一次金属纳米粒子的表面上。二次催化剂原子保持与主要金属纳米颗粒相同的晶面暴露。

7. 发明申请

WO2008100753A2 SUPPOTED NANOCATALYST PARTICLES MANUFACTURED BY HEATING COMPLEXED CATALYST ATOMS 审中-公开
标题翻译：通过加热复合催化剂制备制备的纳米级纳米颗粒
公开(公告)号：WO2008100753A2
公开(公告)日：2008-08-21
申请号：PCT/US2008/053171
申请日：2008-02-06
申请人： HEADWATERS TECHNOLOGY INNOVATION, LLC , WU, Zhihua , ZHOU, Zhenhua , RUETER, Michael , ZHOU, Bing
发明人： WU, Zhihua , ZHOU, Zhenhua , RUETER, Michael , ZHOU, Bing
IPC分类号： B01J31/02 , B01J31/06 , C01B15/029
CPC分类号： C01B15/029 , B01J23/44 , B01J35/0013 , Y10S977/775
摘要： Methods for manufacturing supported catalysts and the use of these catalysts in, e.g., the direct synthesis of hydrogen peroxide. The nanocatalyst particles are manufactured from catalyst atoms complexed with organic agent molecules (e.g., polyacrylic acid). The complexed catalyst atoms are heated to cause formation of the nanocatalyst particles. The temperature used to cause formation of the particles is typically greater than 30 °C, preferably greater than 50 °C, and more preferably greater than 70 °C.
摘要翻译：用于制造负载型催化剂的方法以及这些催化剂在例如直接合成过氧化氢中的用途。纳米催化剂颗粒由与有机试剂分子（例如聚丙烯酸）络合的催化剂原子制备。络合的催化剂原子被加热以引起纳米催化剂颗粒的形成。用于引起颗粒形成的温度通常大于30℃，优选大于50℃，更优选大于70℃。

8. 发明申请

WO2008048693A2 MAGNESIUM HYDROXIDE NANOPARTICLES, METHODS OF MAKING SAME AND COMPOSITIONS INCORPORATING SAME 审中-公开
标题翻译：氢氧化镁纳米颗粒及其制备方法和包含该组合物的组合物
公开(公告)号：WO2008048693A2
公开(公告)日：2008-04-24
申请号：PCT/US2007/060045
申请日：2007-01-03
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , ZHOU, Zhenhua , WU, Zhihua , ZHOU, Bing
发明人： ZHOU, Zhenhua , WU, Zhihua , ZHOU, Bing
IPC分类号： C09K21/00
CPC分类号： C09K21/02
摘要： Magnesium hydroxide nanoparticles are made from a magnesium compound that is reacted with an organic dispersing agent (e.g., a hydroxy acid) to form an intermediate magnesium compound. Magnesium hydroxide nanoparticles are formed from hydrolysis of the intermediate compound. The bonding between the organic dispersing agent and the magnesium during hydrolysis influences the size of the magnesium hydroxide nanoparticles formed therefrom. The magnesium hydroxide nanoparticles can be treated with an aliphatic compound (e.g., a monofunctional alcohol) to prevent aggregation of the nanoparticles during drying and/or to make the nanoparticles hydrophobic such that they can be evenly dispersed in a polymeric material. The magnesium hydroxide nanoparticles exhibit superior fire retarding properties in polymeric materials compared to known magnesium hydroxide particles.
摘要翻译：氢氧化镁纳米颗粒由与有机分散剂（例如羟基酸）反应形成中间体镁化合物的镁化合物制成。氢氧化镁纳米颗粒由中间体化合物的水解形成。水解过程中有机分散剂与镁之间的键合影响由其形成的氢氧化镁纳米粒子的尺寸。氢氧化镁纳米颗粒可以用脂族化合物（例如单官能醇）处理以防止纳米颗粒在干燥过程中聚集和/或使纳米颗粒疏水，使得它们可以均匀分散在聚合物材料中。与已知的氢氧化镁颗粒相比，氢氧化镁纳米颗粒在聚合材料中表现出优异的阻燃性能。

9. 发明申请

WO2008127742A2 METHODS FOR MANUFACTURING SUPPORTED CATALYST FROM A POROUS SUPPORT AND A NANOCATALYST SOLUTION 审中-公开
标题翻译：从多孔支持和纳米级解决方案制造支持的催化剂的方法
公开(公告)号：WO2008127742A2
公开(公告)日：2008-10-23
申请号：PCT/US2008/050016
申请日：2008-01-02
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , ZHOU, Zhenhua , WU, Zhihua , ZHOU, Bing
发明人： ZHOU, Zhenhua , WU, Zhihua , ZHOU, Bing
IPC分类号： C01B15/029 , B01J21/10 , B01J21/04 , B01J21/06 , B01J21/08 , B01J21/12 , B01J21/16 , B01J29/06 , B01J31/06 , B01J31/02
CPC分类号： C01B15/029 , B01J21/08 , B01J23/44 , B01J35/0013 , B01J35/023 , B01J37/0207 , B01J37/0211 , B01J37/0213 , B01J37/10 , B01J37/18
摘要： Supported catalysts are manufactured from a pretreated porous support material and a nanocatalyst solution of catalyst nanoparticles. The porous support material is pre-treated with a gaseous solvent (e.g., steam or alcohol) to protect the support material from cracking during impregnation of the nanocatalyst solution. The supported catalysts have more uniform size, lower attrition of metals during manufacturing and use, and improved distributions of metal loading compared to catalysts manufactured using known techniques. Hydrogen peroxide manufactured from such catalysts is less likely to be contaminated with catalyst metal.
摘要翻译：负载催化剂由预处理的多孔载体材料和催化剂纳米颗粒的纳米催化剂溶液制成。多孔支撑材料用气态溶剂（例如蒸汽或醇）进行预处理，以保护支撑材料在浸渍纳米催化剂溶液期间不会开裂。负载催化剂在制造和使用过程中具有更均匀的尺寸，更低的金属磨损，以及与使用已知技术制造的催化剂相比，金属负载的分布改善。由这种催化剂制造的过氧化氢不太可能被催化剂金属污染。

10. 发明申请

WO2006112993A1 COMPLEXED NANOCATALYSTS, FUEL COMPOSITIONS INCORPORATING SUCH CATALYSTS, AND METHODS MAKING AND USING SUCH NANOCATALYSTS AND COMPOSITIONS 审中-公开
标题翻译：复合纳米催化剂，含有这些催化剂的燃料组合物，以及制备和使用这种纳米催化剂和组合物的方法
公开(公告)号：WO2006112993A1
公开(公告)日：2006-10-26
申请号：PCT/US2006/009387
申请日：2006-03-16
申请人： HEADWATERS NANOKINETIX, INC. , BING, Zhou , PARASHER, Sukesh , RUETER, Michael , WU, Zhihua , HARE, Jeffrey , HARDING, N., Stanley , BLACK, Stephanie, E. , JOHNSON, Kenneth, R.
发明人： BING, Zhou , PARASHER, Sukesh , RUETER, Michael , WU, Zhihua , HARE, Jeffrey , HARDING, N., Stanley , BLACK, Stephanie, E. , JOHNSON, Kenneth, R.
IPC分类号： B01D53/56 , B01D53/86 , B01J8/00 , B01J23/00 , B01J23/32 , B01J23/02 , B01J23/06
CPC分类号： A24B15/28 , A24B15/286 , A24B15/288 , B01D53/8625
摘要： Organically complexed nanocatalyst compositions are applied to or mixed with a carbon-containing fuel ( e.g. , coal, briquetted charcoal, tobacco, biomass, or a liquid hydrocarbon like fuel oils or gasoline) in order to enhance combustion properties of the fuel. The nanocatalyst compositions include nanocatalyst particles made using a dispersing agent. They can be formed as a stable suspension to facilitate storage, transportation and application of the catalyst nanoparticles to a fuel substrate. Nanocatalyst compositions can be applied to or mixed with a solid fuel substrate in order to reduce the amount of CO, hydrocarbons and soot produced by the fuel during combustion, hi addition, a nanocatalyst composition can be applied to or mixed with coal prior to or upon introducing the coal into a coal burner in order to catalyze the removal of coal nitrogen from the coal and its conversion into nitrogen gas prior to combustion of the coal. This leads to reduced NOx production during coal combustion.
摘要翻译：将有机络合的纳米催化剂组合物施用于含碳燃料（例如，煤，压块炭，烟草，生物质或液体烃如燃料油或汽油）或与其混合，以增强燃料的燃烧性能。纳米催化剂组合物包括使用分散剂制备的纳米催化剂颗粒。它们可以形成为稳定的悬浮液，以便于将催化剂纳米颗粒储存，运输和应用于燃料基质。纳米催化剂组合物可以施加到固体燃料基质上或与固体燃料基质混合，以减少在燃烧过程中由燃料产生的CO，烃和烟炱的量。此外，纳米催化剂组合物可以在或之前施加到煤上或与之混合将煤引入煤燃烧器，以便在煤燃烧之前催化从煤中除去煤氮并转化成氮气。这导致煤燃烧期间的NOx产生减少。

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