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    • 5. 发明申请
    • AMMONIUM HALIDE AS GELATION RETARDER FOR CROSSLINKABLE POLYMER COMPOSITIONS
    • 氨基甲酸酯作为可交联聚合物组合物的凝胶阻滞剂
    • WO2011107744A1
    • 2011-09-09
    • PCT/GB2011/000297
    • 2011-03-03
    • HALLIBURTON ENERGY SERVICES, INCSIERRA, LeopoldoAL-MUNTASHERI, Ghaithan, A.BAKHTIRAYOV, AlbertTURNER, Craig, RobertSAUDI ARABIAN OIL COMPANY
    • SIERRA, LeopoldoAL-MUNTASHERI, Ghaithan, A.BAKHTIRAYOV, Albert
    • C09K8/508C09K8/512C09K8/88
    • E21B33/138C09K8/5083C09K8/512C09K8/882C09K8/887
    • According to one embodiment, a treatment fluid for a well includes: (a) a water- soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non- acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker capable of crosslinking the water-soluble polymer; (c) an ammonium halide; and (d) water. According to another embodiment, a method for blocking the permeability of a portion of a subterranean formation penetrated by a wellbore is provided, the method including the steps of: (a) selecting the portion of the subterranean formation to be treated, wherein the bottomhole temperature of the portion of the subterranean formation is equal to or greater than 250 °F (121 °C); (b) selecting estimated treatment conditions, wherein the estimated treatment conditions comprise temperature over a treatment time; (c) forming a treatment fluid that is a crosslinkable polymer composition comprising: (i) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (ii) an organic crosslinker capable of crosslinking the water- soluble polymer; (iii) an ammonium halide; and (iv) water; (d) selecting the water-soluble polymer, the crosslinker, the ammonium halide, and the water, and the proportions thereof, such that the gelation time of the treatment fluid is at least 2 hours when tested under the estimated treatment conditions; and (e) injecting the treatment fluid through the wellbore into the portion of the subterranean formation.
    • 根据一个实施方案,用于井的处理流体包括:(a)水溶性聚合物,其中所述水溶性聚合物包含至少一种非酸性烯属不饱和极性单体的聚合物; (b)能够交联水溶性聚合物的有机交联剂; (c)卤化铵; 和(d)水。 根据另一个实施例,提供了一种用于阻挡由井筒穿透的地下地层的一部分渗透性的方法,所述方法包括以下步骤:(a)选择待处理的地层的部分,其中井底温度 的地层的部分等于或大于250°F(121℃); (b)选择估计的治疗条件,其中估计的治疗条件包括治疗时间以上的温度; (c)形成作为可交联聚合物组合物的处理流体,其包含:(i)水溶性聚合物,其中所述水溶性聚合物包含至少一种非酸性烯属不饱和极性单体的聚合物; (ii)能够交联水溶性聚合物的有机交联剂; (iii)卤化铵; 和(iv)水; (d)选择水溶性聚合物,交联剂,卤化铵和水及其比例,使得在估计的处理条件下进行试验时,处理流体的凝胶化时间至少为2小时; 和(e)将处理流体通过井筒注入到地层的部分中。