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    • 7. 发明申请
    • EMISSIVE POLYMERIC MATERIALS FOR OPTOELECTRONIC DEVICES
    • 用于光电器件的EMISSIVE聚合材料
    • WO2009079039A1
    • 2009-06-25
    • PCT/US2008/073627
    • 2008-08-20
    • GENERAL ELECTRIC COMPANYCHICHAK, Kelly, ScottCELLA, James, AnthonySHIANG, Joseph, JohnLEWIS, Larry, Neil
    • CHICHAK, Kelly, ScottCELLA, James, AnthonySHIANG, Joseph, JohnLEWIS, Larry, Neil
    • C09K11/06H05B33/14C07F15/00H01L51/00
    • C09K11/06C07F15/004C09K2211/1416C09K2211/1425C09K2211/1433C09K2211/1466C09K2211/185H01L51/0035H01L51/0039H01L51/5012H05B33/14
    • Polymers including at least one structural unit derived from a compound of Formula (I) or including at least one pendant group of Formula (II) may be used in optoelectronic devices, wherein R 1 , R 3 , R 4 and R 6 are independently hydrogen, alkyl, alkoxy, oxaalkyl, alkylaryl, aryl, arylalkyl, heteroaryl, substituted alkyl; substituted alkoxy, substituted oxaalkyl, substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted heteroaryl; R 1a is hydrogen or alkyl; R 2 is alkylene, substituted alkylene, oxaalkylene, CO, or CO 2 ; R 2a is alkylene; R 5 is independently at each occurrence hydrogen, alkyl, alkylaryl, aryl, arylalkyl, alkoxy, carboxy, substituted alkyl; substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted alkoxy, X is halo, triflate, -B(OR 1a ) 2 , or Formula (III) located at the 2, 5- or 2, 7- positions; and L is derived from phenylpyridine, tolylpyridine, benzothienylpyridine, phenylisoquinoline, dibenzoquinozaline, fluorenylpyridine, ketopyrrole, 2-(1-naphthyl)benzoxazole)), 2-phenylbenzoxazole, 2-phenylbenzothiazole, coumarin, thienylpyridine, phenylpyridine, benzothienylpyridine, 3-methoxy-2-phenylpyridine, thienylpyridine, phenylimine, vinylpyridine, pyridylnaphthalene, pyridylpyrrole, pyridylimidazole, phenylindole, derivatives thereof or combinations thereof.
    • 包括衍生自式(I)化合物或至少包含式(II)的至少一个侧基的至少一个结构单元的聚合物可以用于光电子器件中,其中R 1,R 3,R 4和R 6独立地为氢,烷基,烷氧基 烷基芳基,芳基,芳基烷基,杂芳基,取代的烷基; 取代的烷氧基,取代的氧杂烷基,取代的烷基芳基,取代的芳基,取代的芳基烷基或取代的杂芳基; R1a是氢或烷基; R2是亚烷基,取代的亚烷基,氧杂亚烷基,CO或CO 2; R2a是亚烷基; R5各自独立地为氢,烷基,烷基芳基,芳基,芳基烷基,烷氧基,羧基,取代的烷基; 取代的烷基芳基,取代的芳基,取代的芳烷基或取代的烷氧基,X是卤素,三氟甲磺酸酯,-B(OR1a)2或位于2,5-或2,7-位的式(III) 苯基吡啶,苯并噻吩并吡啶,二苯并喹嗪,芴基吡啶,酮咯吡咯,2-(1-萘基)苯并恶唑)),2-苯基苯并恶唑,2-苯基苯并噻唑,香豆素,噻吩基吡啶,苯基吡啶,苯并噻吩基吡啶,3-甲氧基 - 2-苯基吡啶,噻吩基吡啶,苯亚胺,乙烯基吡啶,吡啶基萘,吡啶基吡咯,吡啶基咪唑,苯基吲哚,其衍生物或其组合。