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1. 发明申请

WO2017102948A1 CATALYST COMPOSITION, ITS PREPARATION AND PROCESS USING SUCH COMPOSITION 审中-公开
标题翻译：催化剂组合物及其制备方法和使用该组合物的方法
公开(公告)号：WO2017102948A1
公开(公告)日：2017-06-22
申请号：PCT/EP2016/081197
申请日：2016-12-15
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL OIL COMPANY
发明人： MAUER, Richard, Berend , LI, Hong-Xin , SABATER PUJADAS, Gisela
IPC分类号： B01J29/22 , B01J29/44 , B01J29/80 , B01J37/00 , C07C5/27 , C07C6/12
CPC分类号： C07C6/126 , B01J29/18 , B01J29/22 , B01J29/40 , B01J29/44 , B01J29/80 , B01J35/023 , B01J37/0009 , B01J2229/20 , B01J2229/42 , C07C4/18 , C07C5/2737 , C07C2529/18 , C07C2529/22 , C07C2529/40 , C07C2529/44 , C07C2529/80 , Y02P20/52 , C07C15/04 , C07C15/08
摘要： Catalyst composition comprising a carrier and one or more Group 10 metal components, wherein the carrier comprises (i) 20 to 90 wt% mordenite having a silica to alumina molar ratio in the range of from 10 to 60; (ii) 10 to 70 wt% ZSM-5 type zeolite having a silica to alumina molar ratio in the range of from 5 to 50 and an average particle size in the range of from 5 to 50 nm; and (iii) 10 to 50 wt% of binder; a process for preparing the catalyst, and a process for the conversion of an aromatic hydrocarbons-containing feedstock using the catalyst.
摘要翻译：包含载体和一种或多种第10族金属组分的催化剂组合物，其中所述载体包含（i）二氧化硅与氧化铝摩尔比为10-60的20-90wt％丝光沸石 ; （ii）10至70重量％的二氧化硅与氧化铝摩尔比为5至50且平均粒度为5至50纳米的ZSM-5型沸石; 和（iii）10至50重量％的粘合剂; 制备催化剂的方法，以及使用该催化剂转化含芳烃的原料的方法。

2. 发明申请

WO2017078891A8 INTEGRATED GAS TURBINE AND CONVERSION SYSTEM PROCESS 审中-公开
公开(公告)号：WO2017078891A8
公开(公告)日：2017-06-01
申请号：PCT/US2016056007
申请日：2016-10-07
申请人： EXXONMOBIL CHEMICAL PATENTS INC
发明人： IACCINO LARRY L , LEMOINE ROMAIN O V
IPC分类号： C07C5/333 , B01J8/06 , B01J8/18 , B01J38/10 , C07C2/50 , C07C13/15
CPC分类号： C07C5/373 , B01J8/062 , C07C5/333 , C07C2529/44 , C07C2601/10 , Y02P20/125 , C07C13/15
摘要： Disclosed is an integrated process and system to generate power and convert acyclic C5 feedstock to non-aromatic, cyclic C5 hydrocarbon. A combustion device, such as a turbine, and reactor tubes containing catalyst compound are disclosed. A process involving contacting acyclic C5 feedstock with catalyst composition and obtaining cyclic C5 hydrocarbon is also disclosed.

3. 发明申请

WO2017078900A1 PROCESS AND SYSTEM FOR MAKING CYCLOPENTADIENE AND/OR DICYCLOPENTADIENE 审中-公开
标题翻译：制备环戊二烯和/或二环戊二烯的方法和体系
公开(公告)号：WO2017078900A1
公开(公告)日：2017-05-11
申请号：PCT/US2016/056030
申请日：2016-10-07
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： IACCINO, Larry, L. , LEUNG, Kevin, C.P.
IPC分类号： C07C2/52 , C07C13/15 , C07C13/61 , B01J29/44
CPC分类号： C07C5/333 , B01J29/44 , B01J2229/186 , C07C2/52 , C07C5/373 , C07C2529/44 , C07C2601/10 , C07C2603/68 , C07C13/15 , C07C13/61
摘要： Processes and systems for making cyclopentadiene and/or dicyclopentadiene include converting acyclic C5 hydrocarbon(s) into CPD in a first reactor to obtain a product mixture, separating the product mixture in a separation sub-system such as compression train to obtain a C5-rich fraction comprising CPD and essentially depleted of hydrogen and C1-C4 hydrocarbons, dimerizing the C5-rich fraction in a dimerization reactor to obtain a product effluent comprising DCPD, followed by separating the product effluent to obtain a DCPD- rich fraction. Multiple-stage of dimerization and separation steps can be optionally used to obtain multiple DCPD-rich fractions of various degrees of purity and quantity. C5-rich fractions from various stages of the process may be recycled to the first reactor, or converted into mogas components after selective hydrogenation. C5-rich fractions and mogas components may be optionally separated to produce value-adding chemicals.
摘要翻译：用于制备环戊二烯和/或二环戊二烯的方法和系统包括在第一反应器中将无环C5烃转化为CPD以获得产物混合物，将产物混合物在分离子系统例如压缩机组以获得包含CPD且基本上耗尽的氢和C 1 -C 4烃的富含C5的馏分，在二聚反应器中将富含C5的馏分二聚化以获得包含DCPD的产物流出物，接着分离产物流出物以获得DCPD - 丰富的分数。可任选地使用多步二聚和分离步骤来获得不同纯度和量的多种富含DCPD的级分。来自该方法的各个阶段的富含C5的馏分可以被循环到第一反应器中，或者在选择性氢化之后被转化成熟料组分。富含C5的馏分和原料成分可以任选分离以生产增值化学品。

4. 发明申请

WO2017078898A2 PROCESS FOR CONVERSION OF ACYCLIC C5 COMPOUNDS TO CYCLIC C5 COMPOUNDS AND CATALYST COMPOSITION FOR USE THEREIN 审中-公开
标题翻译：将无环C5化合物转化成环状C5化合物的方法及其用于其中的催化剂组合物
公开(公告)号：WO2017078898A2
公开(公告)日：2017-05-11
申请号：PCT/US2016/056025
申请日：2016-10-07
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： IACCINO, Larry L. , BEDARD, Jeremy W. , LAI, Wenyih, F. , EVANS, Christopher M. , CHENG, Jane C.
IPC分类号： C07C5/333 , C07C13/15 , C07C9/15 , B01J29/74 , B01J29/88 , C07C2/50
CPC分类号： C07C5/373 , B01J29/46 , B01J29/88 , B01J2229/183 , B01J2229/186 , C07C5/333 , C07C2529/44 , C07C2601/10 , C07C13/15 , C07C13/12
摘要： Disclosed is a process for the conversion of acyclic C 5 feedstock to a product comprising cyclic C 5 compounds, such as for example, cyclopentadiene, and catalyst compositions for use in such process. The process comprising the steps of contacting said feedstock and, optionally, hydrogen under acyclic C 5 conversion conditions in the presence of a catalyst composition to form said product. The catalyst composition comprising a microporous crystalline ferrosilicate, a Group 10 metal, and, optionally, a Group 11 metal, in combination with an optional Group 1 alkali metal and/or an optional Group 2 alkaline earth metal.
摘要翻译：公开了一种将非环状C 5原料转化为包含环状C 5 5化合物的产物的方法，所述化合物例如为环戊二烯，和用于这种方法的催化剂组合物。该方法包括在催化剂组合物存在下在无环C 5转化条件下使所述原料和任选的氢接触以形成所述产物的步骤。该催化剂组合物包含微孔结晶铁硅酸盐，第10族金属和任选的第11族金属，以及任选的1族碱金属和/或任选的2族碱土金属。

5. 发明申请

WO2015197732A1 PROCESS FOR PRODUCING PURIFIED AROMATIC HYDROCARBONS FROM A MIXED HYDROCARBON FEEDSTREAM 审中-公开
标题翻译：从混合油料生产纯化芳香烃的方法
公开(公告)号：WO2015197732A1
公开(公告)日：2015-12-30
申请号：PCT/EP2015/064314
申请日：2015-06-25
申请人： SABIC GLOBAL TECHNOLOGIES B.V.
发明人： SCOTT, Stevenson , DANIËLS, Dimitri
IPC分类号： C10G35/04 , C07C5/32 , C07C15/04 , C10G45/58 , C10G45/68 , C10G65/04 , C10G69/12
CPC分类号： C07C5/417 , C07C2/66 , C07C2529/44 , C07C2529/70 , C10G35/04 , C10G45/58 , C10G45/68 , C10G47/00 , C10G65/046 , C10G69/123 , C10G2400/30 , C07C15/073 , C07C15/085 , C07C15/04
摘要： The present invention relates to a process for producing benzene from a mixed hydrocarbon feedstream comprising subjecting C6 cut separated from said mixed hydrocarbon feedstream to aromatization to provide a benzene-rich aromatic stream and recovering the benzene from the benzene-rich aromatic stream.
摘要翻译：本发明涉及一种从混合烃进料流中生产苯的方法，包括将从所述混合烃进料流中分离出的C6馏分进行芳构化以提供富含苯的芳族物流，并从富含苯的芳香物流中回收苯。

6. 发明申请

WO2015057485A1 A PROCESS FOR THE AROMATIZATION OF ALKANES IN AN ALKANE-CONTAINING GAS STREAM 审中-公开
标题翻译：含碱性气体流中碱的芳构化方法
公开(公告)号：WO2015057485A1
公开(公告)日：2015-04-23
申请号：PCT/US2014/059869
申请日：2014-10-09
申请人： SHELL OIL COMPANY , SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
发明人： TANEV, Peter Tanev , MARSHALL, Larry Lanier , NILEKAR, Anand , GERWIEN, Daniel Edward , MUSALLAM, Waleed Yosef , HAMILTON JR., David Morris , CISNEROS TREVINO, Lizbeth Olivia , LAURITZEN, Ann Marie , GARZA, Juan Mirabel
IPC分类号： C07C2/84 , B01J12/00
CPC分类号： C07C2/76 , C07C2/84 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/48 , C07C2529/65 , C07C2529/66 , C07C2529/68 , C07C2529/69 , C07C2529/70 , C07C2529/74 , C07C2529/76 , C07C2529/78 , C07C15/04
摘要： A process for the aromatization of alkanes in an alkane-containing gas stream comprising: contacting the alkane-containing gas stream in a reactor with a fluidized bed comprising an aromatization catalyst and a hydrogen acceptor under alkane aromatization conditions to produce a product stream comprising aromatics and hydrogen wherein the hydrogen is, at least in part, bound by the hydrogen acceptor in the reaction zone and removed from the product and the reaction zone.
摘要翻译：一种用于含烷烃气流中的烷烃芳构化的方法，其包括：在烷烃芳构化条件下使反应器中的含烷烃气流与包含芳构化催化剂和氢受体的流化床接触以产生包含芳族化合物和其中氢至少部分地由反应区中的氢受体结合并从产物和反应区除去。

7. 发明申请

WO2015009409A2 PROCESS AND CATALYST FOR C9+ AROMATICS CONVERSION 审中-公开
标题翻译： C9 +芳烃转化过程和催化剂
公开(公告)号：WO2015009409A2
公开(公告)日：2015-01-22
申请号：PCT/US2014/043563
申请日：2014-06-23
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： CHENG, Jane C. , OLIVERI, Christopher G.
CPC分类号： C07C4/18 , B01J8/0453 , B01J8/0457 , B01J23/02 , B01J23/14 , B01J23/50 , B01J23/72 , B01J29/44 , B01J37/0201 , B01J38/06 , B01J2208/00522 , B01J2208/025 , B01J2229/36 , C07C6/126 , C07C7/14858 , C07C2529/44 , C07C2529/46 , C07C2529/70 , Y02P20/52 , Y02P20/584 , C07C15/08 , C07C15/02
摘要： The invention is directed to a multimetallic catalyst and its use in a reactor system in a C9+ aromatics conversion process in order to reduce the saturation of aromatic species, reduce the production of C6+ non-aromatics byproducts, and achieve higher benzene purity. The multimetallic catalyst exhibits improved selectivity towards aromatic hydrocarbons in comparison to a traditional Pt/ZSM-5 catalyst and comprises ZSM-5, a Group 6-10 metal, and an additional metal not in Group 6-10. The C9+ aromatics conversion reactor system comprises a top bed containing the multimetallic catalyst for dealkylation of ethyl and propyl side chains, a second bed containing a catalyst comprising a hydrogenation component for trans alkylation, and an optional third bed containing a catalyst without a hydrogenation component to convert non-aromatic hydrocarbons to gas products.
摘要翻译：本发明涉及多金属催化剂及其在C9 +芳烃转化过程的反应器系统中的用途，以降低芳族物质的饱和度，减少C6 +非芳族副产物的产生，以及达到更高的苯纯度。与传统的Pt / ZSM-5催化剂相比，多金属催化剂对芳族烃表现出改善的选择性，并且包含ZSM-5，第6-10族金属和不在第6-10族中的附加金属。 C9 +芳族化合物转化反应器系统包含含有用于乙基和丙基侧链脱烷基化的多金属催化剂的顶床，含有包含用于反式烷基化的氢化组分的催化剂的第二床和含有不含氢化组分的催化剂的将非芳烃转化为气体产品。

8. 发明申请

WO2012078511A2 PROCESS FOR THE CONVERSION OF MIXED LOWER ALKANES TO ARMOATIC HYDROCARBONS 审中-公开
标题翻译：将混合低级烷烃转化为ARMOATIC烃的方法
公开(公告)号：WO2012078511A2
公开(公告)日：2012-06-14
申请号：PCT/US2011/063286
申请日：2011-12-05
申请人： SHELL OIL COMPANY , SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , IYER, Mahesh Venkataraman , LAURITZEN, Ann Marie , MADGAVKAR, Ajay MADHAV , VECCHIO, Nick Joseph
发明人： IYER, Mahesh Venkataraman , LAURITZEN, Ann Marie , MADGAVKAR, Ajay MADHAV , VECCHIO, Nick Joseph
IPC分类号： C07C15/04 , C07C15/00 , C07C15/06 , B01J29/40 , B01J6/00
CPC分类号： C07C2/76 , B01J29/42 , B01J29/44 , B01J29/90 , B01J37/0201 , C07C2521/04 , C07C2529/44 , C10G50/00 , C10G2300/1025 , C10G2300/104 , C10G2400/30 , Y02P20/584 , C07C15/02
摘要： A process comprising: contacting a lower alkane feed comprising propane and ethane with an aromatization catalyst in a first stage under first stage reaction conditions to produce a first stage product stream comprising ethane and aromatics; separating the aromatics from the first stage product stream to form an aromatics product stream and a second stage feed; and contacting the second stage feed with an aromatization catalyst in a second stage under second stage reaction conditions to produce a second stage product stream comprising ethane and aromatics wherein the amount of ethane in the first stage product stream is equal to from 80 to 300% of the amount of ethane in the lower alkane feed and the amount of ethane in the second stage product stream is equal to at most 80% of the amount of ethane in the second stage feed is described.
摘要翻译：一种方法，其包括：在第一阶段反应条件下，在第一阶段使包含丙烷和乙烷的低级烷烃进料与芳构化催化剂接触以产生包含乙烷和芳族化合物的第一阶段产物流; 将芳族化合物与第一阶段产物物流分离以形成芳族化合物产物物流和第二阶段进料; 以及在第二阶段反应条件下在第二阶段使第二阶段进料与芳构化催化剂接触以产生包含乙烷和芳族化合物的第二阶段产物流，其中第一阶段产物流中乙烷的量等于80-300％低级烷烃进料中乙烷的量和第二级产物流中乙烷的量等于至少描述第二级进料中乙烷量的80％。

9. 发明申请

WO2012078506A2 PROCESS FOR THE CONVERSION OF LOWER ALKANES TO AROMATIC HYDROCARBONS AND ETHYLENE 审中-公开
标题翻译：下烷烃转化为芳香烃和乙烯的方法
公开(公告)号：WO2012078506A2
公开(公告)日：2012-06-14
申请号：PCT/US2011/063279
申请日：2011-12-05
申请人： SHELL OIL COMPANY , SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , IYER, Mahesh Venkataraman , LAURITZEN, Ann Marie , MADGAVKAR, Ajay Madhav , VECCHIO, Nick Joseph
发明人： IYER, Mahesh Venkataraman , LAURITZEN, Ann Marie , MADGAVKAR, Ajay Madhav , VECCHIO, Nick Joseph
IPC分类号： C07C5/333 , C07C15/04 , C07C11/04 , B01J29/06 , B01J19/24 , B01J6/00
CPC分类号： B01J29/44 , B01J37/0201 , C07C2/76 , C07C4/02 , C07C2529/44 , Y02P20/52 , C07C15/04 , C07C15/06 , C07C11/04
摘要： A process comprising: contacting a lower alkane feed with an aromatization catalyst in a first stage under first stage reaction conditions to produce a first stage product stream comprising ethane and aromatics; separating the aromatics from the first stage product stream to form an aromatics product stream and a non-aromatics product stream; introducing a first portion of the non-aromatics product stream into an alkane cracker; and contacting a second portion of the non-aromatics product stream with an aromatization catalyst in a second stage under second stage reaction conditions to produce a second stage product stream comprising aromatics is described herein.
摘要翻译：一种方法，包括：在第一阶段反应条件下的第一阶段使低级烷烃进料与芳构化催化剂接触，以产生包含乙烷和芳族化合物的第一级产物流; 将芳族化合物与第一级产物流分离以形成芳族化合物产物流和非芳族化合物产物流; 将非芳族化合物产物流的第一部分引入烷烃裂化器; 以及在第二阶段反应条件下在第二阶段使非芳族化合物产物流的第二部分与芳构化催化剂接触以产生包含芳族化合物的第二阶段产物流。

10. 发明申请

WO2010051007A1 STABLE SHAPE-SELECTIVE CATALYST FOR AROMATIC ALKYLATION AND METHODS OF USING AND PREPARING 审中-公开
标题翻译：用于芳香烷基化的稳定形状选择性催化剂及其使用和制备方法
公开(公告)号：WO2010051007A1
公开(公告)日：2010-05-06
申请号：PCT/US2009/005613
申请日：2009-10-14
申请人： SAUDI BASIC INDUSTRIES CORPORATION , GHOSH, Ashim, Kumar , KULKARNI, Neeta
发明人： GHOSH, Ashim, Kumar , KULKARNI, Neeta
IPC分类号： C07C2/68
CPC分类号： B01J29/44 , B01J29/40 , B01J29/46 , B01J37/28 , B01J2229/18 , B01J2229/20 , B01J2229/37 , B01J2229/42 , C07C2/66 , C07C2529/44 , C07C15/02
摘要： A catalyst and method of forming a catalyst for use in aromatic alkylation involves treating a zeolite, which may be a ZSM-5 zeolite, with a phosphorus- containing compound. The phosphorus-treated zeolite is combined with a binder material. The bound phosphorus-treated zeolite is treated with an aqueous solution of a hydrogenating metal compound by contacting the bound phosphorus-treated zeolite with the aqueous solution and separating the aqueous solution from the bound phosphorus-treated zeolite to form a hydrogenating-metal-containing zeolite catalyst. The catalyst may be used in preparing an alkyl aromatic product by contacting a hydrogenating-metal-containing zeolite catalyst with an aromatic alkylation feed of an aromatic compound and an alkylating agent under reaction conditions suitable for aromatic alkylation.
摘要翻译：形成用于芳族烷基化的催化剂的催化剂和方法包括用含磷化合物处理可以是ZSM-5沸石的沸石。磷处理的沸石与粘合剂材料组合。将结合的磷处理的沸石用氢化金属化合物的水溶液处理，使结合的磷处理的沸石与水溶液接触，并将水溶液与结合的磷处理的沸石分离，形成含氢化金属的沸石催化剂。通过使含氢化金属的沸石催化剂与芳族化合物和烷基化剂的芳族烷基化进料在适于芳族烷基化的反应条件下接触，催化剂可用于制备烷基芳族化合物。

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