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1. 发明申请

WO2005063622A2 CHABAZITE-TYPE MOLECULAR SIEVE, ITS SYNTHESIS AND ITS USE IN THE CONVERSION OF OXYGENATES TO OLEFINS 审中-公开
标题翻译： CHABAZITE型分子筛，其合成及其在氧气转化为烯烃中的用途
公开(公告)号：WO2005063622A2
公开(公告)日：2005-07-14
申请号：PCT/US2004042737
申请日：2004-12-20
申请人： EXXONMOBIL CHEM PATENTS INC , MERTENS MACHTELD M , CAO GUANG , LI HAILIAN , GURAM ANIL S , SAXTON ROBERT J , MURAOKA MARK T , YODER JEFFREY C
发明人： MERTENS MACHTELD M , CAO GUANG , LI HAILIAN , GURAM ANIL S , SAXTON ROBERT J , MURAOKA MARK T , YODER JEFFREY C
IPC分类号： B01J29/00 , B01J29/70 , C01B37/02 , C01B39/00 , C01B39/02 , C01B39/04 , C01B39/48 , C07C1/00 , C07C1/20
CPC分类号： B01J29/7015 , C01B37/02 , C01B39/48 , C07C1/20 , Y02P20/52 , Y02P30/42 , Y10S423/30 , C07C11/06 , C07C11/04 , C07C11/02
摘要： The synthesis of a crystalline material, in particular a high silica zeolite, having a chabazite-type framework is aided by the addition to the synthesis mixture of seeds of an AEI framework-type material. The chabazite-type product has a relatively small crystal size and exhibits activity and selectivity in the conversion of methanol to lower olefins, especially ethylene and propylene.
摘要翻译：通过添加到AEI骨架型材料的种子的合成混合物来辅助具有菱沸石型骨架的结晶材料，特别是高二氧化硅沸石的合成。菱沸石型产品具有相对较小的晶体尺寸，并且在甲醇转化成低级烯烃，特别是乙烯和丙烯时具有活性和选择性。

2. 发明申请

WO2005063623A3 CHABAZITE-CONTAINING MOLECULAR SIEVE, ITS SYNTHESIS AND ITS USE IN THE CONVERSION OF OXYGENATES TO OLEFINS 审中-公开
标题翻译：含有CHABAZITE的分子筛，其合成及其在氧气转化为烯烃中的用途
公开(公告)号：WO2005063623A3
公开(公告)日：2006-07-20
申请号：PCT/US2004042739
申请日：2004-12-20
申请人： EXXONMOBIL CHEM PATENTS INC , CAO GUANG , MERTENS MACHTELD M , STROHMAIER KARL G , HALL RICHARD B , COLLE THOMAS H , AFEWORKI MOBAE , BONS ANTONIE JAN , MORTIER WILFRIED J , KLIEWER CHRIS , LI HAILIAN , GURAM ANIL S , SAXTON ROBERT J , MURAOKA MARK T , YODER JEFFREY C
发明人： CAO GUANG , MERTENS MACHTELD M , STROHMAIER KARL G , HALL RICHARD B , COLLE THOMAS H , AFEWORKI MOBAE , BONS ANTONIE JAN , MORTIER WILFRIED J , KLIEWER CHRIS , LI HAILIAN , GURAM ANIL S , SAXTON ROBERT J , MURAOKA MARK T , YODER JEFFREY C
IPC分类号： C01B39/02 , C01B37/02 , C01B39/46 , C01B39/48 , C07C1/20 , C10G3/00
CPC分类号： C01B39/46 , C01B37/02 , C01B39/023 , C01B39/48 , C10G3/45 , C10G3/49 , C10G3/62 , C10G2300/708 , C10G2300/802 , C10G2400/20 , Y02P30/20 , Y02P30/42
摘要： A crystalline material substantially free of framework phosphorus and comprising a CHA framework type molecular sieve with stacking faults or at least one intergrown phase of a CHA framework type molecular sieve and an AEI framework type molecular sieve, wherein said material, in its calcined, anhydrous form, has a composition involving the molar relationship: (n)X 2 O 3 :YO 2 , wherein X is a trivalent element; Y is a tetravalent element; and n is from 0 to about 0.5. The material exhibits activity and selectivity in the conversion of methanol to lower olefins, especially ethylene and propylene.
摘要翻译：基本上不含骨架磷的结晶物质，其包含具有层叠缺陷的CHA骨架型分子筛或CHA骨架型分子筛和AEI骨架型分子筛的至少一个共生相，其中所述材料以其煅烧无水形式具有摩尔关系的组成：（n）X 2 O 3：YO 2，其中X是三价元素; Y是四价元素; 且n为0至约0.5。该材料在甲醇转化成低级烯烃，特别是乙烯和丙烯时表现出活性和选择性。

3. 发明申请

WO2010011423A8 SYNTHESIS OF CHABAZITE-CONTAINING MOLECULAR SIEVES AND THEIR USE IN THE CONVERSION OF OXYGENATES TO OLEFINS 审中-公开
标题翻译：含氧化铵分子筛的合成及其在氧气转化为烯烃中的用途
公开(公告)号：WO2010011423A8
公开(公告)日：2010-10-21
申请号：PCT/US2009046172
申请日：2009-06-03
申请人： EXXONMOBIL CHEM PATENTS INC , MERTENS MACHTELD M , CAO GUANG
发明人： MERTENS MACHTELD M , CAO GUANG
IPC分类号： B01J29/04 , C01B37/08 , C07C17/20
CPC分类号： B01J29/85 , B01J35/023 , B01J37/0009 , B01J2229/42 , C01B37/08 , C01B39/54 , C07C1/20 , C07C2529/70 , Y02P30/42 , C07C11/02
摘要： In a method of synthesizing a mostly CHA-type silicoaluminophosphate sieve, a reaction mixture comprises sources of water, silicon, aluminum, phosphorus, and a template. In one aspect, when the reaction mixture Si/A12 ratio is less than 0.33, crystallization is induced at at least 165°C. Advantageously, the sieve so crystallized exhibits a Si/A12 ratio less than 0.33 and/or at least 0.10 greater than the synthesis mixture Si/A12 ratio. In another aspect, the aluminum and phosphorus sources are first combined to form a primary mixture that is aged. The silicon source and template can then be added to form the synthesis mixture. After inducing crystallization, in this aspect, both the synthesis mixture and crystallized sieve exhibit a Si/A12 ratio less than 0.33 and/or the crystallized sieve has an average crystal size not more than 3.0µm. The molecular sieve from both aspects can be used in a hydrocarbon (oxygenates-to-olefins) conversion process.
摘要翻译：在合成大多数CHA型硅铝磷酸盐筛的方法中，反应混合物包含水，硅，铝，磷和模板的来源。一方面，当反应混合物Si / A12比小于0.33时，在至少165℃下诱导结晶。有利地，如此结晶的筛子表现出比合成混合物Si / A12比低小于0.33和/或至少0.10的Si / A12比。另一方面，首先将铝和磷源组合以形成老化的初级混合物。然后可以加入硅源和模板以形成合成混合物。诱导结晶后，在这一方面，合成混合物和结晶化筛均显示小于0.33的Si / A12比例和/或结晶筛的平均晶体尺寸不大于3.0μm。来自两个方面的分子筛可用于烃（含氧化合物 - 烯烃）转化过程。

4. 发明申请

WO2010011423A3 SYNTHESIS OF CHABAZITE-CONTAINING MOLECULAR SIEVES AND THEIR USE IN THE CONVERSION OF OXYGENATES TO OLEFINS 审中-公开
标题翻译：含有柴胡的分子筛的合成及其在氧化物转化为烯烃中的应用
公开(公告)号：WO2010011423A3
公开(公告)日：2010-07-22
申请号：PCT/US2009046172
申请日：2009-06-03
申请人： EXXONMOBIL CHEM PATENTS INC , MERTENS MACHTELD M , CAO GUANG
发明人： MERTENS MACHTELD M , CAO GUANG
IPC分类号： B01J29/04 , C01B37/08 , C07C17/20
CPC分类号： B01J29/85 , B01J35/023 , B01J37/0009 , B01J2229/42 , C01B37/08 , C01B39/54 , C07C1/20 , C07C2529/70 , Y02P30/42 , C07C11/02
摘要： In a method of synthesizing a mostly CHA-type silicoaluminophosphate sieve, a reaction mixture comprises sources of water, silicon, aluminum, phosphorus, and a template. In one aspect, when the reaction mixture Si/Al2 ratio is less than 0.33, crystallization is induced at at least 165°C. Advantageously, the sieve so crystallized exhibits a Si/Al2 ratio less than 0.33 and/or at least 0.10 greater than the synthesis mixture SiMl2 ratio. In another aspect, the aluminum and phosphorus sources are first combined to form a primary mixture that is aged. The silicon source and template can then be added to form the synthesis mixture. After inducing crystallization, in this aspect, both the synthesis mixture and crystallized sieve exhibit a Si/Al2 ratio less than 0.33 and/or the crystallized sieve has an average crystal size not more than 3.0µm. The molecular sieve from both aspects can be used in a hydrocarbon (oxygenates-to-olefins) conversion process.
摘要翻译：在主要合成CHA型硅铝磷酸盐筛的方法中，反应混合物包含水，硅，铝，磷和模板的来源。在一个方面，当反应混合物Si / Al 2比率小于0.33时，在至少165℃下诱导结晶。有利的是，如此结晶的筛表现出比合成混合物SiMl 2比率小的0.34和/或至少0.10的Si / Al 2比率。另一方面，首先将铝和磷源合并以形成老化的主要混合物。然后可以加入硅源和模板以形成合成混合物。在引起结晶之后，在这方面，合成混合物和结晶筛均表现出小于0.33的Si / Al 2比和/或结晶筛的平均结晶尺寸不超过3.0μm。来自两个方面的分子筛可用于烃（含氧化合物转化为烯烃）转化过程。

5. 发明申请

WO2009123782A2 SYNTHESIS OF ALUMINOPHOSPHATE AND METALLOALUMINOPHOSPHATE MOLECULAR SIEVES 审中-公开
标题翻译：铝磷酸盐和金属磷酸盐分子筛的合成
公开(公告)号：WO2009123782A2
公开(公告)日：2009-10-08
申请号：PCT/US2009032116
申请日：2009-01-27
申请人： EXXONMOBIL CHEM PATENTS INC , CAO GUANG , AFEWORKI MOBAE , SHAH MATU J , MERTENS MACHTELD M
发明人： CAO GUANG , AFEWORKI MOBAE , SHAH MATU J , MERTENS MACHTELD M
IPC分类号： C01B37/08 , B01J29/85 , C01B39/54 , C07C1/20 , C10G3/00
CPC分类号： C01B37/08 , B01J29/83 , B01J29/85 , C01B37/04 , C01B39/54 , C07C1/20 , Y02P30/20 , Y02P30/42 , Y10S423/30 , C07C11/02
摘要： In a method of synthesizing an aluminophosphate or metalloaluminophosphate molecular sieve, a synthesis mixture is provided comprising water, a source of aluminum, a source of phosphorus, optionally a source of a metal other than aluminum, a tertiary amine, and an alkylating agent capable of reacting with said tertiary amine to form a quaternary ammonium compound capable of directing the synthesis of said molecular sieve. The synthesis mixture is maintained under conditions sufficient to cause the alkylating agent to react with the tertiary amine to produce the quaternary ammonium compound and to induce crystallization of the molecular sieve.
摘要翻译：在合成磷酸铝或金属铝磷酸盐分子筛的方法中，提供了合成混合物，其包含水，铝源，磷源，任选的除铝之外的金属源，叔胺和烷基化剂，其能够与所述叔胺反应形成能够引导所述分子筛合成的季铵化合物。将合成混合物保持在足以使烷基化剂与叔胺反应以产生季铵化合物并诱导分子筛结晶的条件下。

6. 发明申请

WO2011008329A3 CATALYST AND ONCE-THROUGH REACTOR-REGENERATOR PROCESS FOR OXYGENATE TO OLEFINS PRODUCTION 审中-公开
标题翻译：氧化生成烯烃的催化剂和直通式反应器 - 再生器工艺
公开(公告)号：WO2011008329A3
公开(公告)日：2011-03-17
申请号：PCT/US2010034702
申请日：2010-05-13
申请人： EXXONMOBIL CHEM PATENTS INC , CAO GUANG , CAO CHUNSHE , HALL RICHARD B , COLLE THOMAS H
发明人： CAO GUANG , CAO CHUNSHE , HALL RICHARD B , COLLE THOMAS H
IPC分类号： C07C1/20 , B01J29/70 , B01J29/90 , C07C11/02
CPC分类号： B01J29/90 , B01J29/7015 , B01J38/12 , C07C1/20 , C07C2529/70 , C07C2529/85 , Y02P20/584 , Y02P30/42 , C07C11/02
摘要： Disclosed herein is a method of converting oxygenates to olefins comprising contacting an oxygenate stream with an acidic high silica chabazite catalyst in one or more oxygenate-to-olefins reactors; circulating greater than from 80 % of the catalyst to one or more catalyst regenerators to form regenerated catalyst; circulating the regenerated catalyst, preferably the same amount of regenerated catalyst, back to the oxygenate-to-olefins reactor to contact an oxygenate stream; and isolating a stream of olefins from the one or more oxygenate-to-olefins reactors.
摘要翻译：本文公开了将含氧化合物转化成烯烃的方法，其包括使含氧化合物流与酸性高二氧化硅菱沸石催化剂在一个或多个含氧化合物 - 烯烃反应器中接触; 使大于80％的催化剂循环至一个或多个催化剂再生器以形成再生催化剂; 使再生的催化剂，优选等量的再生催化剂循环回到含氧化合物 - 烯烃反应器以接触含氧化合物物流; 和从一个或多个含氧化合物转化为烯烃反应器中分离烯烃流。

7. 发明申请

WO2007145724A8 TREATMENT OF CHA-TYPE MOLECULAR SIEVES AND THEIR USE IN THE CONVERSION OF OXYGENATES TO OLEFINS 审中-公开
标题翻译： CHA型分子筛的处理及其在氧气转化为OLEFINS中的用途
公开(公告)号：WO2007145724A8
公开(公告)日：2009-01-08
申请号：PCT/US2007010746
申请日：2007-05-01
申请人： EXXONMOBIL CHEM PATENTS INC , CAO GUANG , SHAH MATU J
发明人： CAO GUANG , SHAH MATU J
IPC分类号： B01J29/70 , B01J37/10 , C01B39/00 , C07C1/20 , C10G3/00
CPC分类号： C01B39/46 , B01J29/7015 , B01J37/10 , B01J2229/24 , B01J2229/36 , C01B39/026 , C01B39/48 , C07C1/20 , C07C2529/70 , C10G3/49 , C10G3/62 , C10G2300/807 , C10G2400/20 , Y02P30/20 , C07C11/02
摘要： A method is disclosed of treating a crystalline material comprising a CHA framework-type molecular sieve, wherein said crystalline material has a composition and involving the molar relationship: (n)X2O3:YO2, where X is a trivalent element, Y is a tetravalent element, and n is less than 0.07, and wherein the crystalline material does not comprise a silicoaluminophosphate, is substantially free of framework phosphorus, or both. The method can comprise treating the crystalline material with steam under conditions such that the prime olefin selectivity of the treated material in an oxygenate conversion process is greater than the prime olefin selectivity of the untreated material in the same process.
摘要翻译：公开了一种处理包含CHA骨架型分子筛的结晶材料的方法，其中所述结晶材料具有组成并涉及摩尔关系：（n）X 2 O 3：YO 2，其中X是三价元素，Y是四价元素，并且n小于0.07，并且其中所述结晶材料不包含硅铝磷酸盐，基本上不含骨架磷或两者。该方法可以包括在蒸汽条件下处理结晶物质，使得在相同方法中，处理过的材料在含氧化合物转化方法中的主要烯烃选择性大于未处理材料的主要烯烃选择性。

8. 发明申请

WO2009134534A3 TREATMENT OF SMALL PORE MOLECULAR SIEVES AND THEIR USE IN THE CONVERSION OF OXYGENATES TO OLEFINS 审中-公开
标题翻译：小孔分子筛的处理及其在氧气转化成烯烃中的用途
公开(公告)号：WO2009134534A3
公开(公告)日：2010-04-29
申请号：PCT/US2009036520
申请日：2009-03-09
申请人： EXXONMOBIL CHEM PATENTS INC , CAO GUANG , KENNEDY GORDON J , SHAH MATU J
发明人： CAO GUANG , KENNEDY GORDON J , SHAH MATU J
IPC分类号： C01B37/02 , C01B39/02
CPC分类号： B01J29/7015 , B01J29/035 , B01J29/06 , B01J2229/24 , B01J2229/37 , C01B37/02 , C01B39/026 , C07C1/20 , C07C2529/70 , C07C11/02
摘要： A method is disclosed of treating a porous crystalline molecular sieve having a pore size less than or equal to about 5 Angstroms to decrease its coke selectivity in oxygenate to olefin conversion reactions. The method comprises contacting the molecular sieve with an acid having a kinetic diameter greater than or equal to that of acetic acid.
摘要翻译：公开了一种处理孔径小于或等于约5埃的多孔结晶分子筛以降低其在含氧化合物与烯烃转化反应中的焦炭选择性的方法。该方法包括使分子筛与动力学直径大于或等于乙酸的酸的酸接触。

9. 发明申请

WO2006037436A3 ALUMINOPHOSPHATE MOLECULAR SIEVE, ITS SYNTHESIS AND USE 审中-公开
标题翻译：铝磷酸盐分子筛，其合成和用途
公开(公告)号：WO2006037436A3
公开(公告)日：2006-09-28
申请号：PCT/EP2005009878
申请日：2005-09-12
申请人： EXXONMOBIL CHEM PATENTS INC , EXXONMOBIL CHEMICAL LTD , CAO GUANG , SHAH MATU J , BRODY JOHN F , DORSET DOUGLAS L , STROHMAIER KARL G
发明人： CAO GUANG , SHAH MATU J , BRODY JOHN F , DORSET DOUGLAS L , STROHMAIER KARL G
IPC分类号： C01B39/00 , B01J27/182
CPC分类号： C07C1/20 , B01J29/83 , B01J29/85 , C01B37/04 , C01B37/08 , C01B39/54 , C10G3/00 , C10G3/49 , C10G2400/20 , C07C11/02
摘要： A large pore (metallo)aluminophosphate molecular sieve is disclosed The material has an X-ray diffraction pattern including the lines listed in Table 4 and is synthesized in the presence of 4-dimethylaminopyridine as structure directing agent.
摘要翻译：公开了一种大孔（金属）铝磷酸盐分子筛。该材料具有包括表4中列出的线的X射线衍射图，并在4-二甲基氨基吡啶作为结构导向剂存在下合成。

10. 发明申请

WO2015084576A3 HYDROCARBON CONVERSION 审中-公开
标题翻译：石油转化
公开(公告)号：WO2015084576A3
公开(公告)日：2015-11-19
申请号：PCT/US2014065961
申请日：2014-11-17
申请人： EXXONMOBIL CHEM PATENTS INC
发明人： KEUSENKOTHEN PAUL F , HENAO JUAN D , PATIL ABHIMANYU O , CAO GUANG
IPC分类号： C07C2/76 , C07C15/00
CPC分类号： C07C2/864 , C07C2/76 , C07C2/865 , C07C2529/06 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/48 , C07C2529/87 , C07C15/00
摘要： This disclosure relates to the conversion of methane to higher molecular weight (C5+) hydrocarbon, including aromatic hydrocarbon, to materials and equipment useful in such conversion, and to the use of such conversion for, e.g., natural gas upgrading. A process for producing aromatic hydrocarbon, the process comprising: (a) providing a feed comprising at least one C2+aliphatic hydrocarbon, at least one Ci+organic oxygenate and at least 9 mole % of methane, the mole percent being based on per mole of feed, wherein the molar ratio of methane to Ci+oxygenate in the feed is in the range of 0.6:1 to 20:1 and the molar ratio of methane to C2+aliphatic hydrocarbon in the feed is in the range of from 0.1:1 1 to 20:1; (b) contacting the feed with a catalyst comprising at least one molecular sieve and at least one dehydrogenation component under conditions, including a temperature
摘要翻译：本公开涉及将甲烷转化为高分子量（C 5+）烃（包括芳族烃）转化为可用于这种转化的材料和设备，以及将这种转化用于例如天然气升级。一种制备芳族烃的方法，该方法包括：（a）提供包含至少一种C 2 +脂族烃，至少一种C 1有机含氧化合物和至少9摩尔％甲烷的进料，其摩尔百分比基于每摩尔的进料，其中进料中甲烷与C 1 +含氧化合物的摩尔比在0.6:1至20:1的范围内，并且进料中甲烷与C 2 +脂族烃的摩尔比在0.1:1〜 1 1〜20：1; （b）在包括至少部分甲烷，C2 +烃和C1 +有机含氧化合物的条件下，包括至少一种分解筛和至少一种脱氢组分的催化剂下接触进料在包含至少5wt。基于产品重量的Cs +烃的％; 和（c）从产物中分离出至少部分的C5 +烃。

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