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1. 发明申请

WO2013021314A1 PROCESS FOR THE PREPARATION OF POLYMERS CONTAINING BENZOHETERO [1, 3] DIAZOLE UNITS 审中-公开
标题翻译：制备含有苯并[1,3]二唑单体的聚合物的方法
公开(公告)号：WO2013021314A1
公开(公告)日：2013-02-14
申请号：PCT/IB2012/053925
申请日：2012-08-01
申请人： ENI S.P.A. , SCHIMPERNA, Giuliana , BIANCHI, Gabriele
发明人： SCHIMPERNA, Giuliana , BIANCHI, Gabriele
IPC分类号： C08G61/12 , C08G73/00 , H01B1/00 , H01L51/00
CPC分类号： C08G75/32 , C08G61/123 , C08G61/126 , C08G73/0611 , C08G2261/1412 , C08G2261/3223 , C08G2261/3241 , C08G2261/3246 , C08G2261/92 , H01B1/00 , H01L51/00 , H01L51/0036 , Y02E10/549
摘要： Process for the preparation of a polymer containing benzohetero [1, 3 ] diazole. units which comprises reacting at least one disubstituted benzohetero [1, 3 ] diazole compound with at least one heteroaryl compound. Said polymer can be advantageously used in the construction of photovoltaic devices such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, on both a rigid and flexible support. Furthermore, said polymer can be advantageously used in the construction of Organic Thin Film Transistors (OTFTs), or of Organic Field Effect Transistors (OFETs).
摘要翻译：制备含苯并[1,3]二唑的聚合物的方法。包括使至少一种二取代苯并[1,3]二唑化合物与至少一种杂芳基化合物反应的单元。所述聚合物可以有利地用于在刚性和柔性载体上构建光伏器件，例如光伏电池，光伏模块，太阳能电池，太阳能电池组件。此外，所述聚合物可有利地用于有机薄膜晶体管（OTFT）或有机场效应晶体管（OFET）的构造中。

2. 发明申请

WO2013021315A1 PROCESS FOR THE PREPARATION OF BENZOHETERO [ 1, 3 ] - DIAZOLE COMPOUNDS DISUBSTITUTED WITH HETEOARYL GROUPS 审中-公开
标题翻译：制备苯并[1,3] - 二氧化钛组合物的方法
公开(公告)号：WO2013021315A1
公开(公告)日：2013-02-14
申请号：PCT/IB2012/053927
申请日：2012-08-01
申请人： ENI S.p.A. , SCHIMPERNA, Giuliana , BIANCHI, Gabriele
发明人： SCHIMPERNA, Giuliana , BIANCHI, Gabriele
IPC分类号： C07D409/14 , C07D413/14 , C07D417/14 , C07D519/00
CPC分类号： C07D417/14 , C07D409/14 , C07D413/14 , C07D495/04 , C07D519/00
摘要： Process for the preparation of a benzohetero [ 1, 3 ] diazole compound disubstituted with heteroaryl groups which comprises reacting at least one benzohetero [ 1, 3 ] diazole compound disubstituted with at least one heteroaryl compound. Said benzohetero [ 1, 3 ] diazole compound disubstituted with heteroaryl groups can be advantageously used in the construction of luminescent solar concentrators (LSC). Furthermore, said benzohetero [ 1, 3 ] diazole compound disubstituted with heteroaryl groups can be advantageously used in the construction of photovoltaic devices such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, on both a rigid and flexible support. Said benzohetero [ 1, 3 ] diazole compound disubstituted with heteroaryl groups can also be advantageously used as a precursor of monomeric units in the preparation of semiconductor polymers.
摘要翻译：制备用杂芳基二取代的苯并[1,3]二唑化合物的方法，该方法包括使至少一种被至少一个杂芳基化合物二取代的苯并[1,3]二唑化合物反应。用杂芳基二取代的所述苯并[1,3]二唑化合物可以有利地用于发光太阳能聚光器（LSC）的构建。此外，用杂芳基二取代的所述苯并[1,3]二唑化合物可有利地用于在刚性和柔性载体上构建光伏器件，例如光伏电池，光伏模块，太阳能电池，太阳能电池组件。用杂芳基二取代的所述苯并[1,3]二唑化合物也可有利地用作制备半导体聚合物中单体单元的前体。

3. 发明申请

WO2011144537A1 PHOTOACTIVE COMPOSITION WITH A HIGH MOBILITY OF THE ELECTRONIC HOLES 审中-公开
标题翻译：具有电子孔高移动性的光敏组合物
公开(公告)号：WO2011144537A1
公开(公告)日：2011-11-24
申请号：PCT/EP2011/057791
申请日：2011-05-13
申请人： ENI S.P.A. , SCHIMPERNA, Giuliana , CALDARARO, Maria , BERNARDI, Andrea , CARBONERA, Chiara , LUZZATI, Silvia , CAMAIONI, Nadia , TINTI, Francesca
发明人： SCHIMPERNA, Giuliana , CALDARARO, Maria , BERNARDI, Andrea , CARBONERA, Chiara , LUZZATI, Silvia , CAMAIONI, Nadia , TINTI, Francesca
IPC分类号： C08G61/12 , H01B1/12 , H01L51/52 , C07D471/06 , C07D491/06
CPC分类号： H01L51/0053 , C07D471/06 , H01L51/0036 , H01L51/0039 , H01L51/0043 , H01L51/0068 , H01L51/0566 , H01L51/4253 , Y02E10/549
摘要： A photoactive composition with a high mobility of the elec tronic holes, comprising: -at least one organic photoactive polymer; -at least one naphthalene diimide having general formul (I): wherein: - R 1 and R 2 , the same or different, preferably the same, are selected from linear or branched C 1 -C 36 alky1 groups, preferably C 4 -C 24 , optionally containing heteroatoms such as, for example, oxygen, nitrogen, sulphur; - R' 1 and R' 2 , the same or different, preferably the same, are a hydrogen atom, or are selected from linear or branched C 1 -C 10 alkyl groups, preferably C 2 -C 6 ; they are preferably a hydrogen atom. - R 11 and R 20 , the same or different, preferably the same, are a hydrogen atom, or are selected from linear or branched C 1 -C 16 alkyl groups, preferably C 2 -C 10 ; - R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 12 , R 13 , R 14 , R 15 , R 16 , R 17 , R 18 and R 19 , the same or different, are a hydrogen atom, or are selected from linear or branched C 1 -C 16 alkyl groups preferably C 2 -C 10 ; - a, b, c, d, e, f, g, and h, the same or different, are 0 or 1, on the condition that at least one is different from zero. Said photoactive composition with a high mobility of the electronic holes, can be advantageously used in the construction of photovoltaic devices, such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, both on rigid and flexible support.
摘要翻译：具有高电子迁移率的光敏组合物，其包含： - 至少一种有机光活性聚合物; - 至少一个具有通式（I）的萘二酰亚胺：其中：-R 1和R 2相同或不同，优选相同，选自直链或支链C 1 -C 36烷基，优选C 4 -C 24，任选地含有杂原子例如，氧，氮，硫; -R'1和R'2相同或不同，优选相同的是氢原子，或选自直链或支链C 1 -C 10烷基，优选C 2 -C 6; 它们优选为氢原子。 -R 11和R 20相同或不同，优选相同的是氢原子，或选自直链或支链C 1 -C 16烷基，优选C 2 -C 10; -R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10，R 12，R 13，R 14，R 15，R 16，R 17，R 18和R 19相同或不同，为氢原子，或选自直链或支链 C1-C16烷基优选C2-C10; 在至少一个不同于零的条件下，a，b，c，d，e，f，g和h相同或不同，为0或1。具有电子孔的高迁移率的所述光活性组合物可以有利地用于在刚性和柔性载体上的光伏器件（例如光伏电池，光伏模块，太阳能电池，太阳能电池组件）的构造中。

4. 发明申请

WO2011138655A1 AROMATIC MONOMERS DERIVING FROM GLYCEROL UNITS, PROCESS FOR THEIR PREPARATION AND USE THEREOF FOR THE PREPARATION OF WATER-SOLUBLE CONJUGATED POLYMERS 审中-公开
标题翻译：从甘油单位获得的芳族单体，其制备和使用它们制备水溶性聚合物的方法
公开(公告)号：WO2011138655A1
公开(公告)日：2011-11-10
申请号：PCT/IB2011/000941
申请日：2011-04-29
申请人： ENI S.P.A. , SCHIMPERNA, Giuliana , PO', Riccardo , PELLEGRINO, Andrea , CALDARARO, Maria
发明人： SCHIMPERNA, Giuliana , PO', Riccardo , PELLEGRINO, Andrea , CALDARARO, Maria
IPC分类号： C07D317/22 , C07D405/12 , C07D409/12 , C08G61/12 , H01L51/00
CPC分类号： C07D405/12 , C07D317/22 , C07D409/12 , C08G61/123 , C08G61/124 , C08G61/126 , C08G75/06 , C08G2261/124 , C08G2261/1422 , C08G2261/1424 , C08G2261/3142 , C08G2261/3223 , C08G2261/3241 , C08G2261/3246 , C08G2261/411 , C08G2261/91 , H01L51/0036 , H01L51/0039 , H01L51/0043 , H01L51/0068 , H01L51/0072 , H01L51/42
摘要： Monomers having formula (I) and process for their synthesis which comprises the etherification reaction of a halogen-derivative (Z = C1, Br, I) having formula (III) with the hydroxyl group of the glycerol derivative (IV), according to the following scheme:(Formula III, IV & I) (III) (IV) (I)
摘要翻译：具有式（I）的单体及其合成方法，其包括具有式（III）的卤素衍生物（Z = C1，Br，I）与甘油衍生物（IV）的羟基的醚化反应，根据（式III，IV＆I）（III）（IV）（I）

5. 发明申请

WO2011072876A1 COPOLYMERS FOR SOLAR CELLS BASED ON ACRIDONIC UNITS 审中-公开
标题翻译：基于ACRIDONIC单位的太阳能电池共聚物
公开(公告)号：WO2011072876A1
公开(公告)日：2011-06-23
申请号：PCT/EP2010/007771
申请日：2010-12-15
申请人： ENI S.P.A. , CALDARARO, Maria , PELLEGRINO, Andrea , SCHIMPERNA, Giuliana , PO', Riccardo
发明人： CALDARARO, Maria , PELLEGRINO, Andrea , SCHIMPERNA, Giuliana , PO', Riccardo
IPC分类号： C08G73/06 , C07D409/14 , C08G61/12 , C09D11/10 , H01L51/00
CPC分类号： C07D409/14 , C08G61/122 , C08G61/123 , C08G61/126 , C08G2261/3241 , C08G2261/3246 , C08G2261/411 , C08G2261/91 , H01L51/0036 , H01L51/0043 , H01L51/4253 , Y02E10/549
摘要： The present invention relates to copolymers for solar cells based on acridonic units comprising: a monomeric unit (A) having general formula (I) wherein X is S or Se, Y is 0, S or NR' and R, R', the same or different, are C 4 -C 24 alkyl groups, aryl groups optionally substituted with other functional groups, acyl groups or thioacyl groups; at least one monomer unit (B) having general formula (II) wherein Z is 0, S, Se or N-R", wherein R" is a C 4 -C 24 alkyl group, an aryl group optionally substituted with other functional groups, an acyl group or thioacyl group, said monomeric unit (B) being connected to any position available of a hetero-aromatic side ring of the unit (A) through one of the two positions indicated by the dashed lines in general formula (II). Photovoltaic devices comprising said alternating π-conjugated polymers are also described.
摘要翻译：本发明涉及基于吖啶单体的太阳能电池用共聚物，包括：具有通式（I）的单体单元（A），其中X为S或Se，Y为0，S或NR'，R，R'为相同或不同的是C 4 -C 24烷基，任选被其它官能团取代的芳基，酰基或硫代酰基; 至少一种具有通式（II）的单体单元（B），其中Z为0，S，Se或NR“，其中R”为C 4 -C 24烷基，任选被其它官能团取代的芳基，酰基或硫代酰基，所述单体单元（B）通过通式（II）中虚线所示的两个位置之一连接到单元（A）的异芳族侧环的任何位置上。还描述了包含所述交替的p共轭聚合物的光伏器件。

6. 发明申请

WO2010046114A2 π-CONJUGATED LOW-BAND-GAP COPOLYMERS CONTAINING BENZOTRIAZOLE UNITS 审中-公开
标题翻译：含有苯并噻唑单体的p型共轭低级共聚物
公开(公告)号：WO2010046114A2
公开(公告)日：2010-04-29
申请号：PCT/EP2009/007581
申请日：2009-10-16
申请人： ENI S.P.A. , PO', Riccardo , PELLEGRINO, Andrea , SCHIMPERNA, Giuliana , CALDARARO, Maria
发明人： PO', Riccardo , PELLEGRINO, Andrea , SCHIMPERNA, Giuliana , CALDARARO, Maria
CPC分类号： C08G73/08 , C08G61/123 , C08G61/126 , C08G73/0672 , C08G2261/3142 , C08G2261/3223 , C08G2261/3241 , H01L51/0035 , H01L51/0036 , H01L51/0043 , H01L51/42 , Y02E10/549
摘要： The present invention relates to an alternating or statistical conjugated copolymer comprising: at least one benzotriazole unit B having general formula (Ia) or (Ib) : wherein the group R is selected from alkyl, aryl, acyl or thioacyl groups, possibly substituted; at least one conjugated structural unit A, wherein each unit B is connected with at least one unit A in any of the positions 4, 5, 6 or 7, preferably in positions 4 or 7.
摘要翻译：本发明涉及一种交替或统计共轭共聚物，其包含：至少一种具有通式（Ia）或（Ib）的苯并三唑单元B：其中基团R选自可能被取代的烷基，芳基，酰基或硫代酰基; 至少一个共轭结构单元A，其中每个单元B与位置4,5,6或7中的任何位置中的至少一个单元A相连，优选位置4或7。

7. 发明申请

WO2013001519A1 PHOTOACTIVE CONJUGATED POLYMER COMPRISING DIBENZOTHIENYLPYRROLE UNITS 审中-公开
标题翻译：包含二苯并噻吩单体的光聚合聚合物
公开(公告)号：WO2013001519A1
公开(公告)日：2013-01-03
申请号：PCT/IB2012/053741
申请日：2012-07-23
申请人： ENI S.P.A. , PELLEGRINO, Andrea , SCHIMPERNA, Giuliana
发明人： PELLEGRINO, Andrea , SCHIMPERNA, Giuliana
IPC分类号： C08L61/12 , C08G73/00 , H01B1/00 , H01L51/00 , C09K11/00
CPC分类号： C08L61/12 , C08G61/123 , C08G61/124 , C08G61/126 , C08G73/00 , C08G73/0672 , C08G2261/124 , C08G2261/1412 , C08G2261/3223 , C08G2261/3241 , C08G2261/3243 , C08G2261/3246 , C08G2261/411 , C08G2261/91 , C09K11/00 , H01B1/00 , H01L51/00 , H01L51/0036 , H01L51/4253 , Y02E10/549
摘要： A photoactive conjugated polymer comprising dibenzothienylpyrrole units having general formula (I) wherein: - A and B, equal to or different from each other, represent a 1,2-vinylene group; or they can be selected from divalent cyclic or polycyclic groups containing one or more aromatic or heteroaromatic rings, said aromatic or heteroaromatic rings being optionally substituted; - R represents a linear or branched C 1 -C 32 , preferably C 4 -C 24 , alkyl group; an aryl group optionally substituted; - n is an integer ranging from 10 to 300, preferably ranging from 25 to 250. Said photoactive conjugated polymer comprising dibenzothienylpyrrole units can be advantageously used in the construction of photovoltaic devices such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, on both rigid and flexible supports.
摘要翻译：包含具有通式（I）的二苯并噻吩基吡咯单元的光活性共轭聚合物，其中：-A和B彼此相同或不同，表示1,2-亚乙烯基; 或它们可以选自含有一个或多个芳族或杂芳环的二价环状或多环基团，所述芳族或杂芳环任选被取代; -R表示直链或支链C 1 -C 32，优选C 4 -C 24烷基; 任选取代的芳基; - n为10-300，优选为25-250的整数。所述包含二苯并噻吩基吡咯单元的光敏共轭聚合物可有利地用于构建光电器件，例如光伏电池，光伏组件，太阳能电池，太阳能组件，刚性和柔性支撑。

8. 发明申请

WO2010006698A1 CONJUGATED LOW BAND-GAP COPOLYMERS AND RELATIVE PREPARATION PROCESS 审中-公开
标题翻译：连接低级共聚物和相关制备方法
公开(公告)号：WO2010006698A1
公开(公告)日：2010-01-21
申请号：PCT/EP2009/004710
申请日：2009-06-29
申请人： ENI S.P.A. , PO' Riccardo , SCHIMPERNA, Giuliana , CALDARARO, Maria , CARDACI, Maria. Anna
发明人： PO' Riccardo , SCHIMPERNA, Giuliana , CALDARARO, Maria , CARDACI, Maria. Anna
IPC分类号： C08G73/00 , C08G73/06 , C08G61/12 , H01L51/00
CPC分类号： C08G73/02 , C08G61/122 , C08G61/126 , C08G73/0672 , C08G2261/124 , C08G2261/314 , C08G2261/3142 , C08G2261/3223 , C08G2261/3246 , C08G2261/3422 , C08G2261/91 , C09B21/00 , C09B57/08 , C09B69/105 , C09B69/109 , H01L51/0035 , H01L51/0053 , Y02E10/549
摘要： Alternating conjugated copolymers are described, comprising: naphthalene diimide units A having general formula (I) wherein R and R', the same or different, are alkyl groups, preferably branched, containing from 1 to 36 carbon atoms, preferably from 4 to 24, more preferably from 6 to 18 carbon atoms, or aryl groups, preferably phenyls, substituted with alkyl radicals having from 1 to 24 carbon atoms; at least one conjugated electron-donor structural unit B, wherein unit A is connected to unit B, in the alternating copolymer, in any of the positions 2, 3, 6 or 7.
摘要翻译：描述了交替共轭共聚物，其包含：具有通式（I）的萘二酰亚胺单元A，其中R和R'相同或不同，是优选支链的，含有1至36个碳原子，优选4至24个，或更优选6至18个碳原子的芳基，或由具有1至24个碳原子的烷基取代的芳基，优选苯基; 至少一个共轭电子给体结构单元B，其中单元A连接到单元B，在交替共聚物中，位置2,3,6或7中的任一个。

9. 发明申请

WO2011066954A1 π-CONJUGATED POLYMERS CONTAINING FLUOROARYLVINYLEDENE UNITS AND RELATIVE PREPARATION PROCESS 审中-公开
标题翻译：含有氟代乙烯单体的共聚合聚合物和相关制备方法
公开(公告)号：WO2011066954A1
公开(公告)日：2011-06-09
申请号：PCT/EP2010/007285
申请日：2010-11-30
申请人： ENI S.P.A. , PO' Riccardo , CALDARARO, Maria , SCHIMPERNA, Giuliana
发明人： PO' Riccardo , CALDARARO, Maria , SCHIMPERNA, Giuliana
IPC分类号： C08G61/12 , H01B1/00 , H01L51/00
CPC分类号： C09K11/06 , C08G61/02 , C08G61/123 , C08G2261/1414 , C08G2261/148 , C08G2261/3142 , C08G2261/3246 , C08G2261/3327 , C08G2261/411 , C08G2261/91 , C09K2211/1416 , C09K2211/1483 , H01L51/0036 , H01L51/0039 , H01L51/42 , Y02E10/549 , Y02P70/521
摘要： The present invention relates to π- conjugated polymers containing fluoroarylvinylidene units and the relative preparation process. Photovoltaic devices comprising these alternating π-conjugated polymers are also described.
摘要翻译：本发明涉及含氟芳基亚乙烯基单元的p-共轭聚合物及相对制备方法。还描述了包含这些交替的p共轭聚合物的光伏器件。

10. 发明申请

WO2011048458A8 PHOTOLUMINISCENT COMPOSITIONS FOR SPECTRUM CONVERTERS WITH ENHANCED EFFICIENCY 审中-公开
公开(公告)号：WO2011048458A8
公开(公告)日：2011-04-28
申请号：PCT/IB2010/002639
申请日：2010-10-14
申请人： ENI S.P.A. , ALESSI, Andrea , FUSCO, Roberto , PROTO, Antonio, Alfonso , SCHIMPERNA, Giuliana , SCUDO, Petra
发明人： ALESSI, Andrea , FUSCO, Roberto , PROTO, Antonio, Alfonso , SCHIMPERNA, Giuliana , SCUDO, Petra
IPC分类号： C09K11/06 , H01L31/00
摘要： The present invention relates to a photoluminescent composition comprising an acene compound having general formula (I) or (Ia) and a benzothiadiazole compound having general formula (II), and the relative use as photoluminescent composition in a spectrum converter. A spectrum converter comprising the photoluminescent composition defined above, comprising the above compounds having general formula (I) or (Ia) and (II) and a solar device comprising said spectrum converter, are also described.

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