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1. 发明申请

WO2011144537A1 PHOTOACTIVE COMPOSITION WITH A HIGH MOBILITY OF THE ELECTRONIC HOLES 审中-公开
标题翻译：具有电子孔高移动性的光敏组合物
公开(公告)号：WO2011144537A1
公开(公告)日：2011-11-24
申请号：PCT/EP2011/057791
申请日：2011-05-13
申请人： ENI S.P.A. , SCHIMPERNA, Giuliana , CALDARARO, Maria , BERNARDI, Andrea , CARBONERA, Chiara , LUZZATI, Silvia , CAMAIONI, Nadia , TINTI, Francesca
发明人： SCHIMPERNA, Giuliana , CALDARARO, Maria , BERNARDI, Andrea , CARBONERA, Chiara , LUZZATI, Silvia , CAMAIONI, Nadia , TINTI, Francesca
IPC分类号： C08G61/12 , H01B1/12 , H01L51/52 , C07D471/06 , C07D491/06
CPC分类号： H01L51/0053 , C07D471/06 , H01L51/0036 , H01L51/0039 , H01L51/0043 , H01L51/0068 , H01L51/0566 , H01L51/4253 , Y02E10/549
摘要： A photoactive composition with a high mobility of the elec tronic holes, comprising: -at least one organic photoactive polymer; -at least one naphthalene diimide having general formul (I): wherein: - R 1 and R 2 , the same or different, preferably the same, are selected from linear or branched C 1 -C 36 alky1 groups, preferably C 4 -C 24 , optionally containing heteroatoms such as, for example, oxygen, nitrogen, sulphur; - R' 1 and R' 2 , the same or different, preferably the same, are a hydrogen atom, or are selected from linear or branched C 1 -C 10 alkyl groups, preferably C 2 -C 6 ; they are preferably a hydrogen atom. - R 11 and R 20 , the same or different, preferably the same, are a hydrogen atom, or are selected from linear or branched C 1 -C 16 alkyl groups, preferably C 2 -C 10 ; - R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 12 , R 13 , R 14 , R 15 , R 16 , R 17 , R 18 and R 19 , the same or different, are a hydrogen atom, or are selected from linear or branched C 1 -C 16 alkyl groups preferably C 2 -C 10 ; - a, b, c, d, e, f, g, and h, the same or different, are 0 or 1, on the condition that at least one is different from zero. Said photoactive composition with a high mobility of the electronic holes, can be advantageously used in the construction of photovoltaic devices, such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, both on rigid and flexible support.
摘要翻译：具有高电子迁移率的光敏组合物，其包含： - 至少一种有机光活性聚合物; - 至少一个具有通式（I）的萘二酰亚胺：其中：-R 1和R 2相同或不同，优选相同，选自直链或支链C 1 -C 36烷基，优选C 4 -C 24，任选地含有杂原子例如，氧，氮，硫; -R'1和R'2相同或不同，优选相同的是氢原子，或选自直链或支链C 1 -C 10烷基，优选C 2 -C 6; 它们优选为氢原子。 -R 11和R 20相同或不同，优选相同的是氢原子，或选自直链或支链C 1 -C 16烷基，优选C 2 -C 10; -R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10，R 12，R 13，R 14，R 15，R 16，R 17，R 18和R 19相同或不同，为氢原子，或选自直链或支链 C1-C16烷基优选C2-C10; 在至少一个不同于零的条件下，a，b，c，d，e，f，g和h相同或不同，为0或1。具有电子孔的高迁移率的所述光活性组合物可以有利地用于在刚性和柔性载体上的光伏器件（例如光伏电池，光伏模块，太阳能电池，太阳能电池组件）的构造中。

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