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    • 2. 发明申请
    • PRODUCTION OF C2+ OLEFINS
    • 生产C2 +烯烃
    • WO2015084575A3
    • 2015-11-19
    • PCT/US2014065956
    • 2014-11-17
    • EXXONMOBIL CHEM PATENTS INC
    • KEUSENKOTHEN PAUL FHENAO JUAN D
    • C07C1/06C07C2/76C07C2/86C07C5/333C07C11/04C07C11/06
    • C07C2/864C07C1/06C07C2/76C07C2/862C07C5/333C07C2529/06C07C2529/65C07C2529/70C07C2529/85C08F10/00C07C11/04C07C11/06
    • This disclosure relates to the production of C2+olefins from feeds containing methane and at least one co-reactant, to equipment and materials useful in such processes, and to the use of such olefins in, for example, the production of polymers and in particular to a process for producing one or more of C2+olefin, the process comprising: (a) providing a feed comprising at least 9 vol. % of methane and at least 4 vol. % of at least one co-reactant selected from the group consisting of C2+alkane, syngas, and alcohol; (b) providing a catalyst comprising at least one molecular sieve, the molecular sieve comprising at least one set of pores of substantially uniform size extending through the molecular sieve, wherein geometric mean of the cross-sectional dimensions of each of the pores is less than or equal to 5.3 Â; (c) contacting the feed with the catalyst under conditions, including a temperature of no more than 700°C, effective to convert at least part of the methane and co-reactant in the feed to a product comprising C2+olefin; and (d) separating at least part of the C2+olefin from the product.
    • 本公开涉及从含有甲烷和至少一种共反应物的进料的碳氢化合物生产C2 +烯烃,可用于这些方法的设备和材料,以及在例如聚合物生产中使用这种烯烃 涉及用于生产一种或多种C 2 +烯烃的方法,该方法包括:(a)提供包含至少9体积% 甲烷百分比和至少4体积% %的至少一种选自C2 +烷烃,合成气和醇的共反应物; (b)提供包含至少一种分子筛的催化剂,所述分子筛包括延伸穿过分子筛的至少一组基本上均匀的尺寸的孔,其中每个孔的横截面尺寸的几何平均值小于 或等于5.3? (c)在包括不超过700℃的温度的条件下使进料与催化剂接触,有效地将进料中的至少部分甲烷和共反应物转化为包含C 2 +烯烃的产物; 和(d)从产物中分离出至少部分的C2 +烯烃。
    • 3. 发明申请
    • HYDROCARBON CONVERSION
    • 石油转化
    • WO2015084576A3
    • 2015-11-19
    • PCT/US2014065961
    • 2014-11-17
    • EXXONMOBIL CHEM PATENTS INC
    • KEUSENKOTHEN PAUL FHENAO JUAN DPATIL ABHIMANYU OCAO GUANG
    • C07C2/76C07C15/00
    • C07C2/864C07C2/76C07C2/865C07C2529/06C07C2529/40C07C2529/44C07C2529/46C07C2529/48C07C2529/87C07C15/00
    • This disclosure relates to the conversion of methane to higher molecular weight (C5+) hydrocarbon, including aromatic hydrocarbon, to materials and equipment useful in such conversion, and to the use of such conversion for, e.g., natural gas upgrading. A process for producing aromatic hydrocarbon, the process comprising: (a) providing a feed comprising at least one C2+aliphatic hydrocarbon, at least one Ci+organic oxygenate and at least 9 mole % of methane, the mole percent being based on per mole of feed, wherein the molar ratio of methane to Ci+oxygenate in the feed is in the range of 0.6:1 to 20:1 and the molar ratio of methane to C2+aliphatic hydrocarbon in the feed is in the range of from 0.1:1 1 to 20:1; (b) contacting the feed with a catalyst comprising at least one molecular sieve and at least one dehydrogenation component under conditions, including a temperature
    • 本公开涉及将甲烷转化为高分子量(C 5+)烃(包括芳族烃)转化为可用于这种转化的材料和设备,以及将这种转化用于例如天然气升级。 一种制备芳族烃的方法,该方法包括:(a)提供包含至少一种C 2 +脂族烃,至少一种C 1有机含氧化合物和至少9摩尔%甲烷的进料,其摩尔百分比基于每摩尔 的进料,其中进料中甲烷与C 1 +含氧化合物的摩尔比在0.6:1至20:1的范围内,并且进料中甲烷与C 2 +脂族烃的摩尔比在0.1:1〜 1 1〜20:1; (b)在包括至少部分甲烷,C2 +烃和C1 +有机含氧化合物的条件下,包括至少一种分解筛和至少一种脱氢组分的催化剂下接触进料 在包含至少5wt。 基于产品重量的Cs +烃的%; 和(c)从产物中分离出至少部分的C5 +烃。