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    • 7. 发明申请
    • SALT OF WEAK BRONSTED BASE AND BRONSTED ACID AS GELATION RETARDER FOR CROSSLINKABLE POLYMER COMPOSITIONS
    • 弱碱性碱和琥珀酸作为可交联聚合物组合物的凝胶阻滞剂
    • WO2011107743A1
    • 2011-09-09
    • PCT/GB2011/000296
    • 2011-03-03
    • HALLIBURTON ENERGY SERVICES INCREDDY, Bairreddy, RaghavaEOFF, Larry, StevenVASQUEZ, Julio, EstuardoDALRYMPLE, Eldon, DwyannTURNER, Craig, Robert
    • REDDY, Bairreddy, RaghavaEOFF, Larry, StevenVASQUEZ, Julio, EstuardoDALRYMPLE, Eldon, Dwyann
    • C09K8/508C09K8/512C09K8/88
    • C09K8/5083C09K8/512C09K8/882C09K8/887
    • According to one embodiment, a treatment fluid for a well includes: (a) a water- soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non- acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a salt of a weak Bronsted base and a Bronsted acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition. According to another embodiment, a method for blocking the permeability of a portion of a subterranean formation penetrated by a wellbore is provided, the method including the steps of: (a) selecting the portion of the subterranean formation to be treated; (b) selecting estimated treatment conditions, wherein the estimated treatment conditions comprise temperature over a treatment time; (c) forming a treatment fluid that is a crosslinkable polymer composition comprising: (i) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (ii) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (iii) a salt of a weak Bronsted base and a Bronsted acid; and (iv) water; (d) selecting the water-soluble polymer, the crosslinker, the salt of a weak Bronsted base and a Bronsted acid, and the water, and the proportions thereof, such that the gelation time of the treatment fluid is at least 1 hour when tested under the estimated treatment conditions; and (e) injecting the treatment fluid through the wellbore into the portion of the subterranean formation.
    • 根据一个实施方案,用于井的处理流体包括:(a)水溶性聚合物,其中所述水溶性聚合物包含至少一种非酸性烯属不饱和极性单体的聚合物; (b)包含胺基的有机交联剂,其中所述有机交联剂能够交联所述水溶性聚合物; (c)弱布朗斯台德碱和布朗斯台德酸的盐; 和(d)水; 其中所述处理流体是可交联聚合物组合物。 根据另一个实施例,提供了一种用于阻挡由井眼穿透的地下地层的一部分渗透性的方法,所述方法包括以下步骤:(a)选择待处理的地层的部分; (b)选择估计的治疗条件,其中估计的治疗条件包括治疗时间以上的温度; (c)形成作为可交联聚合物组合物的处理流体,其包含:(i)水溶性聚合物,其中所述水溶性聚合物包含至少一种非酸性烯属不饱和极性单体的聚合物; (ii)包含胺基的有机交联剂,其中所述有机交联剂能够交联所述水溶性聚合物; (iii)弱布朗斯台德碱和布朗斯台德酸的盐; 和(iv)水; (d)选择水溶性聚合物,交联剂,弱布朗斯台德碱和布朗斯台德酸的盐以及水及其比例,使得当测试时处理液的凝胶化时间为至少1小时 在估计治疗条件下; 和(e)将处理流体通过井眼注入到地层的部分中。
    • 8. 发明申请
    • WEAK ORGANIC ACID AS GELATION RETARDER FOR CROSSLINKABLE POLYMER COMPOSITIONS
    • 弱有机酸作为可交联聚合物组合物的凝胶阻滞剂
    • WO2011107735A1
    • 2011-09-09
    • PCT/GB2011/000282
    • 2011-03-02
    • HALLIBURTON ENERGY SERVICES, INC.REDDY, Bairreddy RaghavaEOFF, Larry StevenVASQUEZ, Julio EstuardoDARLYMPLE, Eldon DwyannTURNER, Craig Robert
    • REDDY, Bairreddy RaghavaEOFF, Larry StevenVASQUEZ, Julio EstuardoDARLYMPLE, Eldon Dwyann
    • C09K8/508C09K8/512
    • C09K8/5083C09K8/512C09K8/882C09K8/887
    • According to one embodiment, a treatment fluid for a well includes: (a) a water- soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non- acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a weak organic acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition. According to another embodiment, a method for blocking the permeability of a portion of a subterranean formation penetrated by a wellbore is provided, the method including the steps of: (a) selecting the portion of the subterranean formation to be treated; (b) selecting estimated treatment conditions, wherein the estimated treatment conditions comprise temperature over a treatment time; (c) forming a treatment fluid that is a crosslinkable polymer composition comprising: (i) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (ii) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (iii) a weak organic acid; and (iv) water; (d) selecting the water-soluble polymer, the crosslinker, the weak organic acid, and the water, and the proportions thereof, such that the gelation time of the treatment fluid is at least 1 hour when tested under the estimated treatment conditions; and (e) injecting the treatment fluid through the wellbore into the portion of the subterranean formation.
    • 根据一个实施方案,用于井的处理流体包括:(a)水溶性聚合物,其中所述水溶性聚合物包含至少一种非酸性烯属不饱和极性单体的聚合物; (b)包含胺基的有机交联剂,其中所述有机交联剂能够交联所述水溶性聚合物; (c)弱有机酸; 和(d)水; 其中所述处理流体是可交联聚合物组合物。 根据另一个实施例,提供了一种用于阻挡由井筒穿透的地下地层的一部分的渗透性的方法,所述方法包括以下步骤:(a)选择待处理的地层的部分; (b)选择估计的治疗条件,其中估计的治疗条件包括治疗时间以上的温度; (c)形成作为可交联聚合物组合物的处理流体,其包含:(i)水溶性聚合物,其中所述水溶性聚合物包含至少一种非酸性烯属不饱和极性单体的聚合物; (ii)包含胺基的有机交联剂,其中所述有机交联剂能够交联所述水溶性聚合物; (iii)弱有机酸; 和(iv)水; (d)选择水溶性聚合物,交联剂,弱有机酸和水及其比例,使得在估计的处理条件下进行试验时,处理液的凝胶化时间至少为1小时; 和(e)将处理流体通过井眼注入到地层的部分中。