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1. 发明申请

WO2007123977A3 PRODUCTION OF AROMATICS FROM METHANE 审中-公开
公开(公告)号：WO2007123977A3
公开(公告)日：2007-11-01
申请号：PCT/US2007/009538
申请日：2007-04-18
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , IACCINO, Larry, L. , SANGAR, Neeraj , STAVENS, Elizabeth, L. , PATT, Jeremy, J.
发明人： IACCINO, Larry, L. , SANGAR, Neeraj , STAVENS, Elizabeth, L. , PATT, Jeremy, J.
IPC分类号： C07C2/76 , C10G50/00
摘要： In a process for converting methane to aromatic hydrocarbons, a feed containing methane is supplied to one or more reaction zone(s) containing catalytic material operating under reaction conditions effective to convert at least a portion of the methane to aromatic hydrocarbons; the reaction zone(s) being operated with an inverse temperature profile.

2. 发明申请

WO2007123977A2 PRODUCTION OF AROMATICS FROM METHANE 审中-公开
标题翻译：从甲烷生产芳族化合物
公开(公告)号：WO2007123977A2
公开(公告)日：2007-11-01
申请号：PCT/US2007009538
申请日：2007-04-18
申请人： EXXONMOBIL CHEM PATENTS INC , IACCINO LARRY L , SANGAR NEERAJ , STAVENS ELIZABETH L , PATT JEREMY J
发明人： IACCINO LARRY L , SANGAR NEERAJ , STAVENS ELIZABETH L , PATT JEREMY J
CPC分类号： C07C2/76 , C07C2529/48 , C10G45/44 , Y02P20/142 , Y02P20/52 , Y10S585/943 , C07C15/04 , C07C15/02
摘要： In a process for converting methane to aromatic hydrocarbons, a feed containing methane is supplied to one or more reaction zone(s) containing catalytic material operating under reaction conditions effective to convert at least a portion of the methane to aromatic hydrocarbons; the reaction zone(s) being operated with an inverse temperature profile.
摘要翻译：在将甲烷转化为芳族烃的方法中，含有甲烷的进料被供应到一个或多个反应区，该反应区含有在有效将甲烷的至少一部分转化为芳烃的反应条件下运行的催化材料; 反应区域以反向温度曲线运行。

3. 发明申请

WO2009105344A3 PRODUCTION OF AROMATICS FROM METHANE 审中-公开
标题翻译：从甲烷生产芳族化合物
公开(公告)号：WO2009105344A3
公开(公告)日：2010-01-07
申请号：PCT/US2009033198
申请日：2009-02-05
申请人： EXXONMOBIL CHEM PATENTS INC , SANGAR NEERAJ , XU TENG , IACCINO LARRY L , AFEWORKI MOBAE
发明人： SANGAR NEERAJ , XU TENG , IACCINO LARRY L , AFEWORKI MOBAE
IPC分类号： B01J29/076 , B01J29/48 , B01J38/06 , B01J38/14 , C07C2/76 , C10G50/00
CPC分类号： B01J29/48 , B01J29/076 , B01J29/90 , B01J35/002 , B01J38/06 , B01J38/14 , B01J2229/186 , B01J2229/36 , B01J2229/40 , C07C2/76 , C07C2529/48 , C10G50/00 , C10G2300/1025 , C10G2400/30 , Y02P20/584 , Y02P20/588 , C07C15/00
摘要： A catalyst for the conversion of methane to higher hydrocarbons including aromatic hydrocarbons comprises molybdenum or a compound thereof dispersed on an aluminosilicate zeolite, wherein the amount of aluminum present as aluminum molybdate in the catalyst is less than 2700 ppm by weight.
摘要翻译：用于将甲烷转化为包括芳烃的高级烃的催化剂包括分散在铝硅酸盐沸石上的钼或其化合物，其中在催化剂中以钼酸铝存在的铝的量小于2700ppm重量。

4. 发明申请

WO2009105344A2 PRODUCTION OF AROMATICS FROM METHANE 审中-公开
标题翻译：从甲烷生产芳族化合物
公开(公告)号：WO2009105344A2
公开(公告)日：2009-08-27
申请号：PCT/US2009/033198
申请日：2009-02-05
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , SANGAR, Neeraj , XU, Teng , IACCINO, Larry, L. , AFEWORKI, Mobae
发明人： SANGAR, Neeraj , XU, Teng , IACCINO, Larry, L. , AFEWORKI, Mobae
IPC分类号： B01J29/076 , B01J29/48 , B01J38/14 , C07C2/76 , C10G50/00
CPC分类号： B01J29/48 , B01J29/076 , B01J29/90 , B01J35/002 , B01J38/06 , B01J38/14 , B01J2229/186 , B01J2229/36 , B01J2229/40 , C07C2/76 , C07C2529/48 , C10G50/00 , C10G2300/1025 , C10G2400/30 , Y02P20/584 , Y02P20/588 , C07C15/00
摘要： A catalyst for the conversion of methane to higher hydrocarbons including aromatic hydrocarbons comprises molybdenum or a compound thereof dispersed on an aluminosilicate zeolite, wherein the amount of aluminum present as aluminum molybdate in the catalyst is less than 2700 ppm by weight.
摘要翻译：用于将甲烷转化为包括芳烃的高级烃的催化剂包括分散在铝硅酸盐沸石上的钼或其化合物，其中在催化剂中以钼酸铝存在的铝的量小于2700重量ppm。

5. 发明申请

WO2009097067A2 PRODUCTION OF AROMATICS FROM METHANE 审中-公开
标题翻译：甲烷生产芳香剂
公开(公告)号：WO2009097067A2
公开(公告)日：2009-08-06
申请号：PCT/US2008/087980
申请日：2008-12-22
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , SANGAR, Neeraj , KOWALSKI, Jocelyn, A. , IACCINO, Larry, L. , CLEM, Kenneth, R.
发明人： SANGAR, Neeraj , KOWALSKI, Jocelyn, A. , IACCINO, Larry, L. , CLEM, Kenneth, R.
IPC分类号： B01J29/48 , C07C2/76 , C10G50/00
CPC分类号： B01J29/48 , B01J21/063 , B01J21/066 , B01J29/076 , B01J35/0006 , B01J35/002 , B01J37/0009 , B01J37/08 , B01J2229/20 , B01J2229/42 , C07C2/76 , C07C2529/48 , C10G2300/1025 , C10G2400/30 , C07C15/00
摘要： A catalyst for the conversion of methane to higher hydrocarbons including aromatic hydrocarbons comprises a support and molybdenum or a compound thereof dispersed on the support. The support comprises an aluminosilicate zeolite combined with a binder selected from silica, titania, zirconia and mixtures thereof. The catalyst is substantially free of aluminum external to the framework of the aluminosilicate zeolite.
摘要翻译：用于将甲烷转化成包括芳族烃的高级烃的催化剂包含分散在载体上的载体和钼或其化合物。载体包含与选自二氧化硅，二氧化钛，氧化锆及其混合物的粘合剂组合的硅铝酸盐沸石。该催化剂基本上不含铝在硅铝酸盐沸石骨架外部。

6. 发明申请

WO2007127026A2 PRODUCTION OF AROMATICS FROM METHANE 审中-公开
标题翻译：从甲烷生产芳族化合物
公开(公告)号：WO2007127026A2
公开(公告)日：2007-11-08
申请号：PCT/US2007/008393
申请日：2007-04-05
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , IACCINO, Larry, L. , SANGAR, Neeraj , STAVENS, Elizabeth, L.
发明人： IACCINO, Larry, L. , SANGAR, Neeraj , STAVENS, Elizabeth, L.
CPC分类号： C07C2/84 , C07C2/76 , C07C2529/48 , Y02P20/584 , Y10S585/943 , C07C15/02 , C07C15/04
摘要： In a process for converting methane to aromatic hydrocarbons, a feed containing methane is contacted with a dehydrocyclization catalyst in a reaction zone under conditions including a first maximum temperature effective to convert the methane to aromatic hydrocarbons and generate coke on the catalyst. A portion of the coked catalyst is transferred from the reaction zone to a separate regeneration zone, where the catalyst portion is contacted with a regeneration gas under conditions including a second maximum temperature less than or equal to the first maximum temperature and effective to at least partially remove coke from the catalyst portion. Before being returned to the reaction zone, the regenerated catalyst portion is contacted with a carburizing gas in a catalyst treatment zone separate from the reaction zone at a third maximum temperature less than the first maximum temperature.
摘要翻译：在将甲烷转化为芳烃的方法中，在包括有效将甲烷转化为芳族烃并在催化剂上产生焦炭的第一最高温度的条件下，将含甲烷的进料在反应区中与脱氢环化催化剂接触。焦化催化剂的一部分从反应区转移到单独的再生区，其中催化剂部分在包括第二最高温度小于或等于第一最高温度的条件下与再生气体接触，并有效至少部分地从催化剂部分除去焦炭。在返回到反应区之前，再生的催化剂部分在与反应区分开的催化剂处理区中的渗碳气体在低于第一最高温度的第三最高温度下接触。

7. 发明申请

WO2012047401A2 REGENERATION OF METAL-CONTAINING CATALYSTS 审中-公开
标题翻译：含金属催化剂的再生
公开(公告)号：WO2012047401A2
公开(公告)日：2012-04-12
申请号：PCT/US2011049269
申请日：2011-08-26
申请人： EXXONMOBIL CHEM PATENTS INC , CLEM KENNETH R , IACCINO LARRY L , AFEWORKI MOBAE , HENAO JUAN D , SANGAR NEERAJ , ZHENG XIAOBO , DECAUL LORENZO C
发明人： CLEM KENNETH R , IACCINO LARRY L , AFEWORKI MOBAE , HENAO JUAN D , SANGAR NEERAJ , ZHENG XIAOBO , DECAUL LORENZO C
IPC分类号： B01J38/04 , B01J27/28 , B01J29/90 , B01J38/10 , C07C2/86
CPC分类号： C07C2/76 , B01J29/48 , B01J29/90 , B01J38/02 , B01J38/10 , C07C1/12 , C07C2/66 , C07C2/864 , C07C2/865 , C07C5/10 , C07C5/11 , C07C2521/06 , C07C2523/02 , C07C2523/06 , C07C2523/08 , C07C2523/10 , C07C2523/12 , C07C2523/14 , C07C2523/16 , C07C2523/18 , C07C2523/20 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/34 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/50 , C07C2523/52 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2527/22 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/60 , C07C2529/65 , C07C2529/70 , C07C2601/14 , C07C2601/16 , C07C2602/26 , C07C2602/28 , C10G50/00 , C10G2300/708 , C10G2400/30 , Y02P20/52 , Y02P20/584 , Y02P20/588 , C07C15/04 , C07C15/24 , C07C11/04 , C07C9/04 , C07C9/06 , C07C15/073 , C07C15/08 , C07C13/18 , C07C13/50 , C07C13/20 , C07C13/48
摘要： In a process for the regeneration of a coked metal-containing catalyst, the coked catalyst is contacted in a regeneration zone with an atmosphere which contains carbon dioxide and carbon monoxide at a temperature of at least 400 °C.
摘要翻译：在用于再生焦化含金属催化剂的方法中，焦化催化剂在再生区与含有二氧化碳和一氧化碳的气氛在至少400℃的温度下接触。

8. 发明申请

WO2008027181A3 PRODUCTION OF AROMATICS FROM METHANE 审中-公开
标题翻译：从甲烷生产芳族化合物
公开(公告)号：WO2008027181A3
公开(公告)日：2008-04-24
申请号：PCT/US2007017918
申请日：2007-08-13
申请人： EXXONMOBIL CHEM PATENTS INC , SANGAR NEERAJ , IACCINO LARRY L , JONES JEFFREY P
发明人： SANGAR NEERAJ , IACCINO LARRY L , JONES JEFFREY P
IPC分类号： C07C2/76
CPC分类号： C07C2/76 , C07C2521/04 , C07C2521/08 , C07C2523/06 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2529/40 , C10G50/00 , C10G2300/1025 , C10G2400/30
摘要： In a process for converting methane to aromatic hydrocarbons, a feed containing methane is contacted with a dehydrocyclization catalyst in a reaction zone under conditions effective to convert the methane to aromatic hydrocarbons. The reaction zone is contained within a reactor and the reactor or an internal component of the reactor has at least one surface that is chemically exposed to the feed and is formed from a refractory material that exhibits a carbon uptake (mass of carbon absorbed per unit of exposed metal surface area) of less than 25 g/m 2 when exposed to mixture of 50vol% methane and 50vol% H 2 at 9000C for 168 hours.
摘要翻译：在将甲烷转化为芳族烃的方法中，在有效将甲烷转化为芳烃的条件下，含有甲烷的进料在反应区中与脱氢环化催化剂接触。反应区包含在反应器内，并且反应器或反应器的内部组分具有化学暴露于进料的至少一个表面，并且由表现出碳吸收的耐火材料形成（每单位面积吸收的碳的质量暴露的金属表面积）当暴露于50体积％甲烷和50体积％H 2 O 3的混合物在900℃下168小时时小于25g / m 2。

9. 发明申请

WO2007127026A3 PRODUCTION OF AROMATICS FROM METHANE 审中-公开
标题翻译：从甲烷生产芳族化合物
公开(公告)号：WO2007127026A3
公开(公告)日：2008-01-17
申请号：PCT/US2007008393
申请日：2007-04-05
申请人： EXXONMOBIL CHEM PATENTS INC , IACCINO LARRY L , SANGAR NEERAJ , STAVENS ELIZABETH L
发明人： IACCINO LARRY L , SANGAR NEERAJ , STAVENS ELIZABETH L
IPC分类号： C07C2/84
CPC分类号： C07C2/84 , C07C2/76 , C07C2529/48 , Y02P20/584 , Y10S585/943 , C07C15/02 , C07C15/04
摘要： In a process for converting methane to aromatic hydrocarbons, a feed containing methane is contacted with a dehydrocyclization catalyst in a reaction zone under conditions including a first maximum temperature effective to convert the methane to aromatic hydrocarbons and generate coke on the catalyst. A portion of the coked catalyst is transferred from the reaction zone to a separate regeneration zone, where the catalyst portion is contacted with a regeneration gas under conditions including a second maximum temperature less than or equal to the first maximum temperature and effective to at least partially remove coke from the catalyst portion. Before being returned to the reaction zone, the regenerated catalyst portion is contacted with a carburizing gas in a catalyst treatment zone separate from the reaction zone at a third maximum temperature less than the first maximum temperature.
摘要翻译：在将甲烷转化为芳烃的方法中，在包括有效将甲烷转化为芳族烃并在催化剂上产生焦炭的第一最高温度的条件下，将含甲烷的进料在反应区中与脱氢环化催化剂接触。焦化催化剂的一部分从反应区转移到单独的再生区，其中催化剂部分在包括第二最高温度小于或等于第一最高温度的条件下与再生气体接触，并有效至少部分地从催化剂部分除去焦炭。在返回到反应区之前，再生的催化剂部分在与反应区分开的催化剂处理区中的渗碳气体在低于第一最高温度的第三最高温度下接触。

10. 发明申请

WO2007126811A2 PROCESS FOR METHANE CONVERSION 审中-公开
标题翻译：甲烷转化方法
公开(公告)号：WO2007126811A2
公开(公告)日：2007-11-08
申请号：PCT/US2007/007563
申请日：2007-03-29
申请人： EXXONMOBIL CHEMICAL PATENT INC. , IACCINO, Larry, L. , SANGAR, Neeraj , STAVENS, Elizabeth, L.
发明人： IACCINO, Larry, L. , SANGAR, Neeraj , STAVENS, Elizabeth, L.
CPC分类号： C07C2/84 , C07C2/78 , C07C2529/48 , Y02P20/142 , C07C15/02
摘要： A process for converting methane to higher hydrocarbon(s) including aromatic hydrocarbon(s) comprises providing a hydrocarbon feedstock containing methane and a catalytic particulate material to a reactor system having at least first and second reaction zones connected in series. Each of the reaction zones is operated under reaction conditions sufficient to convert at least a portion of the methane to said higher hydrocarbon(s) and is maintained in a moving bed fashion, with the bulk of the catalytic particulate material being moved from the first reaction zone to the second reaction zone and with the bulk of the hydrocarbon feedstock being moved from the second reaction zone to the first reaction zone.
摘要翻译：将甲烷转化为高级烃（包括芳族烃）的方法包括向具有至少第一和第二反应区串联连接的反应器系统提供含有甲烷和催化颗粒物质的烃原料。每个反应区域在足以将至少一部分甲烷转化成所述较高级烃的反应条件下运行并保持在移动床的方式，其中大部分催化颗粒材料从第一反应区到第二反应区，并且大部分烃原料从第二反应区移动到第一反应区。

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